Kellner, who in 1886 patented the use of cathode (caustic soda) and anode (chlorine) liquors in the manufacture of cellulose from wood-fibre, and has since evolved many similar processes, has produced an apparatus that has been largely used.
When an alkaline chloride, say sodium chloride, is electrolysed with one electrode immersed in a porous cell, while caustic soda is formed at the cathode, chlorine is deposited at the anode.
Many electrolytic methods have been proposed for the purification of sugar; in some of them soluble anodes are used for a few minutes in weak alkaline solutions, so that the caustic alkali from the cathode reaction may precipitate chemically the hydroxide of the anode metal dissolved in the liquid, the precipitate carrying with it mechanically some of the impurities present, and thus clarifying the solution.
13,336 of 1894) a rapidly rotating cathode is used in a chloride solution, a porous partition separating the tank into anode and cathode compartments, and the chlorine generated by electrolysis at the anode being recovered.
The cathode consists of an iron rod which can be gradually raised.
Birkeland (19) supposes the ultimate cause to be cathode rays emanating from the sun; C. Nordmann (24) replaces the cathode rays by Hertzian waves; while Svante Arrhenius (25) believes that negatively charged particles are driven through the sun's atmosphere by the Maxwell-Bartoli repulsion of light and reach the earth's atmosphere.
In 1826 he described the prismatically-coloured films of metal, known as Nobili's' rings, deposited electrolytically from solutions of lead and other salts when the anode is a polished iron plate and the cathode is a fine wire placed vertically above it.
He also found that the liquid round the anode became acid, and that round the cathode alkaline.
Here the ions are potassium and the group Ag(CN)2.1 Each potassium ion as it reaches the cathode precipitates silver by reacting with the solution in accordance with the chemical equation K--+KAg(CN) 2 =2KCN+Ag, while the anion Ag(CN) 2 dissolves an atom of silver from the anode, and re-forms the complex cyanide KAg(CN) 2 by combining with the 2KCN produced in the reaction described in the equation.
Very irregular surfaces may require the use of specially shaped anodes in order that the distance between the electrodes may be fairly uniform, otherwise the portion of the cathode lying nearest to the anode may receive an undue share of the current, and therefore a greater thickness of coat.
In such an arrangement, after the first instant, the melted metal in the furnace does not come in contact with the cathode material.
By electrolysing an aqueous solution of the chloride with a mercury cathode, a liquid and a solid amalgam, SrHgn, are obtained; the latter on heating gives a mixture of Sr 2 Hg 5 and SrHg 5, and on distillation an amalgam passes over, and not the metal.
One process depends upon the fact that, with a suitable current density, if a very dilute solution of silver nitrate be electrolysed between an auriferous silver anode and a silver cathode, the silver of the anode is dissolved out and deposited at the cathode, the gold remaining at the anode.
But if the gold-strength of the bath be maintained, only gold is deposited at the cathode - in a loose powdery condition from pure solutions, but in a smooth detachable deposit from impure liquors.
The reversed plate thus produced is then stripped from the first and used as cathode in its turn, with the result that even the finest lines of the original are faithfully reproduced.
Henri Moissan obtained the metal of 99% purity by electrolysing calcium iodide at a low red heat, using a nickel cathode and a graphite anode; he also showed that a more convenient process consisted in heating the iodide with an excess of sodium, forming an amalgam of the product, and removing the sodium by means of absolute alcohol (which has but little action on calcium), and the mercury by distillation.
On electrolysis a layer of metallic calcium is formed at the lower end of this rod on the surface of the electrolyte; the rod is gradually raised, the thickness of the layer increases, and ultimately a rod of metallic calcium, forming, as it were, a continuation of the iron cathode, is obtained.
Borchers endeavoured to contend against the first difficulty by employing an iron cathode vessel and a chamotte (fire-clay) anode chamber united by a specially constructed water-cooled joint.
The apparatus described in the patent specification is an iron cylinder heated by gas rings below, with a narrower cylinder beneath, through which passes upwards a stout iron cathode rod cemented in place by caustic soda solidified in the narrower vessel.
Iron anodes are suspended around the cathode, and between the two is a cylinder of iron gauze at the bottom with a sheet-iron continuation above, the latter being provided with a movable cover.
Borchers also used an externally heated metal vessel as the cathode; it is provided with a supporting collar or flange a little below the top, so that the upper part of the vessel is exposed to the cooling influence of the air, in order that a crust of solidified salt may there be formed, and so prevent the creeping of the electrolyte over the top. The carbon anode passes through the cover of a porcelain cylinder, open at the bottom, and provided with a side-tube at the top to remove the chlorine formed during electrolysis.
Of cathode surface, and the pressure about 7 volts.
Radium itself emits three types of rays: (1) the a rays, which are regarded as positively charged helium atoms; these rays are stopped by a single sheet of paper; (2) the s rays, which are identified with the cathode rays, i.e.
The hydrogen at the cathode is developed by the secondary action 2Na+2H 2 O =2NaOH+H2.
Small objects are often heaped together in perforated trays or ladles, the cathode connecting-rod being buried in the midst of them.
Care must be taken not to expose goods in the plating-bath to too high a current density, else they may be "burnt"; they must never be exposed one at a time to the full anode surface, with the current flowing in an empty bath, but either one piece at a time should be replaced, or some of the anodes should be transferred temporarily to the place of the cathodes, in order to distribute the current over a sufficient cathode-area.
