Osmotic sentence example
This process involves the performance of 6 7 8 9 an amount of osmotic work P(v - v).
Thermodynamic theory also indicates a connexion between the osmotic pressure of a solution and the depression of its freezing point and its vapour pressure compared with those of the pure solvent.
On the other hand, we may imagine the processes due to the electrical transfer to be reversed by an osmotic operation.
Again, we may calculate the osmotic work done, and, if the whole cycle of operations be supposed to occur at the same temperature, the osmotic work must be equal and opposite to the electrical work of the first operation.
The result of the investigation shows that the electrical work Ee is given by the_equation Ee =1 where v is the volume of the solution used and p its osmotic pressure.Advertisement
When the solutions may be taken as effectively dilute, so that the gas laws apply to the osmotic pressure, this relation reduces to E _ nrRT to c1 ey gE c2 where n is the number of ions given by one molecule of the salt, r the transport ratio of the anion, R the gas constant, T the absolute temperature, y the total valency of the anions obtained from one molecule, and c i and c 2 the concentrations of the two solutions.
When the dissolved molecules are uniformly distributed, the osmotic pressure will be the same everywhere throughout the solution, but, if the concentration vary from point to point, the pressure will vary also.
There must, then, be a relation between the rate of change of the concentration and the osmotic pressure gradient, and thus we may consider the osmotic pressure gradient as a force driving the solute through a viscous medium.
On the analogy between this case and that of the interface between two solutions, Nernst has arrived at similar logarithmic expressions for the difference of potential, which becomes proportional to log (P 1 /P 2) where P2 is taken to mean the osmotic pressure of the cations in the solution, and P i the osmotic pressure of the cations in the substance of the metal itself.
Thus Ludwig was of opinion that the lymph-flow is dependent upon two factors, first, difference in pressure of the blood in the capillaries and the liquid in the plasma spaces outside; and, secondly, chemical interchanges setting up osmotic currents through the vessel-walls.Advertisement
Much more important is the effect of the alteration in the amount of crystalloids in the tissues and blood and therefore of the alteration in the osmotic pressure between these.
Loeb found experimentally that increase of metabolic products in muscle greatly raised its osmotic pressure, and so it would absorb water from a relatively concentrated sodium chloride solution.
Welch produced oedema of the lungs experimentally by increasing the pressure in the pulmonary vessels by ligature of the aorta and its branches, but this raised the blood pressure only about one-tenth of an atmosphere, while in some of Loeb's experiments the osmotic pressure, due to retained metabolic products, was equal to over thirty atmospheres.
Thus differences in osmotic pressure may be much more powerful in producing oedema than mere differences in blood pressure.
Now differences in the amount of crystalloids cause alteration in osmotic pressure while the proteid content affects it but little; and of the crystalloids the chlorides appear to be those most liable to variation.Advertisement
Some other observers, however, have not got such good results with a chloride-free diet, and Marishler, Scheel, Limbecx, Dreser and others, dispute Widal's hypothesis of a retention of chlorides as being the cause of oedema, in the case of renal dropsy at all events; they assert that the chlorides are held back in order to keep the osmotic pressure of the fluid, which they assume to have been effused, equal to that of the blood and tissues.
Thus, while increased pressure in the blood or lymph vessels may be one factor, and increased permeability of the capillary endothelium another, increased osmotic pressure in the tissues and lymph is probably the most important in the production of dropsy.
We therefore regard the body of a Cestode as a single organism within which the gonads have become segmented, and the segmentation of the body as a secondary phenomenon associated with diffuse osmotic feeding in the narrow intestinal canal.
The movement of water into the root-hairs is brought about by the osmotic action of certain salts in their cell-sap. Crops are, however, unable to absorb all the water present in the soil, for when the films become very thin they are held more firmly or cling with more force to the soil particles and resist the osmotic action of the root-hairs.
Further Physical Properties of Sea-water.---The laws of physical chemistry relating to complex dilute solutions apply to seawater, and hence there is a definite relation between the osmotic pressure, freezing-point, vapour tension and boiling-point by which when one of these constants is given the others can be calculated.Advertisement
According to the investigations of Svante Arrhenius the osmotic pressure in atmospheres may be obtained by simply multiplying the temp rature of freezing (r) by the factor -12.08, and it varies with temperature (t) according to the law which holds good for gaseous pressure.
