Metavanadate sentence example

metavanadate
  • Vanadium salts may be obtained from mottramite by digesting the mineral with concentrated hydrochloric acid, the liquid being run off and the residue well washed; the acid liquid and the washings are then evaporated with ammonium chloride, when ammonium metavanadate separates.
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  • This is recrystallized and roasted to vanadium pentoxide, which is then suspended in water into which ammonia is passed, when ammonium metavanadate is again formed and may be purified by recrystallization.
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  • The trioxide, V 2 0 3, is formed when the pentoxide is reduced at a red heat in a current of hydrogen, or by the action of oxalic acid on ammonium metavanadate.
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  • The pentoxide, V205, is obtained when ammonium metavanadate is strongly heated, on calcining the sulphide, or by the decomposition of vanadyl trichloride with water.
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  • Ammonium metavanadate is obtained when the hydrated vanadium pentoxide is dissolved in excess of ammonia and the solution concentrated.
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  • Gain (Comptes rendus, 1906, 1 43, p. 823) by calcining ammonium metavanadate and saturating a solution of the resulting oxides with sulphur dioxide; the resulting blue solution (from which a sulphate of composition 2V 2 0 4.3S0 2.10H 2 O can be isolated) is then boiled with water, when sulphur dioxide is liberated and a pale red crystalline powder of hypovanadic acid, H4V205, is precipitated.
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