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isomers

isomers Sentence Examples

  • Di-derivatives x x x p v as $ v as s Here we have assumed the substituent groups to be alike; when they are unlike, a greater number of isomers is possible.

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  • This tetrahedral configuration is based on the existence of only one methylene dichloride, two being necessary if the carbon valencies were directed from the centre of a plane square to its corners, and on the existence of two optical isomers of the formula C. A.

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  • Thus in the tri-substitution derivatives six isomers, and no more, are possible when two of the substituents are alike; for instance, six diaminobenzoic acids, C 6 H 3 (NH 2) 2 000H, are known; when all are unlike ten isomers are possible; thus, ten oxytoluic acids, C 6 H 3 -CH 3.

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  • In the case of tetra-substituted compounds, thirty isomers are possible when all the groups are different.

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  • Formula (4) is symmetrical and based on Kekule's formula: it is in full accord with the syntheses and decompositions of the naphthalene nucleus and the number of isomers found.

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  • Typical formulae are (R denoting 0, S or NH): Isomers are possible, for the condensation may be effected on the two carbon atoms symmetrically placed to the hetero-atom; these isomers, however, are more of the nature of internal anhydrides.

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  • It is found that isomers have nearly the same critical volume, and that equal differences in molecular content occasion equal differences in critical volume.

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  • Recent researches have shown that the law originally proposed by Kopp - " That the specific volume of a liquid compound (molecular volume) at its boiling-point is equal to the sum of the specific volumes of its constituents (atomic volumes), and that every element has a definite atomic value in its compounds " - is by no means exact, for isomers have different specific volumes, and the volume for an increment of CH 2 in different homologous series is by no means constant; for example, the difference among the esters of the fatty acids is about 57, whereas for the aliphatic aldehydes it is 49.

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  • In general, isomers boil at about the same temperature, as is shown by the isomeric esters CH1802: Methyl octoate..

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  • A factor of considerable importance in determining boiling-points of isomers is the symmetry of the molecule.

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  • molecular weight, is constant for isomers, and that two atoms of hydrogen were equal to one of carbon, three to one of oxygen, and seven to one of chlorine; but these ratios were by no means constant, and afforded practically no criteria as to the molecular weight of any substance.

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  • Three isomers exist, the orthoand para-compounds being the chief products of the direct nitration of toluene.

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  • Sodium percarbonates of the formulae Na 2 CO 4, Na2C206, Na 2 C05, NaHCO 4 (two isomers) are obtained by the action of gaseous or solid carbon dioxide on the peroxides Na 2 0 2, Na 2 0 3, NaHO 2 (two isomers)in the presence of water at a low temperature (R.Wolffenstein and E.Peltner, Ber., 1908, 41, pp. 275, 280).

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  • It is seen that aldoses and ketoses which differ stereochemically in only the two final carbon atoms must yield the same osazone; and since d-mannose, d-glucose, and d-fructose do form the same osazone (d-glucosazone) differences either structural or stereochemical must be placed in the two final carbon atoms.3 It may here be noticed that in the sugars there are asymmetric carbon atoms, and consequently optical isomers are to be expected.

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  • Thus glucose, containing four such atoms, can exist in 16 forms; and the realization of many of these isomers by E.

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  • The crude cresol obtained from tar cannot be separated into its different constituents by fractional distillation, since the boiling points of the three isomers are very close together.

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  • Pimaric acid closely resembles abietic acid into which it passes when distilled in a vacuum; it has been supposed to consist of three isomers.

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  • The one group included those isomers where the identity in composition was accompanied by identity in molecular weight, i.e.

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  • the vapour densities of the isomers were the same, as in butylene and isobutylene, to take the most simple case; here the molecular conception admits that the isolated groups in which the atoms are united, i.e.

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  • This group of isomers was denominated metamers by Berzelius, and now often "isomers" (in the restricted sense), whereas the term polymerism (Gr.

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  • Consequently, of each pair of isomers we may establish beforehand which is the more stable; either in particular circumstances, a direct change taking place, as, for instance, with maleic acid, which when exposed to sunlight in presence of a trace of bromine, yields the isomeric fumaric acid almost at once, or, indirectly, one may conclude that the isomer which forms under greater heat-development is the more stable, at least at lower temperatures.

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  • Nevertheless, the theoretical possibility, and its realization in many cases, has brought considerations to the front which have recently become of predominant interest; consequently the possible transformations of isomers and polymers will be considered later under the denomination of reversible or dynamical isomerisms.

