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dichloride

dichloride

dichloride Sentence Examples

  • Vanadium dichloride, VC12, is a green crystalline solid obtained when the tetrachloride is reduced with hydrogen at a dull red heat.

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  • Molybdenum monoxide, MoO.n(H 2 O), is a black powder obtained when the dichloride is boiled with concentrated potash solution.

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  • Molybdenum dichloride (MoC1 2) 3 or Cl 4 Mo 3 C1 2 (chlormolybdenum chloride), is prepared (together with some tetrachloride) by heating the trichloride in a stream of carbon dioxide (C. W.

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  • Germanium dichloride, GeCl2, and germanium chloroform, GeHCl3, have also been described.

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  • Thionyl chloride, SOC1 21 may be obtained by the action of phosphorus pentachloride on sodium sulphite; by the action of sulphur trioxide on sulphur dichloride at 75 -80° C. (Journ.

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  • Disulphuryl chloride, S 2 O 5 C1 2, corresponding to pyrosulphuric acid, is obtained by the action of sulphur trioxide on sulphur dichloride, phosphorus oxychloride, sulphuryl chloride or dry sodium chloride: 650 3- + 2POC1 3 = P 2 O 5 + 3S 2 O 5 C1 2; S2C12+ 5503 = S 2 0 5 C1 2 + 550 2; SO 3 + SO 2 C1 2 = S 2 0 5 C1 2; 2NaC1 + 3SO 3 = S 2 0 5 C1 2 -1 Na 2 SO 4.

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  • Ruthenium dichloride, RuC1 2, is obtained (in solution) by reducing the sesquichloride by sulphuretted hydrogen or zinc. It is stable in the cold.

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  • Instances had already been recorded of cases where a halogen element replaced hydrogen with the production of a closely allied substance: Gay Lussac had prepared cyanogen chloride from hydrocyanic acid; Faraday, hexachlorethane from ethylene dichloride, &c. Here the electronegative halogens exercised a function similar to electro-positive hydrogen.

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  • This tetrahedral configuration is based on the existence of only one methylene dichloride, two being necessary if the carbon valencies were directed from the centre of a plane square to its corners, and on the existence of two optical isomers of the formula C. A.

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  • It is remarkable that the position of the halogen in the molecule has no effect on the heat of formation; for example, chlorpropylene and allylchloride, and also ethylene dichloride and ethylidene dichloride, have equal heats of formation.

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  • If a suspension of lead dichloride in hydrochloric acid be treated with chlorine gas, a solution of lead tetrachloride is obtained; by adding ammonium chloride ammonium plumbichloride, (NH 4) 2 PbC1 6, is precipitated, which on treatment with strong sulphuric acid yields lead tetrachloride, PbC1 4, as a translucent, yellow, highly refractive liquid.

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  • It freezes at - 15° to a yellowish crystalline mass; on heating it loses chlorine and forms lead dichloride.

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  • Titanium dichloride, TiC1 21 obtained by passing hydrogen over the trichloride at a dull red heat, is a very hygroscopic brown powder which inflames when exposed to air, and energetically decomposes water.

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  • On heating piperidine with phosphorus pentachloride to 200°C. in a sealed tube pentamethylene dichloride is obtained, and this on treatment with potassium phthalimide gives a condensation product of composition, C 6 H 4 [CO] 2 N(CH 2) 5 N[CO] 2 C 6 H 4, which is finally hydrolysed by hydrochloric acid.

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  • Gold dichloride, probably Au 2 C1 4, =Au.AuC1 4, aurous chloraurate, is said to be obtained as a dark-red mass by heating finely divided gold to 140°- 170° in chlorine.

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  • The dichloride, BiC1 2, is obtained as a brown crystalline powder by fusing the metal with the trichloride, or in a current of chlorine, or by heating the metal with calomel to 250°.

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  • Two chlorides are known, the dichloride, TeC121 and the tetrachloride, TeCl 4.

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  • The dichloride is an amorphous, readily fusible, almost black solid.

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  • The tetrachloride is a white crystalline solid which is formed by the action of chlorine on the dichloride or by sulphur chloride on the element.

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  • By heating with sodium amalgam and separating with hydrochloric acid, the dichloride, TaC1 2.2H 2 O, is obtained as emerald green hexagonal crystals.

