For this unfortunate combination Signor Sonnino himself was not altogether to blame; having lost many of his most faithful followers, who, weary of waiting for office, had gone over to the enemy, he had been forced to seek support among men who had professed hostility to the existing order of things and thus to secure at least the neutrality of the Extreme Left and make the public realize that the reddest of Socialists, Radicals and Republicans may be tamed and rendered harmless by the offer of cabinet appointments.
More than ever at the mercy of the Radicals and of their revolutionary allies, Rudini continued so to administer public affairs that subversive propaganda and associations obtained unprecedented extension.
The general election of June 1900 not only failed to reinforce the cabinet, but largely increased the strength of the extreme parties (Radicals, Republicans and Socialists), who in the new Chamber numbered nearly 100 out of a total of 508.
Hess now observed that in the process of mixing such neutral solutions no thermal effect was produced - that is, neutral salts in aqueous solution could apparently interchange their radicals without evolution or absorption of heat.
When in March 1911 the latter resigned in consequence of the hostile vote of the Radicals and the resignation of its two Radical members, Giolitti was again called upon to form a Government (March 3 1).
Berthelot, and many other chemists, from whose researches it results that glycerin is a trihydric alcohol indicated by the formula C 3 H 5 (OH) 3j the natural fats and oils, and the glycerides generally, being substances of the nature of compound esters formed from glycerin by the replacement of the hydrogen of the OH groups by the radicals of certain acids, called for that reason "fatty acids."
Some other glycerides isolated from natural sources are analogous in composition to tristearin, but with this difference, that the three radicals which replace hydrogen in glycerin are not all identical; thus kephalin, myelin and lecithin are glycerides in which two hydrogens are replaced by fatty acid radicals, and the third by a complex phosphoric acid derivative.
And in several European countries; and also in 1882 of the: radicals, or Progressives, who objected to a distinctive dress and'.
Sagasta ultimately headed the most Conservative groups of the revolutionary politicians against Ruiz Zorrilla and the Radicals, and against the Federal Republic in 1873.
The hypothetical radicals of acids, were denoted by squares enclosing the initial letter of the base; an alkali was denoted by a triangle, and the particular alkali by inserting the initial letter.
Groups of two or more atoms like SO 2 and OH, which are capable of playing the part of elementary atoms (that is to say, which can be transferred from compound to compound), are termed compound radicals, the elementary atoms being simple radicals.
The chemical analogy of this substance to chlorine was quickly perceived, especially after its investigation by Davy and Gay Lussac. Cyanogen, a compound which in combination behaved very similarly to chlorine and iodine, was isolated in 1815 by Gay Lussac. This discovery of the first of the then-styled " compound radicals " exerted great influence on the prevailing views of chemical composition.
Lavoisier, to whom chemistry was primarily the chemistry of oxygen compounds, having developed the radical theory initiated by Guyton de Morveau, formulated the hypothesis that vegetable and animal substances were oxides of radicals composed of carbon and hydrogen; moreover, since simple radicals (the elements) can form more than one oxide, he attributed the same character to his hydrocarbon radicals: he considered, for instance, sugar to be a neutral oxide and oxalic acid a higher oxide of a certain radical, for, when oxidized by nitric acid, sugar yields oxalic acid.
2 Compound radicals came to be regarded as the immediate constituents of organic compounds; and, at first, a determination of their empirical composition was supposed to be sufficient to characterize them.
However, in 1833, Berzelius reverted to his earlier opinion that oxygenated radicals were incompatible with his electrochemical theory; he regarded benzoyl as an oxide of the radical C 14 H 1Q, which he named " picramyl " (from 7rucp6s, bitter, and &uvyalk, almond), the peroxide being anhydrous benzoic acid; and he dismissed the views of Gay Lussac and Dumas that ethylene was the radical of ether, alcohol and ethyl chloride, setting up in their place the idea that ether was a suboxide of ethyl, (C2H5)20, which was analogous to K 2 0, while alcohol was an oxide of a radical C 2 H 6; thus annihilating any relation between these two compounds.
Notwithstanding these errors, the value of the " ethyl theory " was perceived; other radicals - formyl, methyl, amyl, acetyl, &c. - were characterized; Dumas, in 1837, admitted the failure of the etherin theory; and, in company with Liebig, he defined organic chemistry as the " chemistry of compound radicals."
The knowledge of compound radicals received further increment at the hands of Robert W.
This rejuvenation of the notion of radicals rapidly gained favour; and the complete fusion of the radical theory with the theory of types was not long delayed.
It did little to satisfy the Radicals, who were angered by the refusal of the second' chamber to agree to their proposal for the summoning of a+.
On the same day (13th of May) a mutiny at Karlsruhe forced the grand-duke to take to flight, and the next day he wis followed by the ministers, while a committee of the diet under Lorenz Brentano (1813-1891), who represented the more moderate Radicals as against the republicans, established itself in the capital to attempt to direct affairs pending the establishment of a provisional government.
In 1891 the National Liberals had but a majority of one in the diet; from 1893 they could maintain themselves only with the aid of the Conservatives; and in 1897 a coalition of Ultramontanes, Socialists, Social-democrats and Radicals (Freisinnige), won a majority for the opposition in the chamber.
Opposition to the " hydrogen-acid " theory centred mainly about the hypothetical radicals which it postulated; moreover, the electrochemical theory of Berzelius exerted a stultifying influence on the correct views of Davy and Dulong.
Depretis, for his part, was compelled to declare impracticable the immediate abolition of the grist tax, and to frame a bill for the increase of revenue, acts which caused the secession of some sixty Radicals and Republicans from the ministerial majority, and gave the signal for an agitation against the premier similar to that which he himself had formerly undertaken against the Right.
