Molecules Sentence Examples
The organism is made up of molecules which are analogous to them.
The preference exhibited by yeast cells for sugar molecules is shared by mould fungi and soluble enzymes in their fermentative actions.
The following table gives a comparative view of the specific heats and the ratio for molecules of variable atomic content.
We may here mention the synthesis of oxyuvitic ester (5-methyl-4-oxy-I-3-benzene dicarboxylic ester) by the condensation of two molecules of sodium acetoacetic ester with one of chloroform (Ann., 1883, 222, p. 249).
This investigator held that the decomposition of the sugar molecules takes place outside the cell wall.
Thus, the symbols 14 2 and P4 indicate that the molecules of hydrogen and phosphorus respectively contain 2 and 4 atoms. Since, according to the molecular theory, in all cases of chemical change the action is between molecules, such symbols as these ought always to be employed.
Hence it may be inferred that this value is typical for diatomic molecules.
He showed that the heat motion of particles, which is too small to be perceptible when these particles are large, and which cannot be observed in molecules since these themselves are too small, must be perceptible when the particles are just large enough to be visible and gave complete equations which enable the masses themselves to be deduced from the motions of these particles.
In the experiment imagined by Lord Rayleigh a porous diaphragm takes the place of the partition and trap-doors imagined by Clerk Maxwell, and the molecules sort themselves automatically on account of the difference in their average velocities for the two gases.
In such experiments the molecular energy of a gas is converted into work only in virtue of the molecules being separated into classes in which their velocities are different, and these classes then allowed to act upon one another through the intervention of a suitable heat-engine.
AdvertisementBut Buffon further imagined that innumerable "molecules organiques " are dispersed throughout the world, and that alimentation consists in the appropriation by the parts of an.
The " molecules organiques " are physical equivalents of Leib nitz's " monads."
These colour changes are connected with a dissociation of the molecules.
Changes of the first and second kind, according to our views of the constitution of molecules, are probably of very rare occurrence; in fact, chemical action appears almost always to involve the occurrence of both these kinds of change, for, as already pointed out, we must assume that the molecules of hydrogen, oxygen and several other elements are diatomic, or that they consist of two atoms. Indeed, it appears probable that with few exceptions the elements are all compounds of similar atoms united together by one or more units of affinity, according to their valencies.
We may suppose that in the formation of gaseous hydrochloric acid from gaseous chlorine and hydrogen, according to the equation H2 +C1 2 = HCI+HC1, a certain amount of energy is expended in separating the atoms of hydrogen in the hydrogen molecule, and the atoms of chlorine in the chlorine molecule, from each other; but that heat is developed by the combination of the hydrogen atoms with the chlorine atoms, and that, as more energy is developed by the union of the atoms of hydrogen and chlorine than is expended in separating the hydrogen atoms from each other and the chlorine atoms from one another, the result of the action of the two elements upon each other is the development of heat, - the amount finally developed in the reaction being the difference between that absorbed in decomposing the elementary molecules and that developed by the combination of the atoms of chlorine and hydrogen.
AdvertisementNo work is done in separating the parts of the molecules from each other.
These natural philosophers suggested that equal volumes of all gaseous substances must contain, at the same temperature and pressure, the same number of molecules.
The gradual accumulation of data referring to organic compounds brought in its train a revival of the discussion of atoms and molecules.
A freedom of interchange is thus indicated between the opposite parts of the molecules of salts in solution, and it follows reasonably that with the solution of a single salt, say sodium chloride, continual interchanges go on between the sodium and chlorine parts of the different molecules.
He pointed out that it followed that the electric forces did not cause the interchanges between the opposite parts of the dissolved molecules but only controlled their direction.
AdvertisementInterchanges must be supposed to go on whether a current passes or not, the function of the electric forces in electrolysis being merely to determine in what direction the parts of the molecules shall work their way through the liquid and to effect actual separation of these parts (or their secondary products) at the electrodes.
This result again indicates that the parts of the molecules are effectively separate from each other, the function of the electric forces being merely directive.
On the right, towards which the faster ion travels, five molecules of salt are left, being a loss of two from the original seven.
On the left, towards which the slower ion moves, only three molecules remain - a loss of four.
For instance, to take the two solutions to which we have already referred, we have of ions between molecules at the instants of molecular collision only; during the rest of the life of the ions they were regarded as linked to each other to form electrically neutral molecules.
AdvertisementLet x be the number of molecules which dissociate per second when the number of undissociated molecules in unit volume is unity, then in a dilute solution where the molecules do not interfere with each other, xp is the number when the concentration is p. Recombination can only occur when two ions meet, and since the frequency with which this will happen is, in dilute solution, proportional to the square of the ionic concentration, we shall get for the number of molecules re-formed in one second ye where q is the number of dissociated molecules in one cubic centimetre.
If µ be the molecular conductivity, and its value at infinite dilution, the fractional number of molecules dissociated is k /µop, which we may write as a.
The number of undissociated molecules is then I - a, so that if V be the volume of the solution containing I gramme-molecule of the dissolved substance, we get q= and p= (I - a)/V, hence x(I - a) V =yd/V2, and constant = k.
Van 't Hoff's formula is equivalent to taking the frequency of dissociation as proportional to the square of the concentration of the molecules, and the frequency of recombination as proportional to the cube of the concentration of the ions.
An explanation of the failure of the usual dilution law in these cases may be given if we remember that, while the electric forces between bodies like undissociated molecules, each associated with equal and opposite charges, will vary inversely as the fourth power of the distance, the forces between dissociated ions, each carrying one charge only, will be inversely proportional to the square of the distance.
The forces between the ions of a strongly dissociated solution will thus be considerable at a dilution which makes forces between undissociated molecules quite insensible, and at the concentrations necessary to test Ostwald's formula an electrolyte will be far from dilute in the thermodynamic sense of the term, which implies no appreciable intermolecular or interionic forces.
As the concentration is increased and un-ionized molecules are formed, a change in temperature begins to affect the ionization as well as the fluidity.
In the case of weaker acids, the dissociation of which is less complete, divergences from this constant value will occur, for some of the molecules have to be separated into their ions.
According to the molecular theory, diffusion is due to the motion of the molecules of the dissolved substance through the liquid.
When the dissolved molecules are uniformly distributed, the osmotic pressure will be the same everywhere throughout the solution, but, if the concentration vary from point to point, the pressure will vary also.
In the case of nonelectrolytes and of all non-ionized molecules this analogy completely represents the facts, and the phenomena of diffusion can be deduced from it alone.
The specific rotation also varies with the concentration; this is due to the dissociation of complex molecules into simpler ones, a view confirmed by cryoscopic measurements.
The properties of caoutchouc clearly show, however, that its actual molecular structure is considerably more complex than is represented by the empirical formula, and that it is to be regarded as the polymer of a terpene or similar hydrocarbon and composed of a cluster of at least ten or twenty molecules of the formula C5H8.
Caoutchouc, like other "unsaturated" molecules, forms compounds with chlorine, bromine, iodine and sulphur.
This result he considered to be due, not to any removal of impurities, but to an actual splitting-up of the yttrium molecule into its constituents, and he ventured to draw the provisional conclusion that the so-called simple bodies are in reality compound molecules, at the same time suggesting that all the elements have been produced by a process of evolution from one primordial stuff or "protyle."
According to this theory the molecules of any magnetizable substance are little permanent magnets the axes of which are, under ordinary conditions, disposed in all possible directions indifferently.
The process of magnetization consists in turning round the molecules by the application of magnetic force, so that their north poles may all point more or less approximately in the direction of the force; thus the body as a whole becomes a magnet which is merely the resultant of an immense number of molecular magnets.
The width of the gap may be diminished until it is no greater than the distance between two neighbouring molecules, when it will cease to be distinguishable, but, assuming the molecular theory of magnetism to be true, the above statement will still hold good for the intermolecular gap. The same pressure P will be exerted across any imaginary section of a magnetized rod, the stress being sustained by the intermolecular springs, whatever their physical nature may be, to which the elasticity of the metal is due.
Weber's theory, the molecules of a ferromagnetic metal are small permanent magnets, the axes of which under ordinary conditions are turned indifferently in every direction, so that no magnetic polarity is exhibited by the metal as a whole; a magnetic force acting upon the metal tends to turn the axes of the little magnets in one direction, and thus the entire piece acquires the properties of a magnet.
If, however, the molecules could turn with perfect freedom, it is clear that the smallest magnetizing force would be sufficient to develop the highest possible degree of magnetization, which is of course not the case.
This represents the condition of the molecules in unmagnetized iron.
Supposing Ewing's hypothesis to be correct, it is clear that if the magnetization of a piece of iron were reversed by a strong rotating field instead of by a field alternating through zero, the loss of energy by hysteresis should be little or nothing, for the molecules would rotate with the field and no unstable movements would be possible.'
The fact being established that magnetism is essentially a molecular phenomenon, the next step is to inquire what is the constitution of a magnetic molecule, and why it is that some molecules are ferromagnetic, others paramagnetic, and others again diamagnetic. The best known of the explanations that have been proposed depend upon the magnetic action of an electric current.
To account for diamagnetism, Weber supposed that there exist within the molecules of diamagnetic substances certain channels around which an electric current can circulate without any resistance.
