Aluminium-chloride sentence example

aluminium-chloride
  • Xanthene, C13H100, may be synthesized by condensing phenol with ortho-cresol in the presence of aluminium chloride.
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  • Sainte Claire Deville working independently obtained aluminium by the electrolysis of the fused double sodium aluminium chloride.
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  • Dorp (Ber.,1874,7,P.578) obtained orthobenzoyl benzoic acid by heating phthalic anhydride with benzene in the presence of aluminium chloride.
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  • As a synthetical agent in organic chemistry, aluminium chloride has rendered possible more reactions than any other substance; here we can only mention the classic syntheses of benzene homologues.
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  • Lagodzinski (Berichte, 1895, 28, p. 1427) has synthesized alizarin by condensing hemipinic acid [(CH30)2C6H2(COOH)2] with benzene in the presence of aluminium chloride.
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  • It may be obtained synthetically by Fittig and Tollens's method (above); by Friedel and Craft's process, devised in 1877, of acting with aluminium chloride on a mixture of benzene and methyl chloride; this reaction leads to the production of higher homologues which may, however, break down under the continued action of the aluminium chloride; or by heating the toluene carboxylic acids obtained by oxidizing the higher homologues of benzene.
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  • The thiophen ketones may be prepared by the interaction of thiophen and its homologues with acid chlorides in the presence of anhydrous aluminium chloride.
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