Anhydride Sentence Examples
A higher temperature decomposes this body into carbon dioxide and itaconic acid, C 5 H 6 0 4, which, again, by the expulsion of a molecule of water, yields citraconic anhydride, C 5 H 4 0 3.
When distilled with phosphoric anhydride they yield nitriles.
Four oxides of sulphur a.re known, namely sulphur dioxide, S02, sulphur trioxide, S03, sulphur sesquioxide, S203, and persulphuric anhydride, S 2 0 7.
Although this acid appears to be derived from an oxide S203, it is not certain that the known sesquioxide is its anhydride.
Persulphuric anhydride, S207, is a thick viscous liquid obtained by the action of the silent discharge upon a mixture of sulphur trioxide and oxygen.Advertisement
Again, in nitrous oxide we have a compound of 8 parts by weight of oxygen and 14 of nitrogen; in nitric oxide a compound of 16 or 8 X 2 parts of oxygen and 1 4 of nitrogen; in nitrous anhydride a compound of 24 or 8 X 3 parts of oxygen and 14 of nitrogen; in nitric peroxide a compound of 3 2 or 8 X 4 parts of oxygen and 14 of nitrogen; and lastly, in nitric anhydride a compound of 4 o or 8 X 5 parts of oxygen and 14 of nitrogen.
A notable example is provided by the phthaleins, which result by the condensation of phthalic anhydride with phenols.
Glucoseoxime on warming with acetic anhydride is simultaneously acetylated and dehydrated, yielding an acetylated gluconitrile, which when warmed with ammoniacal silver nitrate loses hydrocyanic acid and is transformed into an acetyl pentose.
The newer glasses, on the other hand, contain a much wider variety of chemical constituents, the most important being the oxides of barium, magnesium, aluminium and zinc, used either with or without the addition of the bases already named in reference to the older glasses, and - among acid bodies - boric anhydride (B20 3) which replaces the silica of the older glasses to a varying extent.
It is decomposed by cold water with the formation of silicoformic anhydride, H2S1203.Advertisement
Wohl forms the oxime and converts it into an acetylated nitrile by means of acetic anhydride and sodium acetate; ammoniacal silver nitrate solution removes hydrocyanic acid and the resulting acetate is hydrolysed by acting with ammonia to form an amide, which is finally decomposed with sulphuric acid.
It is oxidized by nitric acid to d-saccharic and mucic acids; and acetic anhydride gives an octa-acetate.
Dorp (Ber.,1874,7,P.578) obtained orthobenzoyl benzoic acid by heating phthalic anhydride with benzene in the presence of aluminium chloride.
The hydroxide readily loses its water at a dull red heat and passes into anhydride with vivid incandescence.
In making the acid by this process benzaldehyde, acetic anhydride and anhydrous sodium acetate are heated for some hours to about 180 C., the resulting product is made alkaline with sodium carbonate, and any excess of benzaldehyde removed by a current of steam.Advertisement
Fittig and his pupils (Annalen, 1883, 216, pp. loo, 115; 1885, 227, pp. 55, 119), in which it was shown that the aldehyde forms an addition compound with the sodium salt of the fatty acid, and that the acetic anhydride plays the part of a dehydrating agent.
It is distinguished from the other members of the series by certain characteristic properties; for example, it shows an aldehydic character in reducing silver salts to metallic silver, and it does not form an acid chloride or an acid anhydride.
Chromium forms three series of compounds, namely the chromous salts corresponding to CrO, chromous oxide, chromic salts, corresponding to Cr203, chromium sesquioxide, and the chromates corresponding to Cr0,, chromium trioxide or chromic anhydride.
Heated with anhydrous sodium acetate and acetic anhydride it gives cinnamic acid; with ethyl bromide and sodium it forms triphenyl-carbinol (C 6 H 5) 3 C OH; with dimethylaniline and anhydrous zinc chloride it forms leuco-malachite green C6H5CH[C6H4N(CH3)2]2; and with dimethylaniline and concentrated hydrochloric acid it gives dimethylaminobenzhydrol, C 6 H 5 CH(OH)C 6 H 4 N(CH 3) 2.