The strength of the induced current is - HScosO/L, where 0 is the inclination of the axis of the circuit to the direction of the field, and L the coefficient of self-induction; the resolved part of the magnetic moment in the direction of the field is equal to - HS 2 cos 2 6/L, and if there are n molecules in a unit of volume, their axes being distributed indifferently in all directions, the magnetization of the substance will be-3nHS 2 /L, and its susceptibility - 3S 2 /L (Maxwell, Electricity and Magnetism, § 838).
If the structure of the molecule is so perfectly symmetrical that, in the absence of any external field, the resultant magnetic moment of the circulating electrons is zero, then the application of a field, by accelerating the right-handed (negative) revolutions, and retarding those which are left-handed, will induce in the substance a resultant magnetization opposite in direction to the field itself; a body composed of such symmetrical molecules is therefore diamagnetic. If however the structure of the molecule is such that the electrons revolving around its atoms do not exactly cancel one another's effects, the molecule constitutes a little magnet, which under the influence of an external field will tend to set itself with its axis parallel to the field.
Ordinarily a substance composed of asymmetrical molecules is paramagnetic, but if the elementary magnets are so conditioned by their strength and concentration that mutual action between them is possible, then the substance is ferromagnetic. In all cases however it is the diamagnetic condition that is initially set up - even iron is diamagnetic - though the diamagnetism may be completely masked by the superposed paramagnetic or ferromagnetic condition.
It crystallizes in prisms with four molecules of water; when.
The acid salts are obtained by the addition of one molecule of alkali to two molecules of the acid in concentrated alcoholic solution at a low temperature.
It abolished the conception of life s an entity above and beyond the common properties of matter, and led to the conviction that the marvellous and exceptional qualities of that which we call " living " matter are nothing more nor less than an exceptionally complicated development of those chemical and physical properties which we recognize in a gradually ascending scale of evolution in the carbon compounds, containing nitrogen as well as oxygen, sulphur and hydrogen as constituent atoms of their enormous molecules.
A process of waste resulting from the decomposition of the molecules of the protoplasm, in virtue of which they break up into more highly oxidated products, which cease to form any part of the living body, is a constant concomitant of life.
In either case, the addition of molecules to those which already existed takes place, not at the surface of the living mass, but by interposition between the existing molecules of the latter.
By chemical warnings the defensive processes seem to be awakened, or summoned; and when we think of the infinite variety of such possible phases, and of the multitude of corresponding defensive agents, we may form some dim notion of the complexity of the animal blood and tissues, and within them of the organic molecules.
Chemical, physiological and pathological research is exploring the secret of these more refined kinds of "anchorage" of molecules.
Fraser proved that by substitution of molecules in certain compounds a stimulant could be converted into a sedative action; thus by the addition of the methyl group CH 2 to the molecule of strychnine, thebaine or brucine, the tetanizing action of these drugs is converted into a paralysing action.
Now, what is remarkable in these and many other reactions is not only that effects apparently very opposite may result from minute differences of molecular construction, but also that, whatever the construction, agents, not wholly indifferent to the body or part, tend to anchor themselves to organic molecules in some way akin to them.
On the other hand, the reagents by which such modifications are apt to be produced are not necessarily simple; many of them likewise are known to be of very high degrees of complexity, approaching perhaps in complexity the molecules to which they are akin.
Of such probably are the toxins and antitoxins of certain infections, which, anchoring themselves not by any means indiscriminately, but to particular and concerted molecules, by such anchorage antagonize them or turn them to favourable or unfavourable issues.
The first term includes simple sugars containing two to nine atoms of carbon, which are known severally as bioses, trioses, tetroses, pentoses, hexoses, &c.; whilst those of the second group have the formula C12H22011 and are characterized by yielding two monosaccharose molecules on hydrolysis.
On reduction it yields an inactive mixture of galactonic acids, some molecules being attacked at one end, as it were, and an equal number of others at the other.
Those substituted in the benzene nucleus are obtained by condensing two molecules of a substituted benzyl and benzal chlorides.
The salt crystallizes out on cooling with 7 molecules of water, forming colourless orthorhombic prisms, usually small and needle-shaped.
This view, which was specially supported by Gay-Lussac and Leopold Gmelin and accepted by Berzelius, necessitated that all acids were monobasic. The untenability of this theory was proved by Thomas Graham's investigation of the phosphoric acids; for he then showed that the ortho- (ordinary), pyroand metaphosphoric acids contained respectively 3, 2 and I molecules of " basic water " (which were replaceable by metallic oxides) and one molecule of phosphoric oxide, P2 05.
In the cases of aluminium dissolved in tin and of mercury or bismuth in lead, it is at least probable that the molecules in solution are Al 2j Hg 2 and Bit respectively, while tin in lead appears to form a molecule of the type Sn4.
It mixes with water in all proportions, the mixing being attended by a contraction in volume and a rise in temperature; the maximum contraction corresponds to a mixture of 3 molecules of alcohol and I of water.
In the case of imperfect gases, all the available experimental evidence shows that the specific volume tends towards its ideal value, V =Re/p, in the limit, when the pressure is indefinitely reduced and the molecules are widely separated so as to eliminate the effects of their mutual actions.
The energy is less than that of an ideal gas by the term npc. If we imagine that the defect of volume c is due to the formation of molecular aggregates consisting of two or more single molecules, and if the kinetic energy of translation of any one of these aggregates is equal to that of one of the single molecules, it is clear that some energy must be lost in co-aggregating, but that the proportion lost will be different for different types of molecules and also for different types of co-aggregation.
If two monatomic molecules, having energy of translation only, equivalent to 3 degrees of freedom, combined to form a diatomic molecule with 5 degrees of freedom, the energy lost would.
If two diatomic molecules, having each 5 degrees of freedom, combine to form a molecule with 6 degrees of freedom, we should have n = 2, or the energy lost would be 2pc per unit mass.
If the molecules and molecular aggregates were more complicated, and the number of degrees of freedom of the aggregates were limited to 6, or were the same as for single molecules, we should have n-= so/R.
The loss of energy could not be greater than this on the simple kinetic theory, unless there were some evolution of latent heat of co-aggregation, due to the work done by the mutual attractions of the co-aggregating molecules.
It is not necessary to suppose that the co-aggregated molecules are permanently associated.
In air of considerable density the mean free path of a molecule, between its collisions with other molecules, is exceedingly small, and any such increase of gaseous pressure in front of the black surface would be immediately neutralized by flow of the gas from places of high to places of low pressure.
The general nature of the phenomena is thus easily understood; but it is at a maximum at pressures comparable with a millimetre of mercury, at which the free path is still small, the greater number of molecules operating in intensifying the result.
The hypothesis that the state was steady, so that interchanges arising from convection and collisions of the molecules produced no aggregate result, enabled him to interpret the new constants involved in this law of distribution, in terms of the temperature and its spacial differential coefficients, and thence to express the components of the kinetic stress at each point in the medium in terms of these quantities.
As far as the order to which he carried the approximations - which, however, were based on a simplifying hypothesis that the molecules influenced each other through mutual repulsions inversely as the fifth power of their distance apart--the result was that the equations of motion of the gas, considered as subject to viscous and thermal stresses, could be satisfied by a state of equilibrium under a modified internal pressure equal in all directions.
Reynolds, in his investigation, introducing no new form of law of distribution of velocities, uses a linear quantity, proportional to the mean free path of the gaseous molecules, which he takes to represent (somewhat roughly) the average distance from which molecules directly affect, by their convection, the state of the medium; the gas not being uniform on account of the gradient of temperature, the change going on at each point is calculated from the elements contributed by the parts at this particular distance in all directions.
There must be considerable dissociation of molecules, and as a first approximation it may be taken that of io molecules of most of the components about 9 (or in the case of magnesium sulphate 5) have been separated into their ions, and that it is only during slow concentration as in a natural saline that the ions combine to produce the various salts in the proportions set out in the above table.
The doctrine that matter can be divided into, or regarded as composed of, discrete particles (termed " atoms " by early writers, and " molecules " by modern ones) has at all times played an important part in metaphysics and natural science.
For instance, if oxygen and hydrogen combine to form water, we have no experimental evidence that the molecule of oxygen is not in the very same place with the two molecules of hydrogen.
It ought accordingly to be possible to explain all the non-electrical and non-chemical properties of matter by treating matter as an aggregation of molecules.
The best estimates which we now possess of the sizes of molecules are provided by calculations based upon the kinetic theory of gases.
In the following table are given the values of the diameters of the molecules of six substances with which it is easy to experiment in the gaseous state, these values being calculated in different ways from formulae supplied by the kinetic theory.
An essential feature of the modern view of the structure of matter is that the molecules are supposed to be in rapid motion relatively to one another.
Thus the molecules of a solid must make only small excursions about their mean positions.
In a gas the state of things is very different; an odour is known to spread rapidly through great distances, even in the stillest air, and a gaseous poison or corrosive will attack not only those objects which are in contact with its source but also all those which can be reached by the motion of its molecules.
As a preliminary to examining further into the nature of molecular motion and the differences of character of this motion, let us try to picture the state of things which would exist in a mass of solid matter in which all the molecules are imagined to be at rest relatively to one another.
The fact that a solid body in its natural state is capable both of compression and of dilatation indicates that the molecules of the body must not be supposed to be fixed rigidly in position relative to one another; the further fact that a motion of either compression or of dilatation is opposed by forces which are brought into play in the interior of the solid suggests that the position of rest is one in which the molecules are in stable equilibrium under their mutual forces.
Thus the molecular theory of matter, as we have now pictured it, leads us to identify heat-energy in a body with the energy of motion of the molecules of the body relatively to one another.
