Benzenoid Sentence Examples

This and other facts connected with the stability of benzenoid compounds are clearly shown when we consider mixed aliphatic-aromatic hydrocarbons, i.e.

Hitherto we have generally restricted ourselves to syntheses which result in the production of a true benzene ring; but there are many reactions by which reduced benzene rings are synthesized, and from the compounds so obtained true benzenoid compounds may be prepared.

The transformation is not one of the oxidation of a hexamethylene compound to a benzenoid compound, for only two hydrogen atoms are removed.

The stronger argument against the ethylenoid linkages demanded by Kekule's formula is provided by the remarkable stability towards oxidizing and reducing agents which characterizes all benzenoid compounds.

From the fact that reduction products containing either one or two double linkages behave exactly as unsaturated aliphatic compounds, being readily reduced or oxidized, and combining with the halogen elements and haloid acids, it seems probable that in benzenoid compounds the fourth valencies are symmetrically distributed in such a manner as to induce a peculiar stability in the molecule.

Thomsen then investigated heats of combustion of various benzenoid hydrocarbons - benzene, naphthalene, anthracene, phenanthrene, &c. - in the crystallized state.

The molecule is aromatic but not benzenoid; however, by the reduction of one half of the molecule, the other assumes a benzenoid character.

Bamberger's observations on reduced quinoline derivatives point to the same conclusion, that condensed nuclei are not benzenoid, but possess an individual character, which breaks down, however, when the molecule is reduced.

For general purposes, however, the symbol (2), in which the lateral rings are benzenoid and the medial ring fatty, represents quite adequately the syntheses, decompositions, and behaviour of anthracene.

Systems which are generally unsaturated compounds, often of considerable stability, and behave as nuclei; these compounds constitute a well-individualized class exhibiting closer affinities to benzenoid substances than to the open-chain series.

He suggests that the term " quinone " theory be abandoned, and replaced by the Umlagerungs theory, since this term implies some intermolecular rearrangement, and does not connote simply benzenoid compounds as does " quinonoid."

Chemically it is one of the most interesting substances known, since it is the parent of the enormous number of compounds styled the " aromatic " or " benzenoid " compounds.

Meyer (Ber., 18 94, 2 7, p. 510 et seq.) showed that in benzenoid compounds ortho-substituents exert a great hindering effect on the esterification of alcohols by acids in the presence of hydrochloric acid, this hindering being particularly marked when two substituents are present in the ortho positions to the carboxyl group. In such a case the ester is best prepared by the action of an alkyl halide on the silver salt of the acid, and when once prepared, can only be hydrolysed with great difficulty.