Carbon-bisulphide sentence example

carbon-bisulphide
  • It is decomposed by water, and with a solution of yellow phosphorus in carbon bisulphide it gives a red powder of composition PBI 2, which sublimes in vacuo at 210° C. to red crystals, and when heated in a current of hydrogen loses its iodine and leaves a residue of boron phosphide PB.
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  • Boron sulphide B 2 S 3 can be obtained by the direct union of the two elements at a white heat or from the tri-iodide and sulphur at 44 0 ° C., but is most conveniently prepared by heating a mixture of the trioxide and carbon in a stream of carbon bisulphide vapour.
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  • A pentasulphide B2S5 is prepared, in an impure condition, by heating a solution of sulphur in carbon bisulphide with boron iodide, and forms a white crystalline powder which decomposes under the influence of water into sulphur, sulphuretted hydrogen and boric acid.
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  • Bollman in 1867 the ore may be extracted by carbon bisulphide.
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  • It boils at 139° C. and is solid at - 80° C. It is soluble in carbon bisulphide and in benzene.
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  • The crude solid product from the tar distillate is digested with carbon bisulphide to dissolve the pyrene, the solution filtered and the solvent evaporated.
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  • It may be more conveniently prepared by passing the vapour of sulphur over red hot charcoal, the unccndensed gases so produced being led into a tower containing plates over which a vegetable oil is allowed to flow in order to absorb any carbon bisulphide vapour, and then into a second tower containing lime, which absorbs any sulphuretted hydrogen.
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  • A mixture of carbon bisulphide vapour and nitric oxide burns with a very intense blue-coloured flame, which is very rich in the violet or actinic rays.
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  • A mixture of carbon bisulphide vapour and sulphuretted hydrogen, when passed over heated copper, gives, amongst other products, some methane.
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  • If the plants are subjected to some process, before mounting, by which injurious organisms are destroyed, such as exposure in a closed chamber to vapour of carbon bisulphide for some hours, the presence of pieces of camphor or naphthalene in the cabinet will be found a sufficient preservative.
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  • Columbium oxysulphide, CbOS 3, is obtained as a dark bronze coloured powder when the pentoxide is heated to a white heat in a current of carbon bisulphide vapour; or by gently heating the oxychloride in a current of sulphuretted hydrogen.
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  • Stannic bromide, SnBr 4, is a white crystalline mass, melting at 33° and boiling at 201°, obtained by the combination of tin and bromine, preferably in carbon bisulphide solution.
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  • Silicon tetraiodide, Si14, is formed by passing iodine vapour mixed with carbon dioxide over strongly-heated silicon (C. Friedel, Comptes rendus, 1868, 67, p. 98); the iodo-compound condenses in the colder portion of the apparatus and is purified by shaking with carbon bisulphide and with mercury.
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  • It is soluble in carbon bisulphide, and is decomposed by water and also by heat, in the latter case yielding the tetraiodide and the di-iodide, Si 2 I 4, an orange-coloured solid which is not soluble in carbon bisulphide.
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  • Silicon sulphide, SiS 2, is formed by the direct union of silicon with sulphur; by the action of sulphuretted hydrogen on crystallized silicon at red heat (P. Sabatier, Comptes rendus, 1880, 90, p. 819); or by passing the vapour of carbon bisulphide over a heated mixture of silica and carbon.
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  • Primary amines heated with carbon bisulphide in alcoholic solution are converted into mustard oils, when the dithiocarbamate first produced is heated with a solution of mercuric chloride.
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  • It burns when heated in an atmosphere of oxygen, forming carbon dioxide, and when heated in sulphur vapour it forms carbon bisulphide.
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  • It Is Also Formed When Sulphur Trioxide Reacts With Carbon Bisulphide At 100° C., Cs2 3S03 =Cos 4So 2, And By The Decomposition Of Ethyl Potassium Thiocarbonate With Hydrochloric Acid, Co(0C2115)Sk Hc1= Cos Kc1 C 2 H 5 Oh.
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  • Wood, when white light is transmitted through a paste made of powdered quartz and a mixture of carbon bisulphide with benzol having the same refractive index as the quartz for yellow light.
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  • Its solutions in the alkaline iodides and in alcohol and ether are brown in colour, whilst in chloroform and carbon bisulphide the solution is violet.
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  • This law cannot be maintained in its generality, but nevertheless highly dispersive substances like carbon bisulphide are always found to produce a greater shift than liquids of smaller dispersion like water and alcohol.
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  • Rutherfurd devised one made of flint glass with two crown glass compensating prisms; whilst Thallon employed a hollow prism containing carbon bisulphide also compensated by flint glass prisms. In direct vision spectroscopes the refracting prisms and slit are in the observing telescope.
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  • Lanthanum sulphide, La 2 S 3, is a yellow powder, obtained when the oxide is heated in the vapour of carbon bisulphide.
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  • It is easily soluble in hot alcohol, ether and carbon bisulphide.
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  • When heated with alcohol in sealed tubes, it yields carbamic esters; with alcohol and carbon bisulphide at Ioo° C., carbon dioxide is liberated and ammonium sulphocyanide is formed.
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  • Manganous Sulphide, MnS, found native as manganese glance, may be obtained by heating the monoxide or carbonate in a porcelain tube in a current of carbon bisulphide vapour.
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  • Cerous sulphide, Ce2S3, results on heating cerium with sulphur or cerium oxide in carbon bisulphide vapour.
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  • Tungsten disulphide, W52, is obtained as soft black acicular crystals by the action of sulphur, sulphuretted hydrogen or carbon bisulphide on tungsten.
