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acridine

acridine

acridine Sentence Examples

  • Similarly a CH group may be replaced by a nitrogen atom with the production of compounds of similar stability; thus benzene gives pyridine, naphthalene gives quinoline and isoquinoline; anthracene gives acridine and a and 3 anthrapyridines.

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  • The quinonoid structure of many coloured compounds has been proved experimentally, as, for example, by Hewitt for the benzene-azo-phenols, and Hantzsch for triaminotriphenyl methane and acridine derivatives; but, at the same time, many substances cannot be so explained.

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  • Chemie, 24, p. 468) submitted the view that fluorescence was due to the presence of certain " fluorophore " groups; such groupings are the pyrone ring and its congeners, the central rings in anthracene and acridine derivatives, and the paradiazine ring in safranines.

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  • This oscillation may be represented in the case of acridine and fluorescein as This theory brings the property of fluorescence into relation with that of colour; the forms which cause fluorescence being the coloured modifications: ortho-quinonoid in the case of acridine, paraquinonoid in the case of fluorescein.

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  • This tautomerism may be of a twofold nature :-(I) it may involve the mere oscillation of linkages, as in acridine; or (2) it may involve the oscillation of atoms, as in fluorescein.

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  • ACRIDINE, C13H9N, in chemistry, a heterocyclic ring compound found in crude coal-tar anthracene.

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  • It may be separated by shaking out with dilute sulphuric acid, and then precipitating the sulphuric acid solution with potassium bichromate, the resulting acridine bichromate being decomposed by ammonia.

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  • Many synthetic processes are known for the production of acridine and its derivatives.

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  • Formic acid yields acridine, and the higher homologues give derivatives substituted at the meso carbon atom, N N +[[Hcooh-C 6 H 5 /Inc6h5->C6h4 C6h4 Cho Ch N N +Ch 3 000h->C 6 H 5 /IC 6 H 5 --C 6 H 4 C6h4 Coch 3 C]](CH3) Acridine may also 1:e obtained by passing the vapour of phenylortho-toluidine through a red-hot tube (C. Graebe, Ber., 1884, 17, p. 1 37 0); by condensing diphenylamine with chloroform, in presence of aluminium chloride (0.

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  • Acridine and its homologues are very stable compounds of feebly basic character.

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  • Acridine crystallizes in needles which melt at 110° C. It is characterized by its irritating action on the skin, and by the blue fluorescence shown by solutions of its salts.

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  • Numerous derivatives of acridine are known and may be prepared by methods analogous to those used for the formation of the parent base.

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  • Acridine >>

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  • Anschutz (Ber., 1884, 1 7, p. 439) estimates picric acid by precipitation with acridine.

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  • Many derivatives are known, thus ortho-amino-benzophenone, melting at 106° C., can be obtained by reduction of the corresponding nitro compound; it condenses under the influence of heated lead monoxide to an acridine derivative and with acetone in presence of caustic soda it gives a quinoline.

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  • Acridinic acid (quinoline-a0dicarboxylic acid) is formed when acridine is oxidized by potassium permanganate (C. Gracbe and H.

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  • The next step was to use a fluorochrome (fluorescent stain) which is a powerful nuclear stain, namely, Acridine Orange.

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  • Similarly a CH group may be replaced by a nitrogen atom with the production of compounds of similar stability; thus benzene gives pyridine, naphthalene gives quinoline and isoquinoline; anthracene gives acridine and a and 3 anthrapyridines.

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  • a-pyrone condenses with the benzene ring to form coumarin and isocoumarin; benzo-'y-pyrone constitutes the nucleus of several vegetable colouring matters (chrysin, fisetin, quercetin, &c., which are derivatives of flavone or phenyl benzo-y-pyrone); dibenzo--ypyrone is known as xanthone; related to this substance are fluorane (and fluorescein), fluorone, fluorime, pyronine, &c. The pyridine ring condenses with the benzene ring to form quinoline and isoquinoline; acridine and phenanthridine are dibenzo-pyridines; naphthalene gives rise to a-and /3-naphthoquinolines and the anthrapyridines; anthracene gives anthraquinoline; while two pyridine nuclei connected by an intermediate benzene nucleus give the phenanthrolines.

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  • The quinonoid structure of many coloured compounds has been proved experimentally, as, for example, by Hewitt for the benzene-azo-phenols, and Hantzsch for triaminotriphenyl methane and acridine derivatives; but, at the same time, many substances cannot be so explained.

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  • Chemie, 24, p. 468) submitted the view that fluorescence was due to the presence of certain " fluorophore " groups; such groupings are the pyrone ring and its congeners, the central rings in anthracene and acridine derivatives, and the paradiazine ring in safranines.

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  • This oscillation may be represented in the case of acridine and fluorescein as This theory brings the property of fluorescence into relation with that of colour; the forms which cause fluorescence being the coloured modifications: ortho-quinonoid in the case of acridine, paraquinonoid in the case of fluorescein.

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  • This tautomerism may be of a twofold nature :-(I) it may involve the mere oscillation of linkages, as in acridine; or (2) it may involve the oscillation of atoms, as in fluorescein.

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  • ACRIDINE, C13H9N, in chemistry, a heterocyclic ring compound found in crude coal-tar anthracene.

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  • It may be separated by shaking out with dilute sulphuric acid, and then precipitating the sulphuric acid solution with potassium bichromate, the resulting acridine bichromate being decomposed by ammonia.

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  • Many synthetic processes are known for the production of acridine and its derivatives.

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  • Formic acid yields acridine, and the higher homologues give derivatives substituted at the meso carbon atom, N N +[[Hcooh-C 6 H 5 /Inc6h5->C6h4 C6h4 Cho Ch N N +Ch 3 000h->C 6 H 5 /IC 6 H 5 --C 6 H 4 C6h4 Coch 3 C]](CH3) Acridine may also 1:e obtained by passing the vapour of phenylortho-toluidine through a red-hot tube (C. Graebe, Ber., 1884, 17, p. 1 37 0); by condensing diphenylamine with chloroform, in presence of aluminium chloride (0.

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  • Acridine and its homologues are very stable compounds of feebly basic character.

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  • Acridine crystallizes in needles which melt at 110° C. It is characterized by its irritating action on the skin, and by the blue fluorescence shown by solutions of its salts.

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  • Numerous derivatives of acridine are known and may be prepared by methods analogous to those used for the formation of the parent base.

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  • Anschutz (Ber., 1884, 1 7, p. 439) estimates picric acid by precipitation with acridine.

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  • Many derivatives are known, thus ortho-amino-benzophenone, melting at 106° C., can be obtained by reduction of the corresponding nitro compound; it condenses under the influence of heated lead monoxide to an acridine derivative and with acetone in presence of caustic soda it gives a quinoline.

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  • Acridinic acid (quinoline-a0dicarboxylic acid) is formed when acridine is oxidized by potassium permanganate (C. Gracbe and H.

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  • a-pyrone condenses with the benzene ring to form coumarin and isocoumarin; benzo-'y-pyrone constitutes the nucleus of several vegetable colouring matters (chrysin, fisetin, quercetin, &c., which are derivatives of flavone or phenyl benzo-y-pyrone); dibenzo--ypyrone is known as xanthone; related to this substance are fluorane (and fluorescein), fluorone, fluorime, pyronine, &c. The pyridine ring condenses with the benzene ring to form quinoline and isoquinoline; acridine and phenanthridine are dibenzo-pyridines; naphthalene gives rise to a-and /3-naphthoquinolines and the anthrapyridines; anthracene gives anthraquinoline; while two pyridine nuclei connected by an intermediate benzene nucleus give the phenanthrolines.

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