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ketonic

ketonic Sentence Examples

  • The carbonyl group is not ketonic in character since it yields neither an oxime nor hydrazone.

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  • compounds containing an oxy in addition to an aldehydic or ketonic group) undergo both condensation and oxidation when treated with phenylhydrazine, forming compounds known as osozones; these are of great importance in characterizing the sugars (q.v.).

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  • The remaining oxygen atom is aldehydic or ketonic, for the sugars combine with hydrocyanic acid, hydroxylamine and phenylhydrazine.

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  • p. 2207); and by the action of ammonia on a-halogen ketonic compounds (W.

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  • It unites with aldehydes to form esters of ketonic acids, and with aniline yields anilido-acetic acid.

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  • It crystallizes in deliquescent prisms and melts with partial decomposition at 119-120° C. It behaves as a ketonic acid, being reduced in aqueous solution by sodium amalgam to tartronic acid, and also combining with phenylhydrazine and hydroxylamine.

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  • It also acts in an opposite manner in certain cases, adding the elements of water to compounds; thus, nitriles are converted into acid-amides, and various acetylene derivatives may be caused to yield ketonic derivatives.

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  • CH2 CHz?CU; CO CH 3 CO CH2 from sodio-malonic ester and 0-unsaturated ketones or ketonic esters: /CH, CO (R02C)2CH2+ Ph CH :CH /CH:>; CH(C02R) C07 from aceto-acetic ester and esters of a$-unsaturated acids, followed by elimination of the carboxyl group: CH2 CR', CH 3 CO CH 2.

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  • Pseudopelletierine (methyl granatonine), C9H15N0, an alkaloid of the pomegranate, is a derivative of cyclo-octane, and resembles tropine in that it contains a nitrogen bridge between two carbon atoms. It is an inactive base, and also has ketonic properties.

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  • Certain of these oils consist very largely of hydrocarbons; for example, those of turpentine, citron, thyme, orange, pine-needle, goldenrod (from Solidago canadensis) and cypress, while others contain as their chief constituents various alcoholic and ketonic substances.

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  • LAEVULINIC ACID (3-acetopropionic acid), C 5 H 8 0 3 or CH 3 CO CH 2 CH 2 CO 2 H, a ketonic acid prepared from laevulose, inulin, starch, &c., by boiling them with dilute hydrochloric or sulphuric acids.

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  • H HN CEH?Chch C(Ch3)N.Cs The ketonic esters under like treatment yield oxypyrimidines, whilst if cyanacetic ester be employed then amino-oxypyrimidines are obtained.

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  • The carbonyl group is not ketonic in character since it yields neither an oxime nor hydrazone.

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  • compounds containing an oxy in addition to an aldehydic or ketonic group) undergo both condensation and oxidation when treated with phenylhydrazine, forming compounds known as osozones; these are of great importance in characterizing the sugars (q.v.).

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  • The remaining oxygen atom is aldehydic or ketonic, for the sugars combine with hydrocyanic acid, hydroxylamine and phenylhydrazine.

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  • p. 2207); and by the action of ammonia on a-halogen ketonic compounds (W.

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  • It may also be prepared by oxidizing benzyl alcohol with concentrated nitric acid; by distilling a mixture of calcium benzoate and calcium formate; by the condensation of chlor-oxalic ester with benzene in the presence of aluminium chloride, the ester of the ketonic acid formed being then hydrolysed and the resulting acid distilled: C 6 H 6 +Cl CO Cooc 2 H 5 = C,H5co COOC2H5d-HC1, C 6 H 5 CO 000H =C6H5CHO+C02; by the action of anhydrous hydrocyanic acid and hydrochloric acid on benzene, an aldime being formed as an intermediate product: C 6 H 6 +HCN+HC1= C6H5CH :NH HC1, Benzaldine hydrochloride C 6 H 5 CH: NH HC1+H 2 O =NH4C1+C6H5CHO; and by the action of chromium oxychloride on toluene dissolved in carbon bisulphide (A.

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  • They may also be prepared by the decomposition of ketone chlorides with water; by the oxidation of the tertiary hydroxyacids; by the hydrolysis of the ketonic acids or their esters with dilute alkalis or baryta water (see Aceto-Acetic Ester); by the hydrolysis of alkyl derivatives of acetone dicarboxylic acid, HO 2 C CH 2 CO CHR CO 2 H; and by the action of the Grignard reagent on nitriles (E.

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  • It unites with aldehydes to form esters of ketonic acids, and with aniline yields anilido-acetic acid.

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  • It crystallizes in deliquescent prisms and melts with partial decomposition at 119-120° C. It behaves as a ketonic acid, being reduced in aqueous solution by sodium amalgam to tartronic acid, and also combining with phenylhydrazine and hydroxylamine.

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  • It also acts in an opposite manner in certain cases, adding the elements of water to compounds; thus, nitriles are converted into acid-amides, and various acetylene derivatives may be caused to yield ketonic derivatives.

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  • CH2 CHz?CU; CO CH 3 CO CH2 from sodio-malonic ester and 0-unsaturated ketones or ketonic esters: /CH, CO (R02C)2CH2+ Ph CH :CH /CH:>; CH(C02R) C07 from aceto-acetic ester and esters of a$-unsaturated acids, followed by elimination of the carboxyl group: CH2 CR', CH 3 CO CH 2.

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  • Pseudopelletierine (methyl granatonine), C9H15N0, an alkaloid of the pomegranate, is a derivative of cyclo-octane, and resembles tropine in that it contains a nitrogen bridge between two carbon atoms. It is an inactive base, and also has ketonic properties.

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  • Certain of these oils consist very largely of hydrocarbons; for example, those of turpentine, citron, thyme, orange, pine-needle, goldenrod (from Solidago canadensis) and cypress, while others contain as their chief constituents various alcoholic and ketonic substances.

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