The importance of the osmotic pressure of sea-water in biology will be easily understood from the fact that a frog placed in sea-water loses water by exosmosis and soon becomes 20% lighter than its original weight, while a true salt-water fish suddenly transferred to fresh water gains water by endosmosis, swells up and quickly succumbs.
Pfeffer, made known the phenomena of the osmotic pressure which is set up by the passage of solvent through a membrane impermeable to the dissolved substance or solute.
But such a pressure represents the equilibrium osmotic pressure discussed above.
Therefore the equilibrium osmotic pressure of a solution is connected with the vapour pressure, arid, in a very dilute solution, is expressed by the simple relation just given.Advertisement
In any solution, then, the osmotic pressure represents the excess of hydrostatic pressure which it is necessary to apply to the solution in order to increase its vapour pressure to an equality with that of the solvent in the given conditions.
By imagining that a dilute solution is put through a thermodynamic cycle we may deduce directly relations between its osmotic pressure and its freezing point.
On the fundamental hypotheses of the molecular theory, Value we must regard a solution as composed of a number osmotic of separate particles of solute, scattered through- p out the solvent.
Now the work done by allowing a small quantity of solvent to enter reversibly into an osmotic cylinder is measured by the product of the osmotic pressure into the change in volume.
Hence the osmotic pressure is measured by the work done per unit change of volume of the solution.Advertisement
The result of our consideration, therefore, is that the osmotic pressure of a dilute solution of a volatile solute must have the same value as the gaseous pressure the same number of solute particles would exert if they occupied as gas a volume equal to that of the solution.
The reasoning given above is independent of the temperature, so that the variation with temperature of the osmotic pressure of a dilute solution must be the same as that of a gas, while Boyle's law must equally apply to both systems. Experimental evidence confirms these results, and extends them to the cases of non-volatile solutes - as is, indeed, to be expected, since volatility is merely a matter of degree.
In the limit then, when the concentration of the solution becomes vanishingly small, theory shows that the osmotic pressure is equal to the pressure of a gas filling the same space.
A quantity of gas measured by its molecular weight in grammes when confined in a volume of one litre exerts a pressure of 22.2 atmospheres, and thus the osmotic pressure of a dilute solution divided by its concentration in gramme-molecules per litre has a corresponding value.
Since, in dilute solutions, the osmotic pressure has the gas value, we may apply the gas equation PV=nRT =npvi to osmotic relations.Advertisement
The experiments of Raoult on solutions of organic bodies in water and on solutions of many substances in some dozen organic solvents have confirmed this result, and therefore the theoretical value of the osmotic pressure from which it was deduced.
Although even good membranes of copper ferrocyanide are rarely perfectly semi-permeable, and in other membranes such as indiarubber, &c., which have been used, the defects from the theoretical values of the equilibrium pressure are very great, yet, in the light of the exact verification of theory given by the experiments described above, it is evident that such failures to reach the limiting value in no wise invalidate the theory of osmotic equilibrium.
They merely show that, in the conditions of the particular experiments, the thermodynamic equilibrium value of the osmotic pressure cannot be reached - the thermodynamic or theoretical osmotic pressure (which must be independent of the nature of the membrane provided it is truly semi-permeable) is a different thing from the equilibrium pressure actually reached in a given experiment, which measures the balance of ingress and egress of solvent through an imperfect semi-permeable membrane.
Dilute solutions of substances such as cane-sugar, as we have seen, give experimental values for the connected osmotic properties - pressure, freezing point and vapour pressure - in conformity with the theoretical values.
Now measurements of osmotic properties of these solutions show that their osmotic pressures are abnormally great and that, at extreme dilution, the ratio of their osmotic pressures to that of equivalent solutions of non-electrolytes is equal to the number of ions indicated by the electrolytic properties.Advertisement
The osmotic pressure (defined as the difference in the hydrostatic pressures of the solution and solvent when their vapour pressures are equal and they are consequently in equilibrium through a perfect semi-permeable membrane) may also depend on the absolute values of the hydrostatic pressures, as may the vapour pressure of the liquids.
To investigate the osmotic pressure of a' strong solution we may consider the hydrostatic pressure required to increase its vapour pressure to an equality with that of the solvent.