A body in which all the molecules were at rest relatively to one another would be a body devoid of heat.
The molecules of the two surface-layers will exert forces upon one another, so that, when the rubbing takes place, each layer will set the molecules of the other into motion, and the energy of rubbing will be used in establishing this heat-motion.
At first the heat-motion will be confined to molecules near the rubbing surfaces of the two bodies, but, as already explained, these will in time set the interior molecules into motion, so that ultimately the heat-motion will become spread throughout the whole mass.
When the molecules are oscillating about their equilibrium positions, there is no reason why their mean distance apart should be the same as when they are at rest.
Suppose for instance that two molecules, when at rest in equilibrium, are at a distance a apart.
A body made up of molecules of this kind will expand on heating.
As the temperature of a body increases the average energy of the molecules will increase, and therefore the range of their excursions from their positions of equilibrium will increase also.
The substance attains to a perfectly liquid state as soon as the energy of motion of the molecules is such that there is a constant rearrangement of position among them.
A molecule escaping from its original position in a body will usually fall into a new position in which it will be held in equilibrium by the forces from a new set of neighbouring molecules.
The body is continually losing mass by the loss of individual molecules in this way, and this explains the process of evaporation.
Moreover, the molecules which escape are, on the whole, those with the greatest energy.
The average energy of the molecules of the liquid is accordingly lowered by evaporation.
When a stage is reached such that the number of molecules lost to the liquid by evaporation is exactly equal to that regained by condensation, we have a liquid in equilibrium with its own vapour.
If the whole liquid becomes vaporized before this stage is attained, a state will exist in which the vessel is occupied solely by free molecules, describing paths which are disturbed only by encounters with other free molecules or the sides of the vessel.
It follows that the average distance apart of the molecules in the gaseous state is roughly ten times as great as in the solid or liquid state, and hence that in the gaseous state the molecules are at distances apart which are large compared with their linear dimensions.
A number of molecules moving in obedience to dynamical laws will pass through a series of configurations which can be theoretically determined as soon as the structure of each molecule and the initial position and velocity of every part of it are known.
It is accordingly clear that there can be no property common to all systems, but it can be shown that when the system contains a gas (or any other aggregation of similar molecules) as part of it there are properties which are common to all possible states, except for a number which form an insignificant fraction of the whole.
The second line in E2 will represent the energy (or part of the energy) of s' similar molecules of the second kind, and so on.
It is not at present necessary to suppose that the molecules are those of substances in the gaseous state.
If each of the fractions (3) is put equal to i/4h, it is readily found, from the first property of the normal state, that, of the s molecules of the first kind, a number sal (h3m3 /13)e hm (u2+v2+w2)dudvdw (4) Velocities.
If 2mu 2 denote the mean value of 2mu 2 averaged over the s molecules of the first kind, equations (3) may be written in the form Z mu g = 2 mv 2 = 2 mw 2 = 2x,0 2 1 =.
A simple approximate calculation of the pressure exerted by a gas on its containing vessel can be made by supposing that the molecules are so small in comparison with their distances apart that they may be treated as of infinitesimal size.
Let a mixture of gases contain per unit volume v molecules of the first kind, v' of the second kind, and so on.
The number of molecules of the first kind of gas, whose components of velocity lie within the ranges between u and u+du, v and v+dv, w and w+dw, will, by formula (5), be v?l (h 3 m 3 /7 3)e hm (u2+v2+w2)dudvdw (9) per unit volume.
Each of the molecules enumerated in expression (9) will move parallel to the edge of this cylinder, and each will describe a length equal to its edge in time dt.
Thus each of these molecules which is initially inside the cylinder, will impinge on the area dS within an interval dt.
The cylinder is of volume u dt dS, so that the product of this and expression (9) must give the number of impacts between the area dS and molecules of the kind under consideration within the interval dt.
Thus the contribution to the total impulsive pressure exerted on the area dS in time dt from this cause is mu X udtdS X (11 3 m 3 /,r 3)e hm (u2+v2+w2 )dudvdw (I o) The total pressure exerted in bringing the centres of gravity of all the colliding molecules to rest normally to the boundary is obtained by first integrating this expression with respect to u, v, w, the limits being all values for which collisions are possible (namely from - co too for u, and from - oo to + oo for v and w), and then summing for all kinds of molecules in the gas.
Further impulsive pressures are required to restart into motion all the molecules which have undergone collision.
The aggregate amount of these pressures is clearly the sum of the momenta, normal to the boundary, of all molecules which have left dS within a time dt, and this will be given by expression (pp), integrated with respect to u from o to and with respect to v and w from - oo to +oo, and then summed for all kinds of molecules in the gas.
Clearly the integral is the sum of the values of mu g for all the molecules of the first kind in unit volume, thus p=v mu l +v'm'u 2 +...
T =273, we obtain R =1.35 X Io -16 and this enables us to determine the mean velocities produced by heat motion in molecules of any given mass.
For molecules of known gases the calculation is still easier.
The molecules of gases for which n = o must accordingly be spherical in shape and in internal structure, or at least must behave at collisions as though they were spherical, for they would otherwise be set into rotation by the forces experienced at collisions.
The kinetic energy of the molecules of these gases must contain two terms in addition to those representing translational energy.
We must accordingly suppose that the molecules of gases for which n =2 are of this shape.
Now this is exactly the shape which we should expect to find in molecules composed of two spherical atoms distorting one another by their mutual forces, and all gases for which n=2 are diatomic.
On the other hand, the theory encounters a very serious difficulty in the fact that all molecules possess a great number of possibilities of internal motion, as is shown by the number of distinct lines in their spectra both of emission and of absorption.
Pyrophosphoric acid, 'H' 4 P 2 0 7, is a tetrabasic acid which may be regarded as derived by eliminating a molecule of water between two molecules of ordinary phosphoric acid; its constitution may therefore be written (HO) 2 0P O PO(OH) 2.
In chemistry the term is given to chemical reactions in which a substance decomposes into two or more substances, and particularly to cases in which associated molecules break down into simpler molecules.
Aqueous solutions deposit crystals containing 2, 4 or 6 molecules of water.
Modern theory accepts the deduction, but ascribes the momentum to the revolving ions in the molecules of matter traversed by the light; for the magneto-optic effect is present only in material media.
Long previously Lord Kelvin himself came nearer this view, in offering the opinion that magnetism consisted, in some way, in the angular momentum of the material molecules, of which the energy of irregular translations constitutes.
If the aether were itself constituted of discrete molecules, on the model of material bodies, such transparency would not be conceivable.
To make room for these we have to remember that the atomic nucleus has remained entirely undefined and beyond our problem; so that what may occur, say when two molecules come into close relations, is outside physical science - not, however, altogether outside, for we know that when the vital nexus in any portion of matter is dissolved, the atoms will remain, in their number, and their atmospheres, and all inorganic relations, as they were before vitality supervened.
Our direct knowledge of matter can, however, never be more than a rough knowledge of the general average behaviour of its molecules; for the smallest material speck that is sensible to our coarse perceptions contains myriads of atoms. The properties of the most minute portion of matter which we can examine are thus of the nature of averages.
In the present case the total dielectric contribution to this current works out to be the change per unit time in the electric separation in the molecules of the element of volume, as it moves uniformly with the matter, all other effects being compensated molecularly without affecting the propagation.
In the moist and plastic slate the mineral particles slowly enlarged by the addition of new crystalline molecules.
This was based on the assumption that the medium in which the light is propagated is discontinuous and molecular in character, the molecules being subject to a mutual attraction.
Sellmeier adopted the elastic-solid theory of the ether, and imagined the molecules to be attached to the ether surrounding them, but free to vibrate about their mean positions within a limited range.
Thus the ether within the dispersive medium is loaded with molecules which are forced to perform oscillations of the same period as that of the transmitted wave.
It can be shown mathematically that the velocity of propagation will be greatly increased if the frequency of the light-wave is slightly greater, and greatly diminished if it is slightly less than the natural frequency of the molecules; also that these effects become less and less marked as the difference in the two frequencies increases.
It crystallizes from water in colourless rhombic prisms, containing four molecules of water of crystallization, and possesses a very acid reaction.
The salt crystallizes in large yellow plates, containing three molecules of water of crystallization.
It is only recently that owing to the introduction of carbon tubes heated electrically the excitement of the luminous vibrations of molecules by temperature alone has become an effective method for the study of their spectra even in the case of metals.
When we are trying to bring radiation into connexion with temperature, we must therefore take a sufficiently large group of molecules and compare their average energies with the average radiation.
The question arises whether in a vacuum discharge, in which only a comparatively small proportion of the molecules are affected, we are to take the average radiation of the affected portion or include the whole lot of molecules, which at any moment are not concerned in the discharge at all.
According to present ideas, the wave originates in a disturbance of electrons within the molecules.
But the molecules affected by a spark discharge are not in any sense in equilibrium as regards their partition of energy and the word temperature " cannot therefore be applied to them in the ordinary sense.
If all molecules moved with the velocity of mean square, the line would be drawn out into a band having on the frequency scale a width 2Nv/V, where v is now the velocity of mean square.
In the case of hydrogen rendered luminous in a vacuum tube we may put approximately u equal to 2000 metres per second, if the translatory motion of the luminous molecules is about the same as that at the ordinary temperature.
He finds a remarkable agreement between the theoretical and experimental values, which it would be important to confirm with the more suitable instruments which are now at our disposal, as we might in this way get an estimate of the energy of translatory motion of the luminous molecules.
