Calcium-chloride sentence example
Another mode of separating the two acids is to convert them into calcium salts, which are then treated with a perfectly neutral solution of cupric chloride, soluble cupric citrate and calcium chloride being formed, while cupric tartrate remains undissolved.
Balard discovered chlorine monoxide in 1834, investigating its properties and reactions; and his observations on hypochlorous acid and hypochlorites led him to conclude that " bleaching-powder " or " chloride of lime " was a compound or mixture in equimolecular proportions of calcium chloride and hypochlorite, with a little calcium hydrate.
After having previously roasted the tube and copper oxide, and reduced the copper spiral a, the weighed calcium chloride tube and potash bulbs are put in position, the boat containing the substance is inserted (in the case of a difficultly combustible substance it is desirable to mix it with cupric oxide or lead chromate), the copper spiral (d) replaced, and the air and oxygen supply connected up. The apparatus is then tested for leaks.
The increase in weight of the calcium chloride tube gives the weight of water formed, and of the potash bulbs the carbon dioxide.
When boiled with calcium chloride and ammonia, salicylic acid gives a precipitate of insoluble basic calcium salicylate, C 6 H 4 ‹ 0 2 i Ca, a reaction which serves to distinguish it from the isomeric metaand para-hydroxybenzoic acids.Advertisement
The calcium salt, CaN 2 O 2.4H 2 O, formed by the action of calcium chloride on the silver salt in the presence of a small quantity of nitric acid, is a lustrous crystalline powder, almost insoluble in water but readily soluble in dilute acids.
Strontium chloride, SrC1 2.6H 2 O, is obtained by dissolving the carbonate in hydrochloric acid, or by fusing the carbonate with calcium chloride and extracting the melt with water.
Hermite, which consisted in the production of bleach-liquors by the electrolysis (according to the 1st edition of the 1884 patent) of magnesium or calcium chloride between platinum anodes carried in wooden frames, and zinc cathodes.
Its compound with calcium chloride has the formula CaC1 2.4CH 3.
Electrolysis of lime or calcium chloride in contact with mercury gave similar results.Advertisement
Calcium fluoride, CaF2, constitutes the mineral fluor-spar, and is prepared artificially as an insoluble white powder by precipitating a solution of calcium chloride with a soluble fluoride.
The mineral brushite, CaHPO 4.2H 2 0, which is isomorphous with the acid arsenate pharmacolite, CaHAs04.2H20, is an acid phosphate, and assumes monoclinic forms. The normal salt may be obtained artificially, as a white gelatinous precipitate which shrinks greatly on drying, by mixing solutions of sodium hydrogen phosphate, ammonia, and calcium chloride.
It is obtained as rhombic plates by mixing dilute solutions of calcium chloride and sodium phosphate, and passing carbon dioxide into the liquid.
Calcium metasilicate, CaSiO 3, occurs in nature as monoclinic crystals known as tabular spar or wollastonite; it may be prepared artificially from solutions of calcium chloride and sodium silicate.
Ammonia gas has the power of combining with many substances, particularly with metallic halides; thus with calcium chloride it forms the compound CaCl 2.8NH 3, and consequently calcium chloride cannot be used for drying the gas.Advertisement
In his researches on the bleaching compounds of chlorine he was the first to advance the view that bleaching-powder is a double compound of calcium chloride and hypochlorite; and he devoted much time to the problem of economically obtaining soda and potash from seawater, though here his efforts were nullified by the discovery of the much richer sources of supply afforded by the Stassfurt deposits.
It is easily soluble in water and alcohol, and is thrown out of its aqueous solution by the addition of calcium chloride.
There are also other advantages of this process which explain its wide extension, in spite of the fact that only from 30 to 35 parts of the hydrochloric acid employed is converted into chlorine, the remainder ultimately leaving the factory in the shape of a harmless but useless solution of calcium chloride.
Its composition approaches the formula CaOC1 2, and it is regarded as a double salt of calcium chloride and hypochlorite, which by the action of water splits up into a mixture of these salts.
On adding to this solution, after settling out the mud, a quantity of potassium chloride equivalent to the calcium chlorate, the reaction Ca(C10 3) 2 +2KC1=CaC1 2 +2KC10 3 is produced, the ultimate proportions thus being theoretically 2KC10 3 to 6CaCl2, though in reality there is rather more calcium chloride present.Advertisement
All endeavours to obtain either hydrochloric acid or free chlorine in the ammoniasoda process have proved commercial failures, all the chlorine of the sodium chloride being ultimately lost in the shape of worthless calcium chloride.
The solution of calcium chloride is run to waste, the ammonia is re-introduced into the process.
The reversible character of the principal reaction has the consequence that a considerable portion of the sodium chloride (up to 33%) is lost, being contained in the waste calcium chloride solution which issues from the ammonia stills.
The substance is best prepared by drying ethyl acetate over calcium chloride and treating it with sodium wire, which is best introduced in one operation; the liquid boils and is then heated on a water bath for some hours, until the sodium all dissolves.
The ore is first treated with dilute sulphuric acid, and then ferrous or calcium chloride added, thus forming copper chlorides.Advertisement
If calcium chloride be used the precipitated calcium sulphate must be removed by filtration.
To facilitate the communication of the charge to the needle, the quartz fibre and its attachments are rendered conductive by a thin film of solution of hygroscopic salt such as calcium chloride.
The substitution of potassium chlorate for pyrolusite is recommended when calcium chloride is present in the bittern.
The essential oil is rectified by redistillation with water and alkaline carbonates, and the water which the oil carries over with it is removed by a further distillation over calcium chloride.
Run off the lower layer of 1-bromobutane and add some granular anhydrous calcium chloride.
Titanium Titanium metal made by electrolysis of titanium dioxide in molten calcium chloride.
The templates were used to grow surface microstructures by controlled crystallization of calcium carbonate by immersion in calcium chloride solution.
Of the hygroscopic substances in common use, phosphoric anhydride, concentrated sulphuric acid, and dry potassium hydrate are almost equal in power; sodium hydrate and calcium chloride are not much behind.
Fused calcium chloride is the commonest absorbent; but it must not be used with alcohols and several other compounds, since it forms compounds with these substances.