The osmotic pressure Po is the difference of the hydrostatic pressures P' and P of the solution and the solvent when their vapour pressures are equal.
If V =V' there is no change in osmotic pressure with hydrostatic pressure, and osmotic pressure depends on concentration and temperature only.
From this equation the osmotic pressure Po required to keep a solution in equilibrium as regards its vapour and through a semi-permeable membrane with its solvent, when that solvent is under its own vapour pressure, may be calculated from the results of observations on vapour pressure of solvent and solution at ordinary low hydrostatic pressures.Advertisement
The difference in the lowering of vapour pressures dp - dp' may be put equal to VdP/v, where P is the osmotic pressure, and V the specific volume of the solvent.
Approximately one degree lowering of freezing point corresponds with a change of 12 atmospheres in the osmotic pressure.
Putting in these values and integrating we have, neglecting terms involving 0', P=12.06 0-0.021 O s where P is the osmotic pressure in atmospheres.
Frazer, who have made direct measurements of osmotic pressure of solution of cane-sugar, have also measured the freezing points of corresponding solutions.
Thus the theory of the connexion of osmotic pressure with freezing point (like that with vapour pressure) seems to give results which accord with experiments.Advertisement
At the limit of dilution, when the concentration of a solution approaches zero, we have seen that thermodynamical theory, verified by experiment, shows that the osmotic pressure has the same value as the gas pressure of the same number of molecules in the same space.
The conceptions of osmotic pressure and ideal semi-permeable membranes enable us to deduce other thermodynamic relations between the different properties of solutions.
If it be filled with a solution and the bottom immersed in the pure solvent, pressure equal to the osmotic pressure must be exerted on the piston to maintain equilibrium.
In the equation dP/dT= X/T(v 2 - v 1), P is the osmotic pressure, T the absolute temperature and X the heat of solution of unit mass of the solute when dissolving to form a volume v2 - v1 of saturated solution in an osmotic cylinder.
This result must hold good for any solution, but if the solution be dilute when saturated, that is, if the solubility be small, the equation shows that if there be no heat effect when solid dissolves to form a saturated solution, the solubility is independent of temperature, for, in accordance with the gas laws, the osmotic pressure of a dilute solution of constant concentration is proportional to the absolute temperature.
The available energy A is the work which may be gained from the system by a small reversible isothermal operation with an osmotic cylinder, that is Pdv.
In the case where l is negligible we have P/dP = T/dT, which on integration shows that the osmotic pressure, as in the special case of a dilute solution, is proportional to the absolute temperature.
The physical investigation of osmotic pressure, and its correlation by Van't Hoff with the pressure of a gas, brought forward a new aspect of the phenomena, and suggested an identity of physical modus operandi as well as of numerical value.
Whether osmotic pressure be due to physical impact or to chemical affinity it must necessarily have the gas value in a dilute solution, and be related to vapour pressure and freezing point in the way we have traced.
Boltzmann offered a demonstration of the law of osmotic pressure in dilute solutions, based on the idea that the mean energy of translation of a molecule should be the same in the liquid as in the gaseous state.
In the limit of dilution when n is very small compared with N this gives Raoult's experimental law that the relative lowering is n/N, which we deduced from the osmotic law, and conversely from which the osmotic law follows, while for more concentrated solutions agreement is obtained by assigning arbitrary values to a, which, as we have seen, is 5 in the case of cane-sugar.
The osmotic pressure of a solution depends on the concentration, and, if we regard the difference in that pressure as the effective force driving the dissolved substance through the solution, we are able to obtain the equation of diffusion in another form.
When the solution is dilute enough for the osmotic pressure to possess.
Since some ions are more mobile than others, a separation will ensue when water is placed in contact with a solution, the faster moving ion penetrating quicker into the water under the driving force of the osmotic pressure gradient.
The osmotic pressure of an electrolyte consisting of two ions is double that of a non-electrolyte.
This removal of graphite doubtless further stimulates the formation of graphite, by relieving the mechanical and perhaps the osmotic pressure.
P. Pfeffer (Osmotische Untersuchungen, Leipzig, 1877) was the first to obtain satisfactory measurements of osmotic pressures of cane-sugar solutions up to nearly I atmosphere by means of semi-permeable membranes of copper ferrocyanide.