Experiments which will be discussed in § to seem to show that there is a difference in this respect between the impacts of similar and those of dissimilar molecules.
According to this view the different lines are given out by different molecules, and we should have to take averages over a number of molecules to obtain the complete spectrum just as we now take averages of energy to obtain the temperature.
The facts, as quoted, point to the closeness of the packing of molecules as the factor which always accompanies and perhaps causes the widening of lines.
Increased density at the same temperature means in the first place a reduction of the average distance between the molecules, but it means also a reduction in the mean free path and an increase in the number of impacts.
Assuming for a moment the change to be one of density and leaving out of account the pressure shift, the cases (e) and (f) point to the fact that it is the closeness of packing of similar molecules which is effective, e.g.
But this argument is not conclusive, for though the total number of hydrogen molecules is fixed when the gas is enclosed, yet the number of luminous molecules may vary with the condition.
We have further to consider the possibility of sudden changes of phrase during an encounter between two molecules, and we can easily form an estimate of the amount of apparent widening due to this cause.
Schuster suggested that the proximity of molecules vibrating in the same period might be the cause of the diminished frequency, and suggested that according to this view the shifts would be similar if the increase of density were produced by the presence of molecules of a different kind from those whose lines are being examined.
If the medium which contains the vibration is divided into a sphere equal to k times the molecular vibration outside of which the effects of these molecules may be averaged up, so that its Roy.
The question is complicated by the fact that in the cases which have been observed, the greater portion of the metallic vapour vibrates in an atmosphere of similar molecules, and the static energy of the field is determined by the value of K applicable to the particular frequency.
It would therefore seem to be more appropriate to replace 1 - K- 1 by (2 - I)1112, where j s is the refractive index; but this expression involves the wave propagation for periods coinciding with free periods of the molecules.
The explanation of these facts presents no difficulty, inasmuch as during the sudden discharge which takes place in the absence of a self-induction, the metallic molecules have not sufficient time to diffuse through the spark gap; hence the discharge is carried by the gas in which it takes place.
Hemsalech 1 have measured the velocity with which the luminous molecules are projected from metallic poles when a strong spark is passed through the air interval which separates the poles.
These rays are apparently the trajectories of positively charged particles having masses of the order of magnitude of the gaseous molecules.
Thompson and others have shown however that they contain both neutral and charged molecules in a relative proportion which adjusts itself continuously, so that even neutral molecules may partake of the translatory motion which they gained while carrying a charge.
Applying the reasoning to the case of a homogeneous radiation traversing an absorbing medium, we realize that the mutual disturbances of the molecules by collision or otherwise must bring in the free period of the molecule whatever the incident radiation may be.
This is used as the sulphate, which has the empirical formula of (C15H21N302)2, H 2 SO 4, plus an unknown number of molecules of water.
Tschelinzeff (Ber., 1906, 39, p. 773) considers that they contain two molecules of ether.
With unsaturated alkyl halides the products are only slightly soluble in ether, and two molecules of the alkyl compound are brought into the reaction.
He supposes that aesthesis and tropesis, as rudimentary sensation and will, are the very causes of condensation; that they belong to pyknatoms, to ponderables and imponderables, to chemical atoms and molecules.
If he has any originality, it consists in substituting for the association of ideas the " economy of thinking," by which he means that all theoretical conceptions of physics, such as atoms, molecules, energy, &c., are mere helps to facilitate our consideration of things.
According to him, whatever inferences we make, certain or uncertain, are mere economies of thought, adapting ideas to sensations, and filling out the gaps of experience by ideas; whatever we infer, whether bodies, or molecules, or atoms, or space of more than three dimensions, are all without distinction equally provisional conceptions, things of thought; and " bodies or things are compendious mental symbols for groups of sensations - symbols which do not exist outside thought."
The density of the liquid is MN/V, where N is the number of solvent molecules, and V the total volume of the liquid.
Substituting these values, we find that the relative lowering of vapour pressure in a very dilute solution is equal to the ratio of the numbers of solute and solvent molecules, or (p - p')/p = n/N.
At the limit of dilution, when the concentration of a solution approaches zero, we have seen that thermodynamical theory, verified by experiment, shows that the osmotic pressure has the same value as the gas pressure of the same number of molecules in the same space.
The variation of gases from Boyle's law is represented in the equation of Van der Waals by subtracting a constant b from the total volume to represent the effect of the volume of the molecules themselves.
Callendar is to trace the effect of possible combination of molecules of solute with molecules of the solvent.
These combined solvent molecules are thus removed from existence as solvent, the effective volume of which is reduced to that of the remaining free molecules of solvent.
The greater the number of water molecules attached to one sugar molecule, the less the residual volume, and the greater the theoretical pressure.
Callendar finds that five molecules of water in the case of cane-sugar or two molecules in the case of dextrose are required to bring the curves into conformity with the observations of Berkeley and Hartley, which in fig.
If each molecule of the solute combines with a certain number of molecules of the solvent in such a way as to render them inactive for evaporation, we get a lowering of vapour pressure.
Let us assume that the ratio p/p' of the vapour pressures of the solvent and solution is equal to the ratio of the number of free molecules of solvent to the whole number of molecules in the solution.
If there are n molecules of solute to N of solvent originally, and each molecule of solute combines with a molecule of solvent, we get for the ratio of vapour pressures p/p'=(N - an)/(N - an+n), while the relative lowering of vapour pressure is (p - p')/p=n/(N - an).
On the lines of Poynting's theory of solution, each ion in electrolytes must combine with one or more molecules of solvent.
In yet other solutions, the particles are smaller again, and seem to approach in size the larger molecules of crystalloid substances.
The filtrate, now containing roughly two molecules of alumina to one of soda, is concentrated to the original gravity of 1.45, and employed instead of fresh caustic for the attack of more bauxite; the precipitate is then collected, washed till free from soda, dried and ignited at about looo C. to convert it into a crystalline oxide which is less hygroscopic than the former amorphous variety.
Potassium aluminate, K 2 Al 2 0 4, is obtained in solution by dissolving aluminium hydrate in caustic potash; it is also obtained, as crystals containing three molecules of water, by fusing alumina with potash, exhausting with water, and crystallizing the solution in vacuo.
Its vapour density at temperatures above 750 corresponds to the formula AlCl 3 j below this point the molecules are associated.
It ascends the flow pipe by convection, where its onward journey would speedily end if it were not for the driving force of other molecules of water following, and the suction set up by the gravitation into the boiler of the cooled water by the return pipe.
Traube, Ber., 1882, 15, p. 659); in the oxidation of zinc, lead and copper in presence of water, and in the electrolysis of sulphuric acid of such strength that it contains two molecules of water to one molecule of sulphuric acid (M.
An early step accomplished by Ostwald in this direction is to define ozone in its relation to oxygen, considering the former as differing from the latter by an excess of energy, measurable as heat of transformation, instead of defining the difference as diatomic molecules in oxygen, and triatomic in ozone.
The third most valuable indication which molecular structure gives about these isomers is how to prepare them, for instance, that normal hexane, represented by CH 3 CH 2 CH 2 CH 2 CH 2 CH3, may be obtained by action of sodium on propyl iodide, CH 3 CH 2 CH 2 I, the atoms of iodine being removed from two molecules of propyl iodide, with the resulting fusion.
In this equation a relates to molecular attraction; and it is not improbable that in isomeric molecules, containing in sum the same amount of the same atoms, those mutual attractions are approximately the same, whereas the chief difference lies in the value of b, that is, the volume occupied by the molecule itself.
Conduction, however, is generally understood to include diffusion of heat in fluids due to the agitation of the ultimate molecules, which is really molecular convection.
This, however, is merely transferring the properties of matter in bulk to its molecules.
It is much more probable that heat is really the kinetic energy of motion of the molecules, and is passed on from one to another by collisions.
On the kinetic theory the molecules of a gas are relatively far apart and there is nothing analogous to friction between two adjacent layers A and B moving with different velocities.
There is, however, a continual interchange of molecules between A and B, which produces the same effect as viscosity in a liquid.
Similarly if A is hotter than B, or if there is a gradient of temperature between adjacent layers, the diffusion of molecules from A to B tends to equalize the temperatures, or to conduct heat through the gas at a rate proportional to the temperature gradient, and depending also on the rate of interchange of molecules in the same way as the viscosity effect.
This, at first sight, paradoxical result is explained by the fact that the mean free path of each molecule increases in the same proportion as the density is diminished, so that as the number of molecules crossing each square centimetre decreases, the distance to which each carries its momentum increases, and the total transfer of momentum is unaffected by variation of density.
If the effects depended merely on the velocity of translation of the molecules, both conductivity and viscosity should increase directly as the square root of the absolute temperature; but the mean free path also varies in a manner which cannot be predicted by theory and which appears to be different for different gases (Rayleigh, Proc. R.S., January 1896).
Certain it is that in the course of the waking day a great number of stimuli play on the sense organs, and through these produce disintegration of the living molecules of the central nervous system.
The simple nature of the alkalies Lavoisier considered so doubtful that he did not class them as elements, which he conceived as substances which could not be further decomposed by any known process of analysis - les molecules simples et indivisibles qui composent les corps.
They may be regarded as the anhydrides of the alcohols, being formed by elimination of one molecule of water from two molecules of the alcohols; those in which the two hydrocarbon radicals are similar are known as simple ethers, and those in which they are dissimilar as mixed ethers.