The theory of valency as a means of showing similarity of properties and relative composition became a dominant feature of chemical theory, the older hypotheses of types, radicals, &c.
Dumas went no further that thus epitomizing his observations; and the next development was made in 1836 by Auguste Laurent, who, having amplified and discussed the applicability of Dumas' views, promulgated his Nucleus Theory, which assumed the existence of " original nuclei or radicals " (radicaux or noyaux fondamentaux) composed of carbon and hydrogen, and " derived nuclei " (radicaux or noyaux derives) formed from the original nuclei by the substitution of hydrogen or the addition of other elements, and having properties closely related to the primary nuclei.
At the same time, however, the conception of radicals could not be entirely displaced, for the researches of Liebig and Welder, and those made subsequently by Bunsen, demonstrated beyond all doubt the advantages which would accrue from their correct recognition.
Unwilling to discard the strictly unitary views of these chemists, or to adopt the copulae theory of Berzelius, he revived the notion of radicals in a new form.
According to Gerhardt, the process of substitution consisted of the union of two residues to fo- m a unitary whole; these residues, previously termed " compound radicals," are atomic complexes which remain over from the interaction of two compounds.
Von Hofmann continued the investigation, and established their recognition as ammonia in which one or more hydrogen atoms had been replaced by hydrocarbon radicals, thus formulating the " ammonia type."
He rejected the Berzelian tenet as to the unalterability of radicals, and admitted that they exercised a considerable influence upon the compounds with which they were copulated.
From similar investigations of valerianic acid he was led to conclude that fatty acids were oxygen compounds of the radicals hydrogen, methyl, ethyl, &c., combined with the double carbon equivalent C2.
The brilliant researches of Frankland on the organo-metallic compounds, and his consequent doctrine of saturation capacity or valency of elements and radicals, relieved Kolbe's views of all obscurity.
Substituting one hydroxyl group into each of these residues, we obtain radicals of the type - CH 2.
OH and >CH OH, with the production of radicals of the form - CH(OH) 2 and >C(OH)2.
From these nuclei an immense number of derivatives may be obtained, for the hydrogen atoms may be substituted by any of the radicals discussed in the preceding section on the classification of organic compounds.
It has already been stated that benzene derivatives may be regarded as formed by the replacement of hydrogen atoms by other elements or radicals in exactly the same manner as in the aliphatic series.
Compounds derived by substituting aliphatic radicals in the benzene nucleus; such a compound is methylbenzene or toluene, C 6 H 5 CH 3.
It follows therefore that two hydrocarbon radicals are bound to the carbon monoxide residue with the same strength as they combine to form a paraffin.
By 1863 two parties had arisen among the loyal classes: one of radicals, who demanded the calling of a constitutional convention and the abolition of slavery; the other of conservatives.
Nevertheless, the radicals, because it was impossible to call a convention through the medium of the state government, took advantage of this clause to reconvoke the old convention at New Orleans.
Thus, with the tolylphenylketoximes, one yields the anilide of toluic acid and the other the toluidide of benzoic acid, the former necessitating the presence of the phenyl and hydroxyl radicals in the syn position and the latter the tolyl and hydroxyl radicals in the syn position, thus: CH3 C6H4 C C6H5
We have A +k 1 f =0 2, O+k 2 f = x2, O+k3f =4) 2, and Cayley shows that a root of the quartic can be xpressed in the determinant form 1, k, 0.1y the remaining roots being obtained by varying 1, k, x the signs which occur in the radicals 2 u The transformation to the normal form reduces 1, k 3, ?
During 1919 internal politics centred in a struggle between the Radicals, who still possessed the best party machine and stood for a narrowly Serbian as opposed to a Yugoslav programme, and the newly constituted Democratic party, which absorbed most of the Serbian Opposition parties, the old Serbo-Croat coalition of Zagreb, and the Slovene Liberals.
The Radicals of Serbia being conservative in all but name, made a working alliance with the clericals of Zagreb and Ljubljana, and under the leadership of Protic favoured decentralization, combined with concessions to the expropriated landowners.
No party secured an absolute majority, and the two strongest, the Radicals and Democrats, being almost exactly balanced, were forced to strengthen still further their unnatural alliance.
But the exclusion of Gregoire from the chamber and the changes in the franchise embittered the Radicals without conciliating the "Ultras."
Unable to accept Berzelius's doctrine of the unalterability of organic radicals, he also gave a new interpretation to the meaning of copulae under the influence of his fellow-worker Edward Frankland's conception of definite atomic saturation-capacities, and thus contributed in an important degree to the subsequent establishment of the structure theory.
After undergoing extensive alterations in committee at the hands of the Liberals and Radicals, the bill became law in August.
Presented to parliament in November 1898, the bill was read a second time in the following spring, but its third reading was violently obstructed by the Socialists, Radicals and Republicans of the Extreme Left.
In October 1904, after the September strikes, the Chamber was dissolved, and at the general elections in November a ministerial majority was returned, while the deputies of the Extreme Left (Socialists, Republicans and Radicals) were reduced from 107 to 94, and a few mild clericals elected.
After the resignation of President Grevy (2nd of December 1887), he was a candidate for the presidency of the republic, but the radicals refused to support him, and he withdrew in favour of Sadi Carnot.
Both classes readily exchange the imide hydrogen for acid radicals, and give nitrosamines with nitrous acid.
Berzelius, in 1813 and 1814, by improved methods of analysis, established that the Daltonian laws of combination held in both the inorganic and organic kingdoms; and he adopted the view of Lavoisier that organic compounds were oxides of compound radicals, and therefore necessarily contained at least three elements - carbon, hydrogen and oxygen.