Methyl-iodide Sentence Examples
By passing the vapour of this compound through a red-hot tube, it yields the isomeric a0- pyridylpyrrol, the potassium salt of which with methyl iodide gives a substance methylated both in the pyridine and pyrrol nuclei.
The same methyl iodide gave with potassium cyanide, acetonitril, which was hydrolysed to acetic acid; this must be C(Coch) a H b H c H d.
When methyl iodide is used, nitromethane is the sole product, but the higher homologues give more or less of the isomeric nitrous esters.
Tetramethylammonium iodide, N(CH 3) 4 I, is the chief product obtained by the action of methyl iodide on ammonia (Hofmann).
The amount of methyl alcohol present in wood spirit is determined by converting it into methyl iodide by acting with phosphorus iodide; and the acetone by converting it into iodoform by boiling with an alkaline solution of iodine in potassium iodide; ethyl alcohol is detected by giving acetylene on heating with concentrated sulphuric acid, methyl alcohol, !under the same circumstances, giving methyl ether.Advertisement
Ethylidene succinic acid or isosuccinic acid, CH3 CH(C02H)2, is produced by the hydrolysis of a-cyanpropionic acid and by the action of methyl iodide on sodio-malonic ester.
Silver picrate and methyl iodide yield the methyl ester, which gives with ammonia picramide.
By distilling an alloy of antimony and sodium with mythyl iodide, mixed with sand, trimethyl stibine, Sb(CH 3) 3 i is obtained; this combines with excess of methyl iodide to form tetramethyl stibonium iodide, Sb(CH 3) 4 1.
Narceine, C23H27N08, obtained by the action of potash on the methyl iodide of narcotine, is probably IV.
Para-xylene is obtained when camphor is distilled with zinc chloride, but it is best prepared from para-brom-toluene or dibrombenzene, methyl iodide and sodium.Advertisement
Decker (Ber., 9 5, 38, p. 1144) has found that many ortho substituted quinolines will not combine with methyl iodide owing to steric hindrance, but the difficulty can be overcome in most cases by using methyl sulphate and heating the reaction components to ioo C. for half an hour.
Euler (Ber., 97, 30, 1989) by distilling the addition compound of methyl iodide and 2 3 5-trimethylpyrollidine with caustic potash.
Its derivatives and its relation to benzene had been previously studied by the above and other experimenters, its relation to benzene being first proved experimentally by Cannizzaro and its constitution settled by Fittig and Tollens's synthesis from sodium and a mixture of methyl iodide and brombenzene.