This Effect Is Probably Due, As Suggested By Rowland, To The Presence Of A Certain Proportion Of Ice Molecules In The Liquid, Which Is Also No Doubt The Cause Of The Anomalous Expansion.
They Also Indicate That It Is Much Larger, And Increases Considerably With Rise Of Temperature, In The Case Of More Condensible Vapours, Such As C1 2J Br 2, Or More Complicated Molecules, Such As Co 2, N 2 0, Nh 3, C 2 H 4.
According To The Elementary Kinetic Theory Of An Ideal Gas, The Molecules Of Which Are So Small And So Far Apart That Their Mutual Actions May Be Neglected, The Kinetic Energy Of Translation Of The Molecules Is Proportional To The Absolute Temperature, And Is Equal To 3/2 Of Pv, The Product Of The Pressure And The Volume, Per Unit Mass.
If The Molecules Are Supposed To Be Like Smooth, Hard, Elastic Spheres, Incapable Of Receiving Any Other Kind Of Energy Except That Of Translation, The Specific Heat At Constant Volume Would Be The Increase Per Degree Of The Kinetic Energy Namely 3Pv/20=3R/2, That At Constant Pressure Would Be 5R/2, And The Ratio Of The Specific Heats Would Be 5/3 Or 1.666.
Boltzmann Suggested That A Diatomic Molecule Regarded As A Rigid Dumb Bell Or Figure Of Rotation, Might Have Only Five Effective Degrees Of Freedom, Since The Energy Of Rotation About The Axis Of Symmetry Could Not Be Altered By Collisions Between The Molecules.
Since Much Smaller Values Are Found For More Complex Molecules, We May Suppose That, In These Cases, The Energy Of Rotation Of A Polyatomic Molecule May Be Greater Than Its Energy Of Translation, Or Else That Heat Is Expended In Splitting Up Molecular Aggregates, And Increasing Energy Of Vibration.
For More Complex Molecules The Radiative And Absorptive Powers Are Known To Be Much Greater.
Two hydrated forms have been described, one containing three molecules of water and the other half a molecule.
It forms hydrates containing one, two, five, six and seven molecules of water.
For example, from the evidence of molar changes due to the obvious parts of bodies, science first comes to believe in molecular changes due to imperceptible particles, and then tries to conceive the ideas of particles, molecules, atoms, electrons.
Raoult (Comptes Rendus, 1886-87) employed other solvents besides water, and showed that the relative lowering for different solvents and different dissolved substances was the same in many cases for solutions in which the ratio of the number of gramme-molecules n of the dissolved substance to the number of molecules N of the solvent was the same, or that it varied generally in proportion to the ratio n/N.
The most important apparent exceptions to Raoult's law in dilute solutions are the cases, (I) in which the molecules of the dissolved substance in solution are associated to form compound molecules, or dissociated to form other combinations with the solvent, in such a way that the actual number of molecules n in the solution differs from that calculated from the molecular weight corresponding to the accepted formula of the dissolved substance; (2) the case in which the molecules of the vapour of the solvent are associated in pairs or otherwise so that the molecular weight m of the vapour is not that corresponding to its accepted formula.
It is assumed that each molecule of solute combines with a molecules of solvent according to the ordinary law of chemical combination, and that the number a, representing the degree of hydration, remains constant within wide limits of temperature and concentration.
In this case the ratio of the vapour-pressure of the solution p" to that of the solvent p' should be equal to the ratio of the number of free molecules of solvent N - an to the whole number of molecules N - an+n in the solution.
The explanation of this relation is that each of the n compound molecules counts as a single molecule, and that, if all the molecules were solvent molecules, the vapour-pressure would be p', that of the pure solvent.
Van't Hoff showed that the osmotic pressure P due to a number of dissolved molecules n in a volume V was the same as would be exerted by the same number of gas-molecules at the same temperature in the same volume, or that PV = ROn.
The highest pressures recorded for cane-sugar are nearly three times as great as those given by van't Hoff's formula for the gas-pressure, but agree very well with the vapour-pressure theory, as modified by Callendar, provided that we substitute for V in Arrhenius's formula the actual specific volume of the solvent in the solution, and if we also assume that each molecule of sugar in solution combines with 5 molecules of water, as required by the observations on the depression of the freezing-point and the rise of the boiling-point.
Employing this type of equation, all the thermodynamical properties of the substance may conveniently be expressed in terms of the diminution of volume c due to the formation of compound or coaggregated molecules, (v - b) =RO/p - co(Oo/O) n =V - c. .
The approximate equation of Rankine (23) begins to be I or 2% in error at the boiling-point under atmospheric pressure, owing to the coaggregation of the molecules of the vapour and the variation of the specific heat of the liquid.
It is equivalent, as Callendar (loc. cit.) points out, to supposing that the variation of the specific heat is due to the formation and solution of a mass w/(v-w) of vapour molecules per unit mass of the liquid.
The salt forms large monoclinic prisms; molecules containing 25 and 21 H 2 O separate from solutions crystallized at higher temperatures.
It forms dark blue prismatic crystals containing 3, 4, or 6 molecules of water according to the temperature of crystallization.
In 1855, reviewing the various substances that had been obtained from glycerin, he reached the conclusion that glycerin is a body of alcoholic nature formed on the type of three molecules of water, as common alcohol is on that of one, and was thus led (1856) to the discovery of the glycols or diatomic alcohols, bodies similarly related to the double water type.
A saturated solution of the hydroxide deposits on cooling a hydrated form Ba(OH) 2.8H 2 0, as colourless quadratic prisms, which on exposure to air lose seven molecules of water of crystallization.
Borax crystallizes with ten molecules of water, the composition of the crystals being Na2B407+10H20.
Various attempts have also been made to deduce these laws from particular hypotheses as to the action between the molecules of the elastic substance.
The second part endeavours to deduce the facts of the elasticity of a finite portion of the substance from hypotheses as to the motion of its constituent molecules and the forces acting between them.
Laplace assumed that the liquid has uniform density, and that the attraction of its molecules extends to a finite though insensible distance.
The pressure at any point of the liquid arises from two causes, the external pressure P to which the liquid is subjected, and the pressure arising from the mutual attraction of its molecules.
If we suppose that the number of molecules within the range of the attraction of a given molecule is very large, the part of the pressure arising from attraction will be proportional to the square of the number of molecules in unit of volume, that is, to the square of the density.
It consists in all probability of disturbance, by means of the chemical affinities of the toxin, of the highly complicated molecules of living cells.
In fact, organic molecules can be divided into two classes according as they give rise to anti-substances or fail to do so.
The molecules which lead to the production of anti-substances are usually known as antigens, and each antigen has a specific combining affinity for its corresponding anti-substance, fitting it as a lock does a key.
Kanthack and Cobbett, that in certain instances the toxin can be made to pass through a gelatine membrane, whereas the antitoxin cannot, its molecules being of larger size.
This result, which is usually known now as the " Ehrlich phenomenon," was explained by him on the supposition that the " toxin " does not represent molecules which are all the same, but contains molecules of different degrees of combining affinity and of toxic action.
Accordingly, the most actively toxic molecules will be neutralized first, and those which are left over, that is, uncombined with antitoxin, will have a weaker toxic action.
We are probably safe in saying, however, that the molecules of a toxin are not identical but vary in the degree of their combining affinities, and also in their toxic action, and that, while in some cases the combination of anti-substances has been shown to be reversible, we are far from being able to say that this is a general law.
The' side-chains constitute the means by which other molecules are added to the living molecule, e.g.
It is by means of such side-chains that toxin molecules are attached to the protoplasm, so that the living molecules are brought under the action of the toxophorous groups of the toxins.
Ultimately the regeneration becomes an over-regeneration and free side-chains produced in excess are set free and appear in the blood as antitoxin molecules.
In other words the substances, which when forming part of the cells fix the toxin to the cells, constitute antitoxin molecules when free in the serum.
Wassermann and Takaki in the case of tetanus, that there do exist in the nervous system molecules with combining affinity for the tetanus toxin.
Further, these molecules in the nervous system present the same susceptibility to heat and other physical agencies as does tetanus antitoxin.
There is therefore strong evidence that antitoxin molecules do exist as part of the living substance of nerve cells.
The explanation is thus carried back to the complicated constitution of biogen molecules in various living cells of the body.
We are, accordingly, justified in definitely concluding that their appearance in large amount in the blood, as the result of active immunization, represents an increased production of molecules which are already present in the body, either in a free condition in its fluids or as constituent elements of its cells.
The phenomenon of agglutination depends essentially on the union of molecules in the bacteria - the agglutinogens - with the corresponding agglutinins, but another essential is the presence of a certain amount of salts in the fluid, as it can be shown that when agglutinated masses of bacteria are washed salt-free the clumps become resolved.
Natural immunity against toxins must be taken into account, and, if Ehrlich's view with regard to toxic action be correct, this may depend upon either the absence of chemical affinity of the living molecules of the tissues for the toxic molecule, or upon insensitiveness to the action of the toxophorous group. It has been shown with regard to the former, for example, that the nervous system of the fowl, which possesses immunity against tetanus toxin, has little combining affinity for it.
It can be prepared from dibrom-menthone (obtained by brominating menthone in chloroform solution) by eliminating two molecules of hydrobromic acid.
It is in fact an impossibility that loss should go on without regeneration, for if any part of the sun's body loses heat, it will be unable to support the pressure of neighbouring parts upon it; it will therefore be compressed, in a general sense towards the sun's centre, the velocities of its molecules will rise, and its temperature will again tend upwards.
