Soc.), regards the property as occasioned by internal vibrations within the molecule conditioned by a symmetrical double tautomerism, light of one wave-length being absorbed by one form, and emitted with a different wave-length by the other.
Although the theories of Meyer and Hewitt do not explain (in their present form) the behaviour of anthranilic acid, yet Hewitt has shown that his theory goes far to explain the fluorescence of substances in which a double symmetrical tautomerism is possible.
This tautomerism may be of a twofold nature :-(I) it may involve the mere oscillation of linkages, as in acridine; or (2) it may involve the oscillation of atoms, as in fluorescein.
In ordinary isomers indications of mutual transformation often occur; and among these the predominant fact is that denoted as tautomerism or pseudomerism.
If Y and Z are groups which behave very differently, then there is apparently no tautomerism and a definite formula can be given to the compound.
tautomerism frozen out by crystal packing forces: 13C nmr spectroscopy and the remarkable crystal structure of the bromohydrin of 7,7-dichlorobicyclo[3.2.0]heptan-6-one.
Selected Publications Ring-chain tautomerism frozen out by crystal packing forces: 13C nmr spectroscopy and the remarkable crystal structure of the bromohydrin of 7,7-dichlorobicyclo[3.2.0]heptan-6-one.
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