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orthophosphoric

orthophosphoric Sentence Examples

  • These facts may be illustrated with the aid of orthophosphoric acid, which is tribasic: - Acid.

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  • As stated under Phosphorus, phosphoric oxide, P 2 0 5, combines with water in three proportions to form H 2 O P 2 0 5 or HP03, metaphosphoric acid; 2H 2 O P 2 0 5 or H4P207, pyrophosphoric acid; and 3H 2 O P 2 0 5 or H 3 PO 4, orthophosphoric or ordinary phosphoric acid.

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  • Orthophosphoric acid, H3P04, a tribasic acid, is obtained by boiling a solution of the pentoxide in water; by oxidizing, red phosphorus with nitric acid, or yellow phosphorus under the surface of water by bromine or iodine; and also by decomposing a mineral phosphate with sulphuric acid.

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  • Metaphosphoric acid, HP0 3, is a monobasic acid which may be regarded as derived from orthophosphoric acid by the abstraction of one molecule of water, thus H 3 PO 4 - H 2 O = HP0 3; its constitution is therefore (HO)P0 2.

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  • The acid is formed by dissolving phosphorus pentoxide in cold water, or by strongly heating orthophosphoric acid.

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  • On boiling their solutions they yield orthophosphates, whilst those of the heavy metals on boiling with water give a trimetallic orthophosphate and orthophosphoric acid: 3AgP0 3 +3H 2 O=Ag 3 PO 4 +2H 3 PO 4.

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  • Of the phosphotungstic acids the most important is phosphoduodecitungstic acid, H 3 PW, 2040 nH 2 O, obtained in quadratic pyramids by crystallizing mixed solutions of orthophosphoric and metatungstic acids.

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  • These facts may be illustrated with the aid of orthophosphoric acid, which is tribasic: - Acid.

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  • As stated under Phosphorus, phosphoric oxide, P 2 0 5, combines with water in three proportions to form H 2 O P 2 0 5 or HP03, metaphosphoric acid; 2H 2 O P 2 0 5 or H4P207, pyrophosphoric acid; and 3H 2 O P 2 0 5 or H 3 PO 4, orthophosphoric or ordinary phosphoric acid.

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  • Orthophosphoric acid, H3P04, a tribasic acid, is obtained by boiling a solution of the pentoxide in water; by oxidizing, red phosphorus with nitric acid, or yellow phosphorus under the surface of water by bromine or iodine; and also by decomposing a mineral phosphate with sulphuric acid.

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  • Metaphosphoric acid, HP0 3, is a monobasic acid which may be regarded as derived from orthophosphoric acid by the abstraction of one molecule of water, thus H 3 PO 4 - H 2 O = HP0 3; its constitution is therefore (HO)P0 2.

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  • The acid is formed by dissolving phosphorus pentoxide in cold water, or by strongly heating orthophosphoric acid.

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  • On boiling their solutions they yield orthophosphates, whilst those of the heavy metals on boiling with water give a trimetallic orthophosphate and orthophosphoric acid: 3AgP0 3 +3H 2 O=Ag 3 PO 4 +2H 3 PO 4.

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  • Of the phosphotungstic acids the most important is phosphoduodecitungstic acid, H 3 PW, 2040 nH 2 O, obtained in quadratic pyramids by crystallizing mixed solutions of orthophosphoric and metatungstic acids.

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  • It combines violently with sulphur at 160° to form phosphorus sulphoxide, P406S4, which forms highly lustrous tetragonal plates (after sublimation), melting at 102° and boiling at 295°; it is decomposed by water .into sulphuretted hydrogen and metaphosphoric acid, the latter changing on standing into orthophosphoric acid.

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