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  • Many remedies for this disease have been suggested, including total submersion of the vineyards, the use of carbon bisulphide for spraying, and of copper salts, but there appears to be little doubt that a really serious epidemic can only be dealt with by systematic destruction of the vines, followed by replanting with resistant varieties.
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  • Prepared in this way it contains a small quantity of the unaltered chloride, which can be removed by ether or carbon bisulphide.
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  • Antimony tribromide, SbBr 3, and tri-iodide, SbI 31 may be prepared by the action of antimony on solutions of bromine or iodine in carbon bisulphide.
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  • The behaviour of a drop of carbon bisulphide placed upon clean water is also, at first sight, an exception to Marangoni's rule.
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  • If after the deposition of the drop, a little lycopodium be scattered over the surface, it is seen that a circular space surrounding the drop, of about the size of a shilling, remains bare, and this, however often the dusting be repeated, so long as any of the carbon bisulphide remains.
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  • The carbon bisulphide is really spreading all the while, but on account of its volatility is unable to reach any considerable distance.
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  • It is slightly soluble in carbon bisulphide.
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  • It is a brickred powder which explodes when heated to 130° C. Selenium cyanide, Se(CN) 2, is obtained by decomposing silver selenocyanide with cyanogen iodide, or by the action of silver cyanide on a solution of selenium bromide in carbon bisulphide.
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  • (German Patent, 26642.) The diluents in which bromine is employed are usually ether, chloroform, acetic acid, hydrochloric acid, carbon bisulphide and water, and, less commonly, alcohol, potassium bromide and hydrobromic acid; the excess of bromine being removed by heating, by sulphurous acid or by shaking with mercury.
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  • In front of the aperture were placed a plate of transparent rock-salt, and a flat cell of thin glass containing a solution of iodine in carbon bisulphide.
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  • Both rock-salt and carbon bisulphide are extremely transparent to the luminous and also to the infra-red rays The iodine in the solution, however, has the property of absorbing the luminous rays, while transmitting the infra-red rays copiously, so that in sufficient thicknesses the solution appears nearly black.
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  • The pentaiodide, AsI5, appears to be formed when a mixture of one part of arsenic and seven parts of iodine is heated to 190° C., but on dissolving the resulting product in carbon bisulphide and crystallizing from this solvent, only the tri-iodide is obtained.
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  • Extraction by means o carbon bisulphide was first introduced in 1843 by Jesse Fisher of Birmingham.
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  • Of course, the meal left by the process was so tainted with carbon bisulphide that it was absolutely out of the question to use the extracted meal as cattle food.
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  • With the improvement in the manufacture of carbon bisulphide, these drawbacks have been surmounted to a large extent, and the process of extracting with carbon bisulphide has specially gained much extension in the extraction of expressed olive mare in the south of France, in Italy and in Spain.
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  • Yet even now traces of carbon bisulphide are retained by the extracted meal, so that it is impossible to feed cattle with it.
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  • But owing to the physiological effect carbon bisulphide has on the workmen, coupled with the chemical action of impure carbon bisulphide on iron which has frequently led to conflagrations, the employment of carbon bisulphide must remain restricted.
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  • Carbon tetrachloride would be an ideal solvent, as it is non-inflammable and shares with carbon bisulphide the advantage of being heavier than water.
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  • At the present time the choice lies practically only between the two solvents, carbon bisulphide and naphtha (petroleum ether).
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  • Naphtha is preferable for oil seeds, as it extracts neither resins nor gummy matters from the oil seeds, and takes up less colouring matter than carbon bisulphide.
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  • It is decomposed by water, and with a solution of yellow phosphorus in carbon bisulphide it gives a red powder of composition PBI 2, which sublimes in vacuo at 210° C. to red crystals, and when heated in a current of hydrogen loses its iodine and leaves a residue of boron phosphide PB.
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  • Boron sulphide B 2 S 3 can be obtained by the direct union of the two elements at a white heat or from the tri-iodide and sulphur at 44 0 ° C., but is most conveniently prepared by heating a mixture of the trioxide and carbon in a stream of carbon bisulphide vapour.
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  • It boils at 139° C. and is solid at - 80° C. It is soluble in carbon bisulphide and in benzene.
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  • It has long been known that the definition of a carbon bisulphide prism may be much improved by a vigorous shaking.
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  • Stannic bromide, SnBr 4, is a white crystalline mass, melting at 33° and boiling at 201°, obtained by the combination of tin and bromine, preferably in carbon bisulphide solution.
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  • They give the isonitrile reaction (see above) when warmed with chloroform and a caustic alkali, and form alkyl thioureas when heated with an alcoholic solution of carbon bisulphide.
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  • It Is Also Formed When Sulphur Trioxide Reacts With Carbon Bisulphide At 100° C., Cs2 3S03 =Cos 4So 2, And By The Decomposition Of Ethyl Potassium Thiocarbonate With Hydrochloric Acid, Co(0C2115)Sk Hc1= Cos Kc1 C 2 H 5 Oh.
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  • When heated with alcohol in sealed tubes, it yields carbamic esters; with alcohol and carbon bisulphide at Ioo° C., carbon dioxide is liberated and ammonium sulphocyanide is formed.
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  • It is a brickred powder which explodes when heated to 130° C. Selenium cyanide, Se(CN) 2, is obtained by decomposing silver selenocyanide with cyanogen iodide, or by the action of silver cyanide on a solution of selenium bromide in carbon bisulphide.
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  • The pentaiodide, AsI5, appears to be formed when a mixture of one part of arsenic and seven parts of iodine is heated to 190° C., but on dissolving the resulting product in carbon bisulphide and crystallizing from this solvent, only the tri-iodide is obtained.
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