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  • The constitution of these inorganic isomers is still somewhat questionable; and in addition it seems that polymerism, metamerism and stereoisomerism play a part here, but the general feature is that cobalt and platinum act in them with high valency, probably exceeding four.

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  • Now, in this case, the first definition expresses much better the whole chemical behaviour of ozone, which is that of "energetic" oxygen, while the second only includes the fact of higher vapour-density; but in applying the first definition to organic compounds and calling isobutylene "butylene with somewhat more energy" hardly anything is indicated, and all the advantages of the atomic conception - the possibility of exactly predicting how many isomers a given formula includes and how you may get them - are lost.

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  • The third most valuable indication which molecular structure gives about these isomers is how to prepare them, for instance, that normal hexane, represented by CH 3 CH 2 CH 2 CH 2 CH 2 CH3, may be obtained by action of sodium on propyl iodide, CH 3 CH 2 CH 2 I, the atoms of iodine being removed from two molecules of propyl iodide, with the resulting fusion.

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  • of the two systems of three carbon atoms into a chain of six carbon atoms. But it is not only the formation of different isomers which is included in their constitution, but also the different ways in which they will decompose or give other products.

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  • (Compare Chemistry: Organic.) The above examples may illustrate how, in a general way, chemical properties of isomers, their formation as well as transformation, may be read in the structure formula.

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  • An example may prove this, but before quoting it, the question of determining b must be decided; this results immediately from the above quotation, b being the volume Vat the absolute zero (T =0); so the volume of isomers ought to be compared at the absolute zero.

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  • Now taking the isomers H 3 C CC1 3 (M„ = 108) and C1H 2 C CHC1 2 (M„ = we see the negative chlorine atoms heaped up in the left hand formula, but distributed in the second; the former therefore may be presumed to occupy a larger space, the molecular volume, that is, the volume in cubic centimetres occupied by the molecular weight in grams, actually being 108 in the former, and 103 in the latter case (compare Chemistry: Physical).

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  • An analogous remark applies to the boiling-point of isomers.

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  • Certain investigations on isomerism which have become especially prominent in recent times bear on the possibility of the mutual transformation of isomers.

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  • These laws have the advantage of being applicable to the mutual transformations of isomers, whatever be the nature of the deeper origin, and so bring polymerism, metamerism and polymorphism together.

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  • In ordinary isomers indications of mutual transformation often occur; and among these the predominant fact is that denoted as tautomerism or pseudomerism.

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  • In reality such tautomeric compounds are apparently a mixture of two isomers in equilibrium, and indeed in some cases both forms have been isolated; then one speaks of desmotropy (Gr.

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  • These isomers may frequently be distinguished by the facts that the cis-acids yield anhydrides more readily than the trans-acids, and are generally converted into the trans-acids on heating with hydrochloric acid.

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  • - Two isomers are possible, namely cyclo-hexadiene-i.

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  • Three structural isomers are possible.

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  • Many polymerize readily, or are transformed into isomers by boiling with dilute alcoholic sulphuric acid.

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  • There are three isomers: (1) ortho, or phthalic acid; (2) meta, or isophthalic acid; (3) para, or terephthalic acid.

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  • Candidates should be able to show an understanding of isomerism by predicting some of the structures of the isomers of given higher alkanes.

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  • Both can be formed in cracking pentane or higher alkanes in which various isomers of C 5 H 10 would be formed.

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  • equimolar mixture of the two optical isomers.

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  • geometric isomers.

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  • isomers of linoleic acid.

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  • Where you have isomers, the more branched the chain, the lower the boiling point tends to be.

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  • It's extremely important to draw the isomers correctly.

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  • Drawing structural formulae for the last pair of models gives two possible isomers.

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  • Compounds that have the same formula but differ in their atomic positions, like these two, are called isomers.

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  • For a real PES, there are permutational isomers of each minimum.

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  • Trans and positional isomers are formed during this process, and these are found in depot fat and milk fat.

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  • It is easy to miss geometric isomers in an exam.

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  • For example, there are two structural isomers with the molecular formula C 3 H 7 Br.

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  • I have put models of the chain isomers of pentane here.

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  • There are two functional group isomers of which you need to be aware: alcohols and ethers aldehydes and ketones What is here?

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  • chain isomerism is the type of isomerism you meet in GCSE Chemistry - see the isomers of hexane.