Larmor suggests is due to relaxation of the spring of the surrounding ether by reason of the crowding of the molecules; a shift of 0.17 tenth-metres would, if interpreted by Doppler's principle, have been read as a receding velocity of I I km.
C ALLOXANTIN $ H 4 N 4 0 7.3H 2 0, a product obtained by the combination of alloxan and dialuric acid, probably possessing the constitution NH - CO CO - NH O - O - H NH - C CO - NH one of the three molecules of water being possibly constitutional.
The term "perfect gas" is applied to an imaginary substance in which there is no frictional retardation of molecular motion; or, in other words, the time during which any molecule is influenced by other molecules is infinitesimally small compared with the time during which it traverses its mean free path.
Ferrous chloride dissolved in strong hydrochloric acid absorbs two molecules of the gas (Kohlschiitter and Kutscheroff, Ber., 1907, 40, p. 873).
In crystals the rotary property appears to be sometimes inherent in the crystalline arrangement of the molecules, as it is lost on fusion or solution, and in several cases belongs to enantiomorphous crystals, the two correlated forms of which are the one right-handed and the other left-handed optically as well as crystallographically, this being necessarily the case if the property be retained when the crystal is fused or dissolved.
Substances that by reason of the structure or arrangement of their molecules rotate the plane of polarization are said to be structurally active, and the rotation produced by unit length is called their rotary power.
It is impossible within brief limits to convey more than a general idea of the work of a philosopher who published more than three hundred original papers bearing upon nearly every branch of physical science; who one day was working out the mathematics of a vortex theory of matter on hydrodynamical principles or discovering the limitations of the capabilities of the vortex atom, on another was applying the theory of elasticity to tides in the solid earth, or was calculating the size of water molecules, and later was designing an electricity meter, a dynamo or a domestic water-tap. It is only by reference to his published papers that any approximate conception can be formed of his life's work; but the student who had read all these knew comparatively little of Lord Kelvin if he had not talked with him face to face.
He proceeded to take off on an explanatory lecture that mentioned anandamides as brain messenger molecules and details about brain chemistry.
The world's smallest abacus now uses individual molecules (13 November 1996 ).
Lectures will include examples of signaling molecules that mediate growth and differentiation of cells and describe how these become aberrant in disease.
Her team recently announced it had created the highest density electronically addressable memory reported to date, a 64-bit memory using molecules as switches.
The dissociated molecules can undergo thermal reactions with neighboring surface atoms or with other adsorbates.
The binding energy of a second layer of adsorbate molecules is similar to the latent heat of sublimation or vaporization of the adsorbate molecules is similar to the latent heat of sublimation or vaporization of the adsorbate.
More generally, over 100 molecules are in development as apoptosis agonists, although approaching 70% of these remain in preclinical development.
For simple organic molecules, including alkanes, alkenes and cycloalkanes, construct appropriate isomeric forms, given a molecular formula 11.
H that hydrocarbon molecules can be cracked to form smaller molecules including alkenes.
Acid dye These molecules are generally sodium salts which dissociate to form the acid dye anion.
Another 21% of the air is oxygen, with the molecules having an atomic weight of 32.
We are developing a new method of screening potentially bioactive molecules which uses a combination of enzymes to select active structures.
To complement genetic approaches we are establishing a confocal based screen for small molecules that interfere with peroxisome biogenesis.
These molecules may be of different chain lengths, and may also have double bonds in some places.
Researchers chemically modified adrenaline to find molecules that would have the same effect in dilating the bronchioles but without the stimulation of the heart.
There, the chlorine released by CFCs destroys the ozone at the rate of 100,000 molecules of ozone per chlorine released by CFCs destroys the ozone at the rate of 100,000 molecules of ozone per chlorine atom.
When a solution of the sample molecule is mixed with a metal colloid the molecules are absorbed onto the surface of the colloids.
Molecules are able to activate chloride conductance in airway cell line, primary human cell cultures and most importantly from cells with CFTR mutations.
The two molecules are virtually identical in their molecular conformation.
A large unknown area in pectin chemistry concerns the possible presence in vivo of covalent cross-links between pectic molecules.
The lack of branching allows molecules to lie close together in a regular way which is almost crystalline.
Here is the spectrum of cytochrome c. The absorption pattern for all three cytochrome c. The absorption pattern for all three cytochromes changes markedly when these molecules are oxidized and reduced.
As mentioned above interferon gamma or molecules able to mimic or induce this cytokine may be of use in the treatment of sepsis.
Briefly, target molecules will be used on bone marrow stem cells in tissue culture to induce specific appropriate differentiation.
For small molecules, it is possible to analyze X-ray diffraction data by means of the direct methods.
Each of the hydrogen atoms in each of the molecules of water in your brain is a tiny magnetic dipole.
Some of these molecules are remarkably durable, surviving as evidence of living tissue that has otherwise completely dispersed.
The molecules which bind to these sites are called effectors.
A powerful electromagnet causes the nuclei of atoms (particularly hydrogen in water molecules) to align magnetically.
Many molecules that are capable of blocking neurite elongation in vitro are present in CNS tissue.
This approach has worked very well for other types of molecules studied in frog embryos.
Also... bond enthalpy values apply to molecules in the gaseous state.
Some functionally equivalent molecules can have between 30 - 50% of their amino acids different.
It would also be necessary to use labeled erythrocytes again to determine if isolated molecules are B.bovis derived.
When sunlight strikes methane molecules they react to form ethane molecules they react to form ethane.
A prime example is provided by sugars, which can be represented as straight-chain molecules or as cyclic ethers.
This approach has, however, remained experimental, and indeed most molecules in development remain in preclinical phases.
Outside the cell, collagen molecules become aligned in parallel formations, and then they link up laterally to form fibrils.
The distended capillaries allow large molecules e.g. fibrinogen, red blood cells, to escape into the interstitial spaces.
A myosin filament contains several hundred myosin molecules in two bundles packed end to end.
New methods of introducing fluorine We continue to seek new methods of introducing fluorine to molecules.
Maybe eventually, we'll also find a way to use the antifreeze molecules to prevent frostbite in humans.
Glassy polymers In a glassy polymers In a glassy polymer, all the molecules are fixed firmly in position.
The dust grains may provide the shelter for molecules to form.
This is the way graphene molecules were " extracted " from bulk graphite.
If the surface is too sticky the component building block molecules won't circulate and find their complementary bonding partners to make the honeycomb.
Infrared spectra show the presence of different types of water molecules and/or hydroxyl ions.
In order to see some of these more clearly, 64 of the 280 water molecules have been removed from the water icosahedron.
Cell adherens junctions are points of cell-cell contact, mediated by the extracellular interactions of cadherin molecules.
To the contrary, paraffin molecules are not polar, this is the reason why paraffin cannot respond to the microwave irradiation.
A high temperature from a match or spark etc., gives the reactant molecules enough kinetic energy to overcome the activation energy * .
Cholesterol travels through the blood in minute packages mixed with large molecules called lipoproteins.
Monday's session focused on describing the roles of signaling molecules at the synapse in regulating worm locomotion.
The relation between bulk properties and the properties of individual atoms and molecules, including macromolecules.
Do n't memorize the molecules, study the patterns.
Liposomes are tiny hollow molecules, measuring just one millionth of a millimeter, which are used to carry drugs to the body.
By tuning the laser wavelength, it is possible to ionize molecules from selected energy levels.
The first problem with drawing organic molecules is that I can't draw.
Difference density maps were used to locate the ordered solvent molecules, which were included in the refinement.
All living organisms consist of cells; spherical aggregates of biological molecules surrounded by a thin membrane.
The molecules thus formed are referred to as polar molecules.
One possibility being tested by the Glasgow lab is that very reactive molecules called free radicals may be involved.
Synchrotron infrared spectroscopy allowed the chemisorption bonds of both surface modifiers and reactant molecules to be probed with high spectral resolution.
These bicarbonate ions immediately latch onto a section of the crocodiles ' hemoglobin molecules, forcing the hemoglobin to release its attached oxygen.
Most of these free radicals are oxygen molecules or atoms.
Understand that the variety of possible small alkene monomer molecules leads to a variety of different polymers with differing properties.
A myosin filament contains several hundred myosin filament contains several hundred myosin molecules in two bundles packed end to end.
This sequence of events requires molecules that respond to electrical energy and then interact with other molecular mechanisms which release the chemical neurotransmitters.
Each strand is made up of a series of small molecules called nucleotides.
Most odors are composed of multiple odorant molecules, and each odorant molecule activates several odorant receptors.
These molecules induce smooth muscle contraction and enhance vascular permeability.
This leaves the cycle, and two of these triose phosphate molecules combine to form one glucose molecule using the glycolysis enzymes in reverse.
And the key to doing that appears to lie in fat molecules called phospholipids.
The data in the graph at the top of the page applies to white phosphorus which contains P 4 molecules.
The method provides a very powerful and widely applicable method for studying the primary photochemistry of small gas phase molecules.
Pineapple stem may combat cancer - Two molecules isolated from an extract of crushed pineapple stem may combat cancer - Two molecules isolated from an extract of crushed pineapple stems have shown promise in fighting cancer growth.
However, few organic compounds react readily with water... Their molecules are mostly much less polar than the very polar water molecule.
This is perhaps the biggest advantage that CDT's light-emitting polymer displays have over their competitors, which use small molecules.
The inability of the planar molecules to stack up would prevent polymerization from taking place.
