By the direct action of hydroxylamine on a methyl alcohol solution of mesityl oxide in the presence of sodium methylate a hydr oxylamino - ketone, diacetone hydroxylamine, (CH 3) 2 C(Nhoh) CH20OCH3,is formed.
Carbon monoxide takes part in the syntheses of sodium formate from sodium hydrate, or soda lime (at 200 0 -2 20 0), and of sodium acetate and propionate from sodium methylate and sodium ethylate at 160 0 -200°.
Well-dried hydroxylamine hydrochloride is dissolved in methyl alcohol and mixed with sodium methylate; a solution of methyldichloramine in absolute ether is then added and an ethereal solution of diazomethane distils over.
It crystallizes in prisms which melt at 121° C. It yields addition compounds with aniline and naphthalene, and combines directly with potassium methylate, sodio-malonic ester and hydrocyanic ester.
Ramsay, Ber., 1877, 10, p. 736); by heating pyrrol with sodium methylate and methylene iodide to 200° C. (M.
Lobry de Bruyn from the hydrochloride, by dissolving it in absolute methyl alcohol and then adding sodium methylate.
They form unstable addition products with sodium ethylate or methylate.
6-trichlor-5-methylpyrimidine by the action of sodium methylate.