Carbon-disulphide sentence example

carbon-disulphide
  • Passing over the discovery of carbon disulphide by W.
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  • Either they are placed in a leaden cupboard into which the vapour is introduced, or they are dipped for a few seconds in a mixture of one part of chloride of sulphur and forty parts of carbon disulphide or purified light petroleum.
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  • Its specific gravity is o 899 at o° C. It is very slightly soluble in water, more soluble in alcohol, and completely miscible with ether, acetic acid and carbon disulphide.
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  • Aqueous alcohol becomes turbid when mixed with benzene, carbon disulphide or paraffin oil; when added to a solution of barium oxide in absolute alcohol, a white precipitate of barium hydroxide is formed.
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  • The solubility of the gas in various liquids, as given by different observers, is zoo Volumes of Brine Water Alcohol Paraffin Carbon disulphide Fusel oil Benzene Chloroform Acetic acid Acetone It will be seen from this table that where it is desired to collect and keep acetylene over a liquid, brine, i.e.
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  • Heated in chlorine or with bromine, it yields carbon and calcium chloride or bromide; at a dull red heat it burns in oxygen, forming calcium carbonate, and it becomes incandescent in sulphur vapour at 500°, forming calcium sulphide and carbon disulphide.
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  • Aluminium sulphide, Al2S3, results from the direct union of the metal with sulphur, or when carbon disulphide vapour is passed over strongly heated alumina.
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  • The carbon disulphide and salicylic aldehyde products have also been used as means of distinction, as has also the formation of the stilbazonium bases obtained by condensing ortho-semidines with benzil (0.
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  • Phosphorus trichloride or phosphorous chloride, PC13, discovered by Gay-Lussac and Thenard in 1808, is obtained by passing a slow current of chlorine over heated red phosphorus or through a solution of ordinary phosphorus in carbon disulphide (purifying in the latter case by fractional distillation).
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  • Phosphorus tribromide, PBr 3, prepared by mixing solutions of its elements in carbon disulphide and distilling, is a transparent, mobile liquid, boiling at 173° and resembling the trichloride chemically.
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  • The product is extracted with carbon disulphide and the residue distilled in carbon dioxide.
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  • The second, P4S7, is obtained by heating a mixture of red phosphorus and sulphur in the proportions given by P4S7+5% P4S3, and crystallizing from carbon disulphide in which P 4 S 3 is readily soluble.
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  • Thiel (Ber., 1905, 3 8, p. 2719 1910, 43, p. 1223), who heated sulphur with phosphorus in carbon disulphide solution with a trace of iodine to 120 0 -130 0.
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  • At this point in the manufacturing process the gas has already undergone some important changes in its composition, but there yet remain impurities which must be removed, these being ammonia, sulphuretted hydrogen, carbon disulphide and carbon dioxide.
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  • In this wet purifying apparatus the gas is almost wholly freed from ammonia and from part of the sulphuretted hydrogen, whilst carbon dioxide and carbon disulphide are also partially extracted.
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  • When the gas had to be purified from carbon disulphide as well as from sulphuretted hydrogen, slaked lime was employed for the removal of carbon dioxide and the greater quantity of the sulphur compounds, whilst a catch box or purifier of oxide of iron served to remove the last traces of sulphuretted hydrogen.
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  • The foul gas leaving the scrubbers contains, as a general average, 30 grains of sulphuretted hydrogen, 40 grains of carbon disulphide and zoo grains of carbon dioxide per Ioo cub.
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  • On entering the first purifier, which contains calcium thiocarbonate and other combinations of calcium and sulphur in small quantity, the sulphuretted hydrogen and disulphide vapour have practically no action upon the material, but the carbon dioxide immediately attacks the calcium thiocarbonate, forming calcium carbonate with the production of carbon disulphide vapour, which is carried over with the gas into the second box.
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  • In the connexion between the first and the second box the gas is found to contain 500 grains of sulphuretted hydrogen and 80 grains of carbon disulphide per Ioo cub.
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  • In the second box the formation of calcium thiocarbonate takes place by the action of carbon disulphide upon the calcium sulphide with the liberation of sulphuretted hydrogen, which is carried over to the third purifier.
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  • The gas in the connecting pipe between the second and third purifier will be found to contain 400 grains of sulphuretted hydrogen and 20 grains of carbon disulphide.
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  • The contents of the third box, being mostly composed of slaked lime, take up sulphuretted hydrogen forming calcium sulphide, and practically remove the remaining impurities, the outlet gas showing 20 grains of sulphuretted hydrogen and 8 grains of carbon disulphide per Ioo cub.
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  • Sulphuretted hydrogen is passed through the liquid until it is thoroughly saturated, the excess of sulphuretted hydrogen is expelled from the solution by a brisk stream of carbon dioxide, and the precipitate is filtered on a Gooch crucible and washed with water containing a little sulphuretted hydrogen and dried at 100° C.; it is then well washed with small quantities of pure carbon disulphide to remove any free sulphur, again dried and weighed.
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  • Aniline combines directly with alkyl iodides to form secondary and tertiary amines; boiled with carbon disulphide it gives sulphocarbanilide (diphenyl thio-urea), CS(NHC 6 H 5) 2, which may be decomposed into phenyl mustard-oil, C 6 H 5 CNS, and triphenyl guanidine, C 6 H 5 N: C(NHC6H5)2.
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  • If cotton or linen is used, it is usual to incorporate sulphur with the paste, and to effect vulcanization by steam heat; but, when silk or wool is employed, no sulphur is added to the paste, the dried coating of rubber being merely brought into momentary contact with the mixture of chloride of sulphur and carbon disulphide already mentioned.
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  • Its specific gravity is o 899 at o° C. It is very slightly soluble in water, more soluble in alcohol, and completely miscible with ether, acetic acid and carbon disulphide.
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  • Heated in chlorine or with bromine, it yields carbon and calcium chloride or bromide; at a dull red heat it burns in oxygen, forming calcium carbonate, and it becomes incandescent in sulphur vapour at 500°, forming calcium sulphide and carbon disulphide.
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  • Phosphorus tribromide, PBr 3, prepared by mixing solutions of its elements in carbon disulphide and distilling, is a transparent, mobile liquid, boiling at 173° and resembling the trichloride chemically.
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  • Sulphuretted hydrogen is passed through the liquid until it is thoroughly saturated, the excess of sulphuretted hydrogen is expelled from the solution by a brisk stream of carbon dioxide, and the precipitate is filtered on a Gooch crucible and washed with water containing a little sulphuretted hydrogen and dried at 100° C.; it is then well washed with small quantities of pure carbon disulphide to remove any free sulphur, again dried and weighed.
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