This resetting of the hypothalamus is usually caused by small molecules called pyrogens in the blood.
We must reject the reductionism that gives priority to molecules over cells and cells over organisms and organisms over populations.
The purple bacteria evolved oxygen respiration by reversing the flow of molecules through their carbon fixing pathways and modifying their electron transport chains.
The molecular sieve with very large surface area accumulates water molecules from the gas stream.
The enzymes break down large molecules into smaller ones so the food becomes soluble.
Hydrogen fluoride is very soluble due to hydrogen bonding with water molecules.
This means that polar molecules dissolve well in polar solvents - and what better polar solvent than water!
Without iron the hemoglobin molecules cannot carry oxygen and the tissues of the body become oxygen starved.
Fluid Friction Occurs between the molecules of a gas or liquid in motion, and is expressed as shear stress.
The first image below shows the structure of part of the hamster and mouse PrPc molecules superimposed.
In this movie you get interleaved the fragments that superpose well and the full superposed molecules.
Nearly all molecules synthesized by living organisms are optically active.
Antigenic molecules will be chemically synthesized from peptides on a ' scaffold ' to help hold them in a correct position.
Each filament is made up of many molecules of a protein called tau.
Abstract thiourea inclusion compounds comprise a thiourea host structure containing one-dimensional (1D) tunnels within which guest molecules are accommodated.
Studies have shown that three uncoating ATPase molecules will bind to one clathrin triskelion in the absence of ATP.
These small molecules pass through the renal tube (coiled tubule) which is surrounded by a capillary network.
Also singly linked water molecules involve greater (energetically unfavorable) rearrangements in the surrounding water.
These techniques have led to new insight into how several relatively unstudied molecules undergo such dynamic exchange.
The increased kinetic motion of some receiving molecules should become vigorous enough to dislodge electrons.
Petroleum solvents are used to soften the wax into a spreadable paste, by preventing the individual molecules from bonding together.
It is evident that these laws all follow from the idea that a compound molecule can only alter through the addition or subtraction of one or more complete atoms, together with the idea that all the molecules in a pure substance are alike.
But, unfortunately, the assumption as to the number of atoms in the molecules of these two compounds was an arbitrary one, based on no valid evidence.
The superiority of this notation over that of Dalton is not so obvious when we consider such simple cases as the above, but chemists are now acquainted with very complex molecules containing numerous atoms; cane sugar, for example, has the formula C 12 H 22 0, 1.
This principle at once enables the weights of molecules to be compared even when their composition is unknown; it is only 1 It will be seen that in the three gas diagrams of Dalton that are reproduced above, equal numbers of molecules are contained in equal volumes, but if Dalton held this view at one time he certainly afterwards abandoned it.
It may be remarked that it is only the constant part of sky-light that can be due to detached molecules.
From the condensation of two molecules of ethyl borate with one molecule of zinc ethyl the compound B2 C2H5.
If, on the other hand, we have to deal with a system of molecules of whose motions in the aggregate we become conscious only by indirect means, while we know absolutely nothing either of the motions or positions of any individual molecule, it is obvious that we cannot grasp single molecules and control their movements so as to derive the full amount of work from the system.
So far back as 1850 he also suggested a view which, in a modified form, is of fundamental importance in the modern theory of ionic dissociation, for, in a paper on the theory of the formation of ether, he urged that in an aggregate of molecules of any compound there is an exchange constantly going on between the elements which are contained in it; for instance, in hydrochloric acid each atom of hydrogen does not remain quietly in juxtaposition with the atom of chlorine with which it first united, but changes places with other atoms of hydrogen.
In common with physics it includes the determination of properties or characters which serve to distinguish one substance from another, but while the physicist is concerned with properties possessed by all substances and with processes in which the molecules remain intact, the chemist is restricted to those processes in which the molecules undergo some change.
For instance if the reaction 2112+02=1120+1120 be true, the molecules of water should be different, for a negative oxygen atom would combine in one case, and a positive oxygen atom in the other.
His terminology was vague and provoked caustic criticism from Berzelius; he assumed that all molecules contained two atoms, and consequently the atomic weights deduced from vapour density determinations of sulphur, mercury, arsenic, and phosphorus were quite different from those established by gravimetric and other methods.
Many diketo compounds suffer condensation between two molecules to form hydrobenzene derivatives; thus a, 7 -di-acetoglutaric ester, C 2 H S O 2 C(CH 3 CO) CH CH 2 CH(CO CH 3)CO 2 C 2 H 5, yields a methylketohexamethylene,whiles-acetobutyric ester,CH 3 CO (CH2)2C02C2N5, is converted into dihydroresorcinol or m-diketohexamethylene by sodium ethylate; this last reaction is reversed by baryta (see Decompositions of Benzene Ring).
For succinosuccinic ester, formed by the action of sodium on two molecules of succinic ester, has either of the formulae (I) or (II); oxidation of the free acid gives dioxyterephthalic acid in which the para-positions must remain substituted as in (I) and (II).
If, however, two compounds only differ with regard to the spatial arrangement of the atoms, the physical properties may be (I) for the most part identical, differences, however, being apparent with regard to the action of the molecules on polarized light, as is the case when the configuration is due to the presence of an asymmetric atom (optical isomerism); or (2) both chemical and physical properties may be different when the configuration is determined by the disposition of the atoms or groups attached to a pair of doubly-linked atoms, or to two members of a ring system (geometrical isomerism or allo-isomerism).
The abnormal specific heats of the halogen elements may be due to a loosening of the atoms, a preliminary to the dissociation into monatomic molecules which occurs at high temperatures.
It is this wide range of dynamic peculiarities above the common range of known physical and chemical molecules which excites our wonder; and a reflection of these peculiar properties is seen in their affinities for this or that toxic or constructive agent, whereby the peculiarity, for example, of a particular kind of nerve cell may be altered, antagonized, reinforced or converted.
Meyer, on slightly different assumptions, it should be 41/2 times, the actual volume of the molecules.
The assumption usually made is that the total kinetic energy of the molecules, including possible energy of rotation or vibration if the molecules consist of more than one atom, is proportional to the energy of translation in the case of an ideal gas.
The temperature of a gas is measured by the mean energy of translation of its molecules, which are independent of each other except during the brief intervals of collision; and collision of the separate molecules with the blackened surface of a vane, warmed by the radiation, imparts heat to them, so that they rebound from it with greater velocity than they approached.
He assumed that the distribution of molecules and of their velocities, at each point, was slightly modified, from the exponential law belonging to a uniform condition, by the gradient of temperature in the gas (see Diffusion).
The impact will accordingly result in all the molecules being set into motion, and by the time that the masses have ceased impinging on one another the molecules of which they are composed will be performing oscillations about their positions of equilibrium.
In this expression the first line may be supposed to represent the energy (or part of the energy) of s similar molecules of a kind which we shall call the first kind, the terms 2 (mu 2 +mv 2 +mw 2) being the kinetic energy of translation, and the remaining terms arising from energy of rotation or of internal motion, or from the energy, kinetic and potential, of small vibrations.
For instance, if the system is composed of a gas and a solid boundary, some of the terms in expression (2) may be supposed to represent the kinetic energy of the molecules of the boundary, so that equations (7) show that in the normal state the gas has the same temperature as the boundary.
The presence of this field of force results in the molecules, when they reach the boundary, being acted on by forces in addition to those originating in their impact with the boundary.
Hagen that for dark heat rays of only about ten times the wave-length of luminous radiation, the properties of metals are determined by their electric resistance alone, which then masks all resonance due to periods of free vibration of the molecules; and, moreover, that the resistance for such alternations is practically the same as the ohmic resistance for ordinary steady currents.
That, however, complete conduction should arrive with alternations only ten times slower than light was an unexpected and remarkable fact, which verifies the presumption that the process of conduction is one in which the dynamic activities of the molecules do not come into play.
On this view, the function of the solvent is to give space for the solute to diffuse, and the pressure on a semi-permeable membrane is due to the excess of solvent molecules entering over those leaving in consequence of the smaller number which impinge on the membrane from the side of the solution; the defect in the number must be proportional, roughly at any rate, to the number of solute molecules, present, that is, to the strength of the solution.
Whilst it leaves us with the view that we are a totally insignificant collection of molecules in a purposeless universe.
Putting too many dye molecules close together, however, can lead to the quenching of the fluorescence.
There is now space on the surface of the nickel for new reactant molecules to go through the whole process again.
Fundamentally, what is going on is that replicating molecules ensure their survival by means of phenotypic effects on the world.
A similar treatment may be applied to the recognition sequences for other DNA binding proteins such as repressor molecules.
This occurs at the surface of the drops and depends in part on repulsion between the charges on the molecules.
Chemical shifts in the nuclear magnetic resonance spectra of molecules containing polar groups.
In the rhombohedral crystal, the unit cell contains six molecules of insulin.
Research topics ranging from the fabrication of self-replicating molecules to the study of evolving POPULATION s of computer programs will be included.
He knew where and when the first self-replicating molecules would form, and when the first amphibians would step onto land.
If an acid, e.g. sulphuric acid, is added to such a solution, low molecular silicic acid molecules are formed.
We used the conventional AFM to probe the orientation of the LC molecules in the smectic layers immediately above this adsorbed layer.
In Henry 's Law the solute molecule is surrounded by solvent molecules at the limit.
Molecules in clusters have properties similar to solvated species and cluster studies offer an opportunity of investigating these processes.