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  • Osmium dichloride, OsC1 21 is obtained as a dark coloured powder when the metal is heated in a current of chlorine.

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  • The tetrachloride, OsC1 41 is obtained as a dark red sublimate (mixed with the dichloride) when osmium is l}eated in dry chlorine.

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  • It readily forms addition products with chlorine and with hydrogen; the dichloride, C10H8C12, is obtained as a yellow liquid by acting with hydrochloric acid and potassium chlorate; the solid tetrachloride, C,o 11 8 C1 4, results when chlorine is passed into naphthalene dissolved in chloroform.

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  • By heating gallium in a regulated stream of chlorine the dichloride GaC1 2 is obtained as a crystalline mass, which melts at 164° C. and readily decomposes on exposure to moist air.

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  • The dichloride, WC1 2, is an amorphous grey powder obtained by reducing the hexachloride at a high temperature in hydrogen, or, better, by heating the tetrachloride in a current of carbon dioxide.

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  • Braun (Ber., 1904, 37, p. 2915) showed that benzoyl piperidine, when heated with phosphorus pentachloride to 200° C. in sealed tubes, yields benzonitrile, and pentamethylene dichloride, thus leading to a simple method of preparing pentamethylene compounds.

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  • Fournier (Comptes rendus, 1901, 150, p. 102) obtained phosphorus dichloride, P2C14, as a colourless, oily, strongly fuming liquid, freezing at -28° and boiling at 180° with decomposition.

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  • The pure metal may be obtained by reducing vanadium dichloride in hydrogen, the operation being exceedingly difficult (for details, see Roscoe's original papers).

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  • Three chlorides of indium are known: the trichloride, InC13j a deliquescent salt, formed by heating a mixture of the oxide and carbon in a current of chlorine; the dichloride, InCl2, obtained by heating the metal in hydrochloric acid gas; and the monochloride, InCl, which is prepared by distilling the vapour of the dichloride over metallic indium.

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  • dichloride oxide.

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  • The process by-passes the ethylene cracker and avoids the intermediate product ethylene dichloride.

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  • You would obviously still have to fractionally distil the mixture to separate the acyl chloride from any excess acid or sulfur dichloride oxide.

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  • ethylene dichloride and is susceptible to hydrolysis in prolonged contact with hot water.

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  • Thionyl chloride, SOC1 21 may be obtained by the action of phosphorus pentachloride on sodium sulphite; by the action of sulphur trioxide on sulphur dichloride at 75 -80° C. (Journ.

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  • It freezes at - 15° to a yellowish crystalline mass; on heating it loses chlorine and forms lead dichloride.

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  • On heating piperidine with phosphorus pentachloride to 200°C. in a sealed tube pentamethylene dichloride is obtained, and this on treatment with potassium phthalimide gives a condensation product of composition, C 6 H 4 [CO] 2 N(CH 2) 5 N[CO] 2 C 6 H 4, which is finally hydrolysed by hydrochloric acid.

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  • Gold dichloride, probably Au 2 C1 4, =Au.AuC1 4, aurous chloraurate, is said to be obtained as a dark-red mass by heating finely divided gold to 140°- 170° in chlorine.

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  • The dichloride, BiC1 2, is obtained as a brown crystalline powder by fusing the metal with the trichloride, or in a current of chlorine, or by heating the metal with calomel to 250°.

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  • By heating gallium in a regulated stream of chlorine the dichloride GaC1 2 is obtained as a crystalline mass, which melts at 164° C. and readily decomposes on exposure to moist air.

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  • Braun (Ber., 1904, 37, p. 2915) showed that benzoyl piperidine, when heated with phosphorus pentachloride to 200° C. in sealed tubes, yields benzonitrile, and pentamethylene dichloride, thus leading to a simple method of preparing pentamethylene compounds.

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  • Selenium dichloride, Se 2 C1 21 is obtained by the action of chlorine on selenium; by the action of phosphorus pentachloride on selenium or the dioxide; by the action of hydrochloric acid on seleno-sulphur trioxide (E.

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  • Fournier (Comptes rendus, 1901, 150, p. 102) obtained phosphorus dichloride, P2C14, as a colourless, oily, strongly fuming liquid, freezing at -28° and boiling at 180° with decomposition.

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