Iron ships' plates have recently been coated with copper in sections (to prevent the adhesion of barnacles), by building up a temporary trough against the side of the ship, making the thoroughly cleansed plate act both as cathode and as one side of the trough.
Others have arranged a means of obtaining high conductivity wire from cathode-copper without fusion, by depositing the metal in the form of a spiral strip on a cylinder, the strip being subsequently drawn down in the usual way; at present, however, the ordinary methods of wire production are found to be cheaper.
Canvas diaphragms were used to prevent the acid formed by electrolysis at the anode from mixing with the cathode liquor, and so hindering deposition.
Liquid metal coming in contact with such a surface forms a crust of solidified metal over it, and this crust thickens up to a certain point, namely, until the heat from within the furnace just overbalances that lost by conduction through the solidified crust and the cathode material to the flowing water.
If, however, no porous division be used to prevent the intermingling by diffusion of the anode and cathode solutions, a complicated set of subsidiary reactions takes place.
At the same time, the diffusion of these compounds into contact with the cathode leads to a partial reduction to chloride, by the removal of combined oxygen by the instrumentality of the hydrogen there evolved.
Hypochlorites were made, at ordinary temperatures, and chlorates at higher temperatures, in a cell without a partition in which the cathode was placed horizontally immediately above the anode, to favour the mixing of the ascending chlorine with the descending caustic solution.
In art-work of this nature the principal points to be looked to in depositing are the electrical connexions to the cathode, the shape of the anode (to secure uniformity of deposition), the circulation of the electrolyte, and, in some cases, the means for escape of anode oxygen.
Filr Electrochemie, 1902, p. 8757) obtained the metal of 90% purity by electrolysing calcium chloride at a temperature of about 780°, using an iron cathode, the anode being the graphite vessel in which the electrolysis was carried out.
During electrolysis, oxygen is evolved at the anode and escapes from the outer vessel, while the sodium deposited in globules on the cathode floats upwards into the iron cylinder, within which it accumulates, and from which it may be removed at intervals by means of a perforated iron ladle, the fused salt, but not the metal, being able to pass freely through the perforations.
Graetzel's process, which was at one time employed, consisted in electrolysing the chloride in a metal crucible heated externally, the crucible itself forming the cathode, and the magnesium being deposited upon its inner surface.
His attention was at first divided between two processes - the chemical method of reducing the chloride with potassium, and an electrolytic method of decomposing it with a carbon anode and a platinum cathode, which was simultaneously imagined by himself and R.
In the case we have chosen, the solution becomes stronger near the anode, or electrode at which the current enters, and weaker near the cathode, or electrode at which it leaves the solution.
If we assume that no other cause is at work, it is easy to prove that, with non-dissolvable electrodes, the ratio of salt lost at the anode to the salt lost at the cathode must be equal to the ratio of the velocity of the cation to the velocity of the anion.
The Heroult cell consists of a square iron or steel box lined with carbon rammed and baked into a solid mass; at the bottom is a cast-iron plate connected with the negative pole of the dynamo, but the actual working cathode is undoubtedly the layer of already reduced and molten metal that lies in the bath.
The operation is essentially a dissociation of alumina into aluminium, which collects at the cathode, and into oxygen, which combines with the anodes to form carbon monoxide, the latter escaping and being burnt to carbon dioxide outside.
Palladium and some other metals are capable of absorbing large volumes of hydrogen (especially when the metal is used as a cathode in a water electrolysis apparatus).
Cathode rays usually have a velocity about a tenth that of light, but in exceptional cases it may approach a third of that of light.
On either Birkeland's or Nordmann's theory, the electric impulse from the sun acts indirectly by creating secondary cathode rays in the earth's atmosphere, or ionizing it so that discharges due to natural differences of potential are immensely facilitated.
The sodium as it is formed at the cathode at once dissolves in the mercury which protects it against the action of the water as long as the percentage of sodium in the mercury does not exceed, say, 0.02%.
Sodium hypochlorite can be prepared by the electrolysis of brine solution in the presence of carbon electrodes, having no diaphragm in the electrolytic cell, and mixing the anode and cathode products by agitating the liquid.
In the 7th series (1834) he defines a number of new terms, such as electrolyte, electrolysis, anode and cathode, &c., in connexion with electrolytic phenomena, which were immediately adopted into the vocabulary of science.
Hittorf made in 1869 the discovery that solid objects could cast shadows or intercept this cathode discharge.
The cathode discharge henceforth engaged the attention of many physicists.
A battery with a sufficient number of cells is connected to these two electrodes so as to pass a current through the mercury vapour, negative electricity proceeding from the mercury cathode to the iron anode.
The electrolysis is generally conducted with platinum electrodes, of which the cathode takes the form of a piece of foil bent into a cylindrical form, the necessary current being generated by one or more Daniell cells.
In spite of this appearance, however, while the supply of copper is maintained, copper, being more easily separated from the solution than zinc, is deposited alone at the cathode, and the cell remains constant.
It is for this reason that Siemens, Borchers and others substituted a hollow watercooled metal block for the carbon cathode upon which the melted metal rests while in the furnace.
In the " dry " methods the silver is converted into sulphide or chloride, the gold remaining unaltered; in the " wet " methods the silver is dissolved by nitric acid or boiling sulphuric acid; and in the electrolytic processes advantage is taken of the fact that under certain current densities and other circumstances silver passes from an anode composed of a gold-silver alloy to the cathode more readily than gold.