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  • 20, 451, 757) regards molten sulphur as a mixture of two isomers SA and Sµ in dynamic equilibrium, SA being light in colour and mobile, and S, dark and viscous.

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  • This tetrahedral configuration is based on the existence of only one methylene dichloride, two being necessary if the carbon valencies were directed from the centre of a plane square to its corners, and on the existence of two optical isomers of the formula C. A.

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  • Di-derivatives x x x p v as $ v as s Here we have assumed the substituent groups to be alike; when they are unlike, a greater number of isomers is possible.

    0
    0
  • Thus in the tri-substitution derivatives six isomers, and no more, are possible when two of the substituents are alike; for instance, six diaminobenzoic acids, C 6 H 3 (NH 2) 2 000H, are known; when all are unlike ten isomers are possible; thus, ten oxytoluic acids, C 6 H 3 -CH 3.

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  • In the case of tetra-substituted compounds, thirty isomers are possible when all the groups are different.

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  • Simultaneously with the discussions of Kekule, Ladenburg, Claus, Baeyer and others as to the merits of various plane formulae of the benzene complex, there were published many suggestions with regard to the arrangement of the atoms in space, all of which attempted to explain the number of isomers and the equivalence of the hydrogen atoms. The development of stereo-isomerism at the hands of ' Victor Meyer and G.

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  • Formula (4) is symmetrical and based on Kekule's formula: it is in full accord with the syntheses and decompositions of the naphthalene nucleus and the number of isomers found.

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  • Typical formulae are (R denoting 0, S or NH): Isomers are possible, for the condensation may be effected on the two carbon atoms symmetrically placed to the hetero-atom; these isomers, however, are more of the nature of internal anhydrides.

    0
    0
  • It is found that isomers have nearly the same critical volume, and that equal differences in molecular content occasion equal differences in critical volume.

    0
    0
  • Recent researches have shown that the law originally proposed by Kopp - " That the specific volume of a liquid compound (molecular volume) at its boiling-point is equal to the sum of the specific volumes of its constituents (atomic volumes), and that every element has a definite atomic value in its compounds " - is by no means exact, for isomers have different specific volumes, and the volume for an increment of CH 2 in different homologous series is by no means constant; for example, the difference among the esters of the fatty acids is about 57, whereas for the aliphatic aldehydes it is 49.

    0
    0
  • In general, isomers boil at about the same temperature, as is shown by the isomeric esters CH1802: Methyl octoate..

    0
    0
  • A factor of considerable importance in determining boiling-points of isomers is the symmetry of the molecule.

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  • i n general, isomers, i.e.

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  • molecular weight, is constant for isomers, and that two atoms of hydrogen were equal to one of carbon, three to one of oxygen, and seven to one of chlorine; but these ratios were by no means constant, and afforded practically no criteria as to the molecular weight of any substance.

    0
    0
  • Three isomers exist, the orthoand para-compounds being the chief products of the direct nitration of toluene.

    0
    0
  • Sodium percarbonates of the formulae Na 2 CO 4, Na2C206, Na 2 C05, NaHCO 4 (two isomers) are obtained by the action of gaseous or solid carbon dioxide on the peroxides Na 2 0 2, Na 2 0 3, NaHO 2 (two isomers)in the presence of water at a low temperature (R.Wolffenstein and E.Peltner, Ber., 1908, 41, pp. 275, 280).

    0
    0
  • It is seen that aldoses and ketoses which differ stereochemically in only the two final carbon atoms must yield the same osazone; and since d-mannose, d-glucose, and d-fructose do form the same osazone (d-glucosazone) differences either structural or stereochemical must be placed in the two final carbon atoms.3 It may here be noticed that in the sugars there are asymmetric carbon atoms, and consequently optical isomers are to be expected.

    0
    0
  • Thus glucose, containing four such atoms, can exist in 16 forms; and the realization of many of these isomers by E.

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  • Their number is further increased by spatial inversion of the dicarboxylic acids formed on oxidation, followed by reduction; for example: d- and /-glucose yield d-and l-gulose; and also by Lobry de Bruyn and Van Ekenstein's discovery that hexoses are transformed into mixtures of their isomers when treated with alkalis, alkaline earths, lead oxide, &c.

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  • The crude cresol obtained from tar cannot be separated into its different constituents by fractional distillation, since the boiling points of the three isomers are very close together.

    0
    0
  • Pimaric acid closely resembles abietic acid into which it passes when distilled in a vacuum; it has been supposed to consist of three isomers.