The ethoxymethylene aceto-acetic esters are prepared by condensing aceto-acetic ester with ortho-formic ester in the presence of acetic anhydride (German patents 77354, 79087, 79863).Advertisement
Bamberger (Ber., 18 94, 27, p. 9 1 4) obtained the diazoic acids, R NH NO 2, substances which he had previously prepared by similarly oxidizing the diazonium salts, by dehydrating the nitrates of primary amines with acetic anhydride, and by the action of nitric anhydride on the primary amines.
Anthragallol is synthetically prepared by the condensation of benAoic and gallic acids with sulphuric acid OH i [[Cooh + I 10h - 2h20+ Hooc /Oh]] or from pyrogallol and phthalic anhydride in the presence of sulphuric acid or zinc chloride.
Succinic anhydride, C 2 H 4 (CO) 2 0, is obtained by heating the acid or its sodium salt with acetic anhydride; by the action of acetyl chloride on the barium salt; by distilling a mixture of succinic acid and succinyl chloride, or by heating succinyl chloride with anhydrous oxalic acid.
It forms an anhydride when heated.
It does not yield an anhydride, but when heated loses carbon dioxide and leaves a residue of propionic acid.Advertisement
Phosphorous acid, P(OH) 3, discovered by Davy in 1812, may be ' obtained by dissolving its anhydride, P 4 0 61 in cold water; by immersing sticks of phosphorus in a solution of copper sulphate contained in a well-closed flask, filtering from the copper sulphide and precipitating the sulphuric acid simultaneously formed by baryta water, and concentrating the solution in vacuo; or by passing chlorine into melted phosphorus covered with water, the first formed phosphorus trichloride being decomposed by the water into phosphorous and hydrochloric acids.
The re-formed nitrous acid, although not stable, any more than is its anhydride, N203, is nevertheless the j` oxygen carrier" in question, as the products of its spontaneous decomposition, when meeting with other compounds, always react like nitrous acid itself and thus may transfer an indefinite quantity of oxygen to the corresponding quantities of SO 2 and H 2 O, with the corresponding formation of H2S04.
It does not yield an anhydride.
The trans-acid is a racemic compound, which on heating with acetyl chloride gives the anhydride of the cis-acid.
The A l -' 4 acid is obtained as its anhydride by heating A 2.4 dihydrophthalic anhydride with acetic anhydride.
When heated for some time with acetic anhydride it changes to the cis-form.
Moissan (Comptes rendus, 1896, 122, p. 1297) obtained a vanadium containing from Io to 16% of carbon by fusing vanadic anhydride with carbon in the electric furnace.
Phthalimide, C6H4(CO)2NH, is formed by heating phthalic anhydride or chloride in ammonia gas or by molecular rearrangement of ortho-cyanbenzoic acid.
Unlike resorcin it does not give a fluorescein with phthalic anhydride.
By long heating the acid is converted into its anhydride, which, however, is obtained more readily by heating the silver salt of the acid with acetyl chloride.
Koppers makes carbon pitch, coal tar distillates, and phthalic anhydride and ships products to customers in rail cars.
Fumaric Acid is produced from petroleum feed stock (butane) via maleic anhydride.
Thus, in 1850 he predicted the existence of acetic anhydride, which was prepared in 1851.
The same reactions with acid anhydrides Ethanoic anhydride is the only one you are likely to come across for UK A level purposes.
We'll take ethanoyl chloride as a typical acyl chloride, and ethanoic anhydride as a typical acid anhydride.
Of the hygroscopic substances in common use, phosphoric anhydride, concentrated sulphuric acid, and dry potassium hydrate are almost equal in power; sodium hydrate and calcium chloride are not much behind.
Kulisch, Monats., 1894, 15, p. 276); by the action of phosphorus pentachloride on hydrocarbostyril (the inner anhydride of ortho-aminohydrocinnamic acid), the chlorinated compound first formed being then reduced by hydriodic acid (A.
The acid (and anhydride) are largely used in the colour industry (see Fluorescein; Phenol Phthalein) .
With regard to Graham's more purely chemical work, in 1833 he showed that phosphoric anhydride and water form three distinct acids, and he thus established the existence of polybasic acids, in each of which one or more equivalents of hydrogen are replaceable by certain metals (see Acid).