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nitromethane

nitromethane

nitromethane Sentence Examples

  • A laboratory method is to mix solutions of sodium nitromethane, CH 2: NO(ONa), and mercuric chloride, a yellow basic salt being formed at the same time.

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  • Ag ?HC 'OH ?H CO 2 H-f-H 2 N OH, and also on the production from sodium nitromethane and mercuric chloride, thus CH 2: NO Ohg - > H 2 O -I-C: NOhg (hg = 2 Hg).

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  • This acid with silver nitrite gave nitroacetic acid, which readily gave the second nitromethane, CH a (NO 2) b H c H d, identical with the first nitromethane.

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  • This acid gives with silver nitrite the corresponding nitromalonic acid, which readily yielded the third nitromethane, CHaHb(N02),Hd, also identical with the first.

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  • When methyl iodide is used, nitromethane is the sole product, but the higher homologues give more or less of the isomeric nitrous esters.

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  • Nitromethane, CH 3 NO 2, is a colourless oil which boils at 101° C. Fuming sulphuric acid decomposes it into carbon monoxide and hydroxylamine.

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  • The ketone, dihydroxyacetone, CH 2 OH CO CH 2 OH, was obtained by Piloty by condensing formaldehyde with nitromethane, reducing to a hydroxylamino compound, which is oxidized to the oxime of dihydroxyacetone; the ketone is liberated by oxidation with bromine water: 3H CHO + CH 3 NO 2 -- (CH 2 OH) 3 C NO 2 - (CH 2 OH) 3 C NH OH -- (CH 2 OH) 2 C: NOH - > (CH20H)2CO.

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  • A laboratory method is to mix solutions of sodium nitromethane, CH 2: NO(ONa), and mercuric chloride, a yellow basic salt being formed at the same time.

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  • Ag ?HC 'OH ?H CO 2 H-f-H 2 N OH, and also on the production from sodium nitromethane and mercuric chloride, thus CH 2: NO Ohg - > H 2 O -I-C: NOhg (hg = 2 Hg).

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  • This readily gave with silver nitrite a nitromethane in which we may suppose the nitro-group to replace the a hydrogen atom, i.e.

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  • This acid with silver nitrite gave nitroacetic acid, which readily gave the second nitromethane, CH a (NO 2) b H c H d, identical with the first nitromethane.

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  • This acid gives with silver nitrite the corresponding nitromalonic acid, which readily yielded the third nitromethane, CHaHb(N02),Hd, also identical with the first.

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  • The fourth nitromethane was obtained from the nitromalonic acid previously mentioned by a repetition of the method by which the third was prepared; this was identical with the other three.

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  • When methyl iodide is used, nitromethane is the sole product, but the higher homologues give more or less of the isomeric nitrous esters.

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  • Nitromethane, CH 3 NO 2, is a colourless oil which boils at 101° C. Fuming sulphuric acid decomposes it into carbon monoxide and hydroxylamine.

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  • The ketone, dihydroxyacetone, CH 2 OH CO CH 2 OH, was obtained by Piloty by condensing formaldehyde with nitromethane, reducing to a hydroxylamino compound, which is oxidized to the oxime of dihydroxyacetone; the ketone is liberated by oxidation with bromine water: 3H CHO + CH 3 NO 2 -- (CH 2 OH) 3 C NO 2 - (CH 2 OH) 3 C NH OH -- (CH 2 OH) 2 C: NOH - > (CH20H)2CO.

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