rend., 1869, 69, p. 169) obtained the sodium salt by the action of zinc on a concentrated solution of sodium bisulphite: Zn + 4NaHSO 3 = Na 2 S 2 O 4 + ZnSO 3 + Na 2 SO 3 + 2H 2 O, the salt being separated from the sulphites formed by fractional precipitation.
Thus if concentrated instead of dilute sulphuric acid acts upon zinc, the action takes place to a great extent not according to the equation given above, but according to the equation Zn +2H 2 SO 4 = ZnS04+S02+2 H20, sulphur dioxide and water being produced instead of hydrogen.
The metals may be arranged in a series according to their power of displacing one another in salt solutions, thus Cs, Rb, K, Na, Mg, Al, Mn, Zn, Cd, Tl, Fe, Co, Ni, Sn, Pb, (H), Sb, Bi, As, Cu, Hg, Ag, Pd, Pt, Au.
Group II.: the alkaline earth metals Ca, Sr, Ba, and also Be (GI), Mg, Zn, Cd, divalent; Hg, monovalent and divalent.
Ca, Ba, Sr, Pb; Fe, Zn, Mn, Mg; Ni, Co, Cu; Ce, La, Di, Er, Y, Ca; Cu, Hg, Pb; Cd, Be, In, Zn; Tl, Pb.
We may therefore form an orthogonal transformation in association with every skew determinant which has its leading diagonal elements unity, for the Zn(n-I) quantities b are clearly arbitrary.
Hence the produc J1 t theorem (21, Z2,...zn / (y1, Y2,...y.n) = ?
zl, z2,...zn) yl, y2,.
yl, y 2,...yn) (zl, z2,...zn z1, z 2, ï¿½ï¿½ï¿½zn xi, 'X' 2,...
- zn +9 1 -z2.1 -z3....1-z8; and since this expression is unaltered by the interchange of n and B we prove Hermite's Law of Reciprocity, which states that the asyzygetic forms of degree 0 for the /t ie are equinumerous with those of degree n for the The degree of the covariant in the variables is e=nO-2w; consequently we are only concerned with positive terms in the developments and (w, 0, n) - (w - r; 0, n) will be negative unless nO It is convenient to enumerate the seminvariants of degree 0 and order e=n0-2w by a generating function; so, in the first written generating function for seminvariants, write z2 for z and az n for a;.
826, Sb =0.958, Sn =1.354, Fe =0.007, Zn =0.002, S =0.051.
Associated with these new units there is a system of extensive quantities of the second species, represented by symbols of the type = Ei 121 [i=I, 2,...zn(n - I)].
Of minerals containing this element mention may be made of cassiterite or tinstone, Sn02, tin pyrites, Cu 4 SnS 4 + (Fe,Zn) 2 SnS 4; the metal also occurs in some epidotes, and in company with columbium, tantalum and other metals.
The most important of these are aluminium and zinc, which are converted into aluminate, Al(OK,Na) 3, and zincate, Zn(OK,Na) 2, respectively.
ZINC, a metallic chemical element; its symbol is Zn, and atomic weight 65.37 (0= 16).
Of less importance is the silicate, Zn 2 SiO 4 H 2 0, named electric calamine or hemimorphite; this occurs in quantity in Altenburg near Aix-laChapelle, Sardinia, Spain and the United States (New Jersey, Pennsylvania, Missouri, Wisconsin).
Other zinc minerals are willemite, Zn 2 SiO 4, hydrozincite or zinc bloom, ZnCO 3.2Zn(OH)2, zincite or red zinc ore, ZnO, and franklinite, 3(Fe,Zn)0 (Fe,Mn) 2 0 3 .
Boiling water attacks it appreciably, but slightly, with evolution of hydrogen and formation of the hydroxide, Zn(OH) 2.
Zn(OK)2] Zinc oxide is used in the arts as a white pigment (zinc white); it has not by any means the covering power of white lead, but offers the advantages of being non-poisonous and of not becoming discoloured in sulphuretted hydrogen.
Zinc hydroxide, Zn (OH) 2, is prepared as a gelatinous precipitate by adding a solution of any zinc salt to caustic potash.
Of zinc phosphates we notice the minerals hopeite, Zn.
3 (P04)2.4H20, and tarbuttite, Zn 3 (P04)2.Zn(OH)2, both found in Rhodesia.
According to Christy, the precipitation with zinc follows equations for 2 according as potassium cyanide is present or not: (1) 4 KAu(CN)2+4Zn+2H20=2Zn(CN)2+ K 2 Zn(CN) 4 +Zn(OK) 2 +4H+4Au; (2) 2KAu (CN) 2 +3Zn+4KCN+2H 2 0 = 2K 2 Zn(CN) 4 +Zn(OK) 2 +4H+2Au; one part of zinc precipitating 3.1 parts of gold in the first case, and 2.06 in the second.
If U is the velocity of sound in a gas at pressure P with density p, and if waves of length X and frequency N are propagated through it, then the distanc?e l between the dust-heaps is 2 = N - zN Vyp' where y is the ratio of the two specific heats.
FRANKLINITE, a member of the spinel group of minerals, consisting of oxides of iron, manganese and zinc in varying proportions, (Fe, Zn, Mn)"(Fe, Mn) 2"'0 4.
+Zn(n -I) a n_ 1= Zn(n+3) -2 (without which the transformation would be illusory); and the conclusion is that a 1, a 2, ...
considering the curves of the order n which satisfy Zn(n+3) - 1 conditions, then the index N is the number of these curves which pass through a given arbitrary point.
Calcium ferrite, magnesium ferrite and zinc ferrite, ROFe203(R=Ca, Mg, Zn), are obtained by intensely heating mixtures of the oxides; magnesium ferrite occurs in nature as the mineral magnoferrite, and zinc ferrite as franklinite, both forming black octahedra.
zn'i, the adversary, Gr.
The bacterial biosensors were most sensitive to Zn and showed a clear relationship with the amount of metal found in solution after 1 month.
enol form is certainly capable of a better complexation to Zn A.
Upper panel - found for all examples so far examined of Zn coordinated by two histidines, four residues apart in the protein chain.
In general in space of n dimensions we have n substitutions similar to X l = a11x1 +a12x2 + Ã¯¿½ Ã¯¿½ Ã¯¿½ + ainxn, and we have to express the n 2 coefficients in terms of Zn(n - I)i independent quantities; which must be possible, because X1+X2+..."IL Xn =xi+x2 +x3 +...+4.
yl, y 2,...yn) (zl, z2,...zn z1, z 2, Ã¯¿½Ã¯¿½Ã¯¿½zn xi, 'X' 2,...
(a+nb) is (Ã¯¿½ 28 (i.)) Zn t(a+b)+ (a+nb)} = na+zn(n+1)b = nr1 1 .a+nr2 1.
In general in space of n dimensions we have n substitutions similar to X l = a11x1 +a12x2 + ï¿½ ï¿½ ï¿½ + ainxn, and we have to express the n 2 coefficients in terms of Zn(n - I)i independent quantities; which must be possible, because X1+X2+..."IL Xn =xi+x2 +x3 +...+4.
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