This function shows us that the lithium cations are strongly solvated by 4 ammonia molecules.
This means that polar molecules dissolve well in polar solvents - and what better polar solvent than water !
Infrared spectra of the molecule CH 4 - one of at least ten new molecules detected by ISO.
This is compared to a turnover rate of 118 substrate molecules per second in solution.
In more recent research, we have been studying molecules that are involved in extracellular regulation of TGF- b superfamily members.
We are interested in the ways in which the properties of metals and molecules can be tailored to produce supramolecular assemblies with interesting properties.
The surface of the particle shows a monolayer of bound surfactant molecules (far right).
Ice is usually composed of a lattice of water molecules arranged with perfect tetrahedral geometry.
Abstract Thiourea inclusion compounds comprise a thiourea host structure containing one-dimensional (1D) tunnels within which guest molecules are accommodated.
An example of the use of simple molecules for directed screening for thrombin inhibitors will be presented.
Expression of several angiogenic growth factors, cytokines and signal transduction molecules was shown to be altered after stroke.
In this Center, ultrashort pulse lasers are used to manipulate atoms and molecules and to generate non-classical radiation using non-linear optical processes.
The uncharged methyl groups of the fatty acid chains that form the phospholipid bilayer have very little attractive force for water molecules.
They also give protein molecules the odd ability to coil and uncoil like tiny, cellular snakes.
That is to say, the water molecules will tend to vibrate at high speed causing a heating or cooking effect.
When bombarded with protons from the Sun, water vapor molecules break up into forms where they react with ozone.
Carbon dioxide molecules absorb radiant heat at a wavelength of 15 microns.
The human body contains specialized cells called macrophages that remove worn-out cells by degrading them to simple molecules for recycling.
All the nutrients required for embryo development are already present within the fertilized egg, stored in the form of yolk protein molecules.
To relate the relative sizes of common organic molecules to structural features (channels) in zeolite crystal structures.
Osmosis is one method of diffusion, which is when molecules distribute themselves evenly.
The chlorine reacts with oxygen, which leads to the chemical process of destroying ozone molecules."
An antioxidant is any substance that can reduce cellular damage caused by oxygen molecules.
These particles are free, or unbound, and bounce around looking for molecules to bind to in order to become complete at the molecular level.
Within the body, substances called antioxidants mop up the free oxygen molecules before they cause damage.
The bleaching chemicals are applied to your teeth for a certain length of time and they gradually remove the stain molecules from the tooth surface.
Free radicals are molecules within your body damaged by a variety of factors.
Protein found in sunflower seeds is most readily processed by the human body when the seeds are in their raw form and the protein molecules remain unaltered by heat.
These byproducts actually aid the human body and are often composed of predigested food molecules your system can utilize easily.
Proteins are formed from about 20 amino acids that combine in different ways to form protein molecules.
J.Crew's raincoats for boys are made from water-resistant, water-repellent nylon and features a special hydrophilic coating, which repels water molecules and protects your little one from the strongest winds.
The metal ring conducts the skin temperature to the liquid crystals, which causes the molecules to move into a new position, depending on the temperature.
According to Gore-tex.com, the pores are roughly 20,000 times smaller than a molecule of water and 700 times larger than the molecules of moisture vapor.
The body readily absorbs these trace minerals when they are bonded to the water molecules.
PreCip® technology produces a textile with a barrier technology that prevents large water molecules from passing through the fabric, but allows small molecules, like skin moisture, to be absorbed.
It can also effect the connective tissue in the body and cause a higher level of production of free radicals (molecules which cause aging and tissue damage).
Human Leukeocytic Antigens (HLA) molecules are found on the surface of human white blood cells and help to coordinate the immune response.
When the wearer is exposed to UV, photochromatic molecules (silver halide or silver chloride) that are deeply embedded in the lens begin to change shape.
When UV exposure ends, the molecules resume their normal shape and lose their ability to absorb light.
Hoya makes the Sungray line, another plastic lens with the photochromic molecules blended into the plastic.
Since half of the surface is covered with highly reflective molecules, about half of the total visible light is reflected away from your eyes.
Flash mirror coatings have reflective molecules spread further apart, so people can partially see your eyes, even though the lens surface is still highly reflective.
The lenses are made with molecules of phosphorylcholine (PC), a substance found in human cells.
Lasting comfort is made possible since the molecules used in the lenses attract and hold in moisture, resulting in lenses less prone to drying out and causing discomfort.
Antibodies are specific proteins the immune system manufactures to bind to corresponding molecules (antigens) on the cell surfaces of foreign organisms in an attempt to render them harmless.
A titer is the serial dilution of antibodies (protein molecules or immunoglobulins produced by the immune system in response to specific disease agents) found in blood serum that determines their level of concentration.
IgM is one of five types of antibodies (protein molecules) produced by the immune system and found in blood.
Cellular respiration, a process by which food molecules are converted into high-energy molecules used as a source of energy, takes place in structures called mitochondria.
It contains glucose, electrolytes, amino acids, and other small molecules found in plasma, but it has very little protein and few cells.
Lactulose is composed of two sugar molecules; galactose and fructose, and should not be administered to patients who require a low galactose diet.
The two main groups are the B cells that have antibody molecules on their surface and T cells that destroy antigens.
Prostaglandins-A group of hormone-like molecules that exert local effects on a variety of processes including fluid balance, blood flow, and gastrointestinal function.
Free radicals are necessary molecules in the body's metabolism, but in excess they can also destroy cells and harm the body.
The x rays that pass through the body strike the photographic plate and interact with silver molecules on the surface of the film.
The mineral nutrients are defined as all the inorganic elements or inorganic molecules that are required for life.
Mucopolysaccharides are long chains of sugar molecules that are essential for building the bones, cartilage, skin, tendons, and other tissues in the body.
Lysosome-A membrane-enclosed compartment in cells, containing many hydrolytic enzymes, where large molecules and cellular components are broken down.
Mucopolysaccharide-A complex molecule made of smaller sugar molecules strung together to form a chain.
When used to assess the brain, it produces a three-dimensional image that shows anatomy and function, including such information as blood flow, oxygen consumption, glucose metabolism, and concentrations of various molecules in brain tissue.
Biosynthesis of heme is a multistep process that begins with simple molecules and ends with a large, complex heme molecule.
Because heme levels remain low, the synthesis pathway continues to churn out precursor molecules in an attempt to correct the heme deficit.
The net effect of this continued production is an abnormal accumulation of precursor molecules and development of some type of porphyria.
These altered protoporphyrin molecules can cause skin damage.
Cytosine and guanine are two of the four molecules, called nucleic acids, that make up DNA.
Globin-One of the component protein molecules found in hemoglobin.
Normal adult hemoglobin has a pair each of alpha-globin and beta-globin molecules.
Hemoglobin A-Normal adult hemoglobin that contains a heme molecule, two alpha-globin molecules, and two beta-globin molecules.
Hemoglobin electrophoresis-A laboratory test that separates molecules based on their size, shape, or electrical charge.
Fetal hemoglobin has a pair of gamma-globin molecules in place of the typical beta-globins of adult hemoglobin.
Retroviruses are composed of RNA molecules instead of DNA, and the only treatable one is the one that causes acquired immune deficiency syndrome (AIDS).
T cells regulate the production of antibodies, which are protein molecules produced as the first line of the immune system's defense against disease-causing organisms.
Normal T cells produce a ligand (a small molecule that links to larger molecules) known as CD40.
Human leuckocyte antigen (HLA)-A group of protein molecules located on bone marrow cells that can provoke an immune response.
They are generally very large molecules composed of strings of smaller building blocks or molecules called amino acids.
Each class of antibody binds to corresponding molecules (antigens) on the cell surfaces of certain foreign organisms or substances, attempting to protect the body against reactions or illness.
Larger drug molecules are more likely to cause allergic reactions than smaller drug molecules.
Unlike most other allergens, such as pollen or mold spores, drug molecules often are too small to be detected by the immune system.
The disaccharides maltose, sucrose, and lactose cannot be absorbed until they have been separated into simple sugar molecules by their corresponding enzymes present in the cells lining the intestinal tract.
As a person breathes CO contaminated air, more and more oxygen transportation sites on the hemoglobin molecules become blocked by CO.
Antibodies are specific proteins (immunoglobulins) manufactured by the immune system to bind to corresponding molecules (antigens) on the cell surfaces of foreign organisms in an attempt to make them harmless.
For example, the network of signaling molecules that normally regulates a person's immune response is disrupted during HIV disease, impairing a person's ability to fight other infections.
Defined in the study of human nutrition as all the inorganic elements or molecules required for life, minerals assist in body functions such as producing energy, growing, and healing.
Immunoglobulins are protein molecules in blood serum that function like antibodies.
Free radicals are molecules that steal electrons from other molecules, turning the other molecules into free radicals and destabilizing the molecules in the body's cells.
Antibodies are capable of binding to identifying molecules (antigens) on the foreign particle.
The color molecules will usually exit the hair between 6 to 12 shampoos.
Trace amounts of peroxide serve to blend the shade evenly and promote the entry of color molecules into the hair's cortex.
They all work the same way, though, even though the molecules are a little different.
Vitamins are organic molecules vital to every day life functions but are not directly produced by the human body.
Current theories focus on finding particular proteins or molecules that lead to the condition.
More specifically, they're molecules that directly counteract the harmful effect of free radicals.
This type of vitamin "piggy-backs" on fat molecules on their way into your system, making them that much more difficult to manage.