His observations showed that the osmotic pressure was nearly proportional to the concentration and to the absolute temperature over a limited range.
Van't Hoff showed that the osmotic pressure P due to a number of dissolved molecules n in a volume V was the same as would be exerted by the same number of gas-molecules at the same temperature in the same volume, or that PV = ROn.
Arrhenius, by reasoning similar to that of section 5, applied to an osmotic cell supporting a column of solution by osmotic pressure, deduced the relation between the osmotic pressure P at the bottom of the column and the vapour-pressure p" of the solution at the top, viz.
It is probable that osmotic pressure is not really of the same nature as gas-pressure, but depends on equilibrium of vapour-pressure.
Chemical imbalance can occur as a result of osmotic diuresis.
Osmotic laxatives keep fluid in the bowel for longer which soften feces.
The Cry gene toxins target specific insect cell receptor proteins and create pores that lead to osmotic lysis of the insect gut cells.
This increases osmotic pressure in astrocytes, resulting in cerebral edema.
Nerve impulses from the hypothalamus stimulate the posterior pituitary to produce ADH when the osmotic pressure of the blood rises.
All dissolved substances will contribute to the osmotic pressure of a fluid.
Osmotic laxatives The most commonly used osmotic laxatives include magnesium hydroxide, sodium potassium tartrate, lactulose and glycerol.
In these we have (1) the evaporation from the damp delicate cell-walls into the intercellular spaces; (2) the imbibition by the cell-wall of water from the vacuole; (3) osmotic action, consequent upon the subsequent increased concentration of the cell sap, drawing water from the wood cells or vessels which abut upon the leaf parenchyma.
Marchal points out the analogy of this phenomenon to the artificial polyembryony that has been induced in Echinoderm and other eggs by separating the blastomeres, and suggests that the abundant food-supply afforded by the host-larva is favourable for this multiplication of embryos, which may be, in the first instance, incited by the abnormal osmotic pressure on the egg.
The evidence which led Arrhenius to this conclusion was based on van 't Hoff's work on the osmotic pressure of solutions (see Solution).
At present, measurements of freezing point are more convenient and accurate than those of osmotic pressure, and we may test the validity of Arrhenius' relations by their means.
This increased osmotic pressure is again due to accumulation of crystalloids in the tissues, either products of metabolism due to deficient oxidation from alteration in the blood or other cause, or, it may be, as in some cases of nephritis, owing to a.
Another application of the theory of energy enables us to coordinate the osmotic pressure of a dilute solution with the pressure of a gas occupying the same space.
Gases at high pressures fail to conform to Boyle's law, and solu tions at moderate concentrations give osmotic pressures which increase faster than the concentration.
Hydrogen ions, Potassium ions and Chloride ions are important, but sucrose concentration in the guard cells affects the osmotic concentration too.
Sugars that are not broken down into one of the simplest forms cause the body to push fluid into the intestines, which results in watery diarrhea (osmotic diarrhea).
Multitudes of such hairs on the branches of the roots cause the entry of great quantities of water, which by a subsequent similar osmotic action accumulates in the cortex of the roots.
Doubtless, the excess of any soluble mineral salt or salts interferes with the osmotic absorption of the roots; and although calcium carbonate is insoluble in pure water, it is slightly soluble in water containing carbon dioxide.
Van Hoff pointed out that measurements of osmotic pressure confirmed this value in the case of dilute solutions of cane sugar.
But when we pass to solutions of mineral salts and acids - to solutions of electrolytes in fact - we find that the observed values of the osmotic pressures and of the allied phenomena are greater than the normal values.
Thus the osmotic pressure, or the depression of the freezing point of a solution of potassium chloride should, at extreme dilution, be twice the normal value, but of a solution of sulphuric acid three times that value, since the potassium salt contains two ions and the acid three.
It' would be possible for a body in solution to be dissociated into non-electrical parts, which would give osmotic pressure effects twice or three times the normal value, but, being uncharged, would not act as ions and impart electrical conductivity to the solution.
It should be pointed out that no measurements on osmotic pressures or freezing points can do more than tell us that an excess of particles is present; such experiments can throw no light on the question whether or not those particles are electrically charged.
The dissociation theory was originally suggested by the osmotic pressure relations.