Aluminium-chloride Sentence Examples

Xanthene, C13H100, may be synthesized by condensing phenol with ortho-cresol in the presence of aluminium chloride.

Sainte Claire Deville working independently obtained aluminium by the electrolysis of the fused double sodium aluminium chloride.

Dorp (Ber.,1874,7,P.578) obtained orthobenzoyl benzoic acid by heating phthalic anhydride with benzene in the presence of aluminium chloride.

As a synthetical agent in organic chemistry, aluminium chloride has rendered possible more reactions than any other substance; here we can only mention the classic syntheses of benzene homologues.

Lagodzinski (Berichte, 1895, 28, p. 1427) has synthesized alizarin by condensing hemipinic acid [(CH30)2C6H2(COOH)2] with benzene in the presence of aluminium chloride.

It may be obtained synthetically by Fittig and Tollens's method (above); by Friedel and Craft's process, devised in 1877, of acting with aluminium chloride on a mixture of benzene and methyl chloride; this reaction leads to the production of higher homologues which may, however, break down under the continued action of the aluminium chloride; or by heating the toluene carboxylic acids obtained by oxidizing the higher homologues of benzene.

The thiophen ketones may be prepared by the interaction of thiophen and its homologues with acid chlorides in the presence of anhydrous aluminium chloride.