Moreover, while methylamine, dimethylamine, and trimethylamine increase in basicity corresponding to the introduction of successive methyl groups, phenylamine or aniline, diphenylamine, and triphenylamine are in decreasing order of basicity, the salts of diphenylamine being decomposed by water.
Methylamine, CH 3 NH 2, occurs in Mercurialis perennis, in bone-oil, and herring brine.
Soc., 1901, 79, p. 828) has resolved benzyl-allyl-phenyl-methylamine iodide by boiling with silver d-camphorsulphonate in a nearly anhydrous mixture of acetone and ethyl acetate.
It is prepared by the action of aqueous or alcoholic solutions of the caustic alkalis on the nitroso-acidyl derivatives of methylamine (such, for example, as nitrosomethyl urethane, NO.
By the action of bleaching powder on methylamine hydrochloride, there is obtained a volatile liquid (methyldichloramine, CH 3 -N C1 2), boiling at 58-60° C., which explodes violently when heated with water, yielding hydrocyanic acid (CH 3 NC1 2 =HCN+2HC1).
When heated with water it is decomposed into carbon dioxide, ammonia, methylamine and acetic acid.
Hydrochloric acid at 200° C. decomposes into oxalic acid, carbon dioxide and methylamine, whilst an alcoholic solution of a caustic alkali gives dimethyl urea and oxalic acid.
Investigation of the cyanic ethers (1848) yielded a class of substances which opened out a new field in organic chemistry, for, by treating those ethers with caustic potash, he obtained methylamine, the simplest organic derivative of ammonia (1849), and later (1851) the compound ureas.
With baryta it yields methylamine, and when heated with concentrated hydrochloric acid to 260° C. it yields methyl chloride and nicotinic acid.
The acetyl compound on reduction yields two of its nitrogen atoms in the form of ammonia and the third in the form of methylamine.