    0
    0
  • The one group included those isomers where the identity in composition was accompanied by identity in molecular weight, i.e.

    0
    0
  • the vapour densities of the isomers were the same, as in butylene and isobutylene, to take the most simple case; here the molecular conception admits that the isolated groups in which the atoms are united, i.e.

    0
    0
  • This group of isomers was denominated metamers by Berzelius, and now often "isomers" (in the restricted sense), whereas the term polymerism (Gr.

    0
    0
  • Consequently, of each pair of isomers we may establish beforehand which is the more stable; either in particular circumstances, a direct change taking place, as, for instance, with maleic acid, which when exposed to sunlight in presence of a trace of bromine, yields the isomeric fumaric acid almost at once, or, indirectly, one may conclude that the isomer which forms under greater heat-development is the more stable, at least at lower temperatures.

    0
    0
  • Nevertheless, the theoretical possibility, and its realization in many cases, has brought considerations to the front which have recently become of predominant interest; consequently the possible transformations of isomers and polymers will be considered later under the denomination of reversible or dynamical isomerisms.

    0
    0
  • The constitution of these inorganic isomers is still somewhat questionable; and in addition it seems that polymerism, metamerism and stereoisomerism play a part here, but the general feature is that cobalt and platinum act in them with high valency, probably exceeding four.

    0
    0
  • Now, in this case, the first definition expresses much better the whole chemical behaviour of ozone, which is that of "energetic" oxygen, while the second only includes the fact of higher vapour-density; but in applying the first definition to organic compounds and calling isobutylene "butylene with somewhat more energy" hardly anything is indicated, and all the advantages of the atomic conception - the possibility of exactly predicting how many isomers a given formula includes and how you may get them - are lost.

    0
    0
  • The third most valuable indication which molecular structure gives about these isomers is how to prepare them, for instance, that normal hexane, represented by CH 3 CH 2 CH 2 CH 2 CH 2 CH3, may be obtained by action of sodium on propyl iodide, CH 3 CH 2 CH 2 I, the atoms of iodine being removed from two molecules of propyl iodide, with the resulting fusion.

    0
    0
  • of the two systems of three carbon atoms into a chain of six carbon atoms. But it is not only the formation of different isomers which is included in their constitution, but also the different ways in which they will decompose or give other products.

    0
    0
  • (Compare Chemistry: Organic.) The above examples may illustrate how, in a general way, chemical properties of isomers, their formation as well as transformation, may be read in the structure formula.

    0
    0
  • An example may prove this, but before quoting it, the question of determining b must be decided; this results immediately from the above quotation, b being the volume Vat the absolute zero (T =0); so the volume of isomers ought to be compared at the absolute zero.

    0
    0
  • Now taking the isomers H 3 C CC1 3 (M„ = 108) and C1H 2 C CHC1 2 (M„ = we see the negative chlorine atoms heaped up in the left hand formula, but distributed in the second; the former therefore may be presumed to occupy a larger space, the molecular volume, that is, the volume in cubic centimetres occupied by the molecular weight in grams, actually being 108 in the former, and 103 in the latter case (compare Chemistry: Physical).

    0
    0
  • An analogous remark applies to the boiling-point of isomers.

    0
    0
  • Certain investigations on isomerism which have become especially prominent in recent times bear on the possibility of the mutual transformation of isomers.

    0
    0
  • These laws have the advantage of being applicable to the mutual transformations of isomers, whatever be the nature of the deeper origin, and so bring polymerism, metamerism and polymorphism together.

    0
    0
  • In ordinary isomers indications of mutual transformation often occur; and among these the predominant fact is that denoted as tautomerism or pseudomerism.

    0
    0
  • In reality such tautomeric compounds are apparently a mixture of two isomers in equilibrium, and indeed in some cases both forms have been isolated; then one speaks of desmotropy (Gr.

    0
    0
  • These isomers may frequently be distinguished by the facts that the cis-acids yield anhydrides more readily than the trans-acids, and are generally converted into the trans-acids on heating with hydrochloric acid.

    0
    0
  • - Two isomers are possible, namely cyclo-hexadiene-i.

    0
    0
  • Three structural isomers are possible.

    0
    0
  • Many polymerize readily, or are transformed into isomers by boiling with dilute alcoholic sulphuric acid.

    0
    0
  • There are three isomers: (1) ortho, or phthalic acid; (2) meta, or isophthalic acid; (3) para, or terephthalic acid.

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    0
  • i n general, isomers, i.e.

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