Acetyl-chloride sentence example

acetyl-chloride
  • (C 6 H 4 CO 2 H) 2 is obtained by continued heating of salicylic acid and acetyl chloride to 130140° C. It is an amorphous yellow mass which is easily soluble in alcohol.
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  • The syn-aldoximes or treatment with acetyl chloride readily lose water and yield nitriles; the anti-aldoximes as a rule are acetylated and do not yield nitriles.
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  • Triethyl silicol, (C2H5),Si OH, is a true alcohol, obtained by condensing zinc ethyl with silicic ester, the resulting substance of composition, (C2H5)3 SiOC2H51 with acetyl chloride yielding a chloro-compound (C2H5)3SiC1, which with aqueous ammonia yields the alcohol.
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  • Succinic anhydride, C 2 H 4 (CO) 2 0, is obtained by heating the acid or its sodium salt with acetic anhydride; by the action of acetyl chloride on the barium salt; by distilling a mixture of succinic acid and succinyl chloride, or by heating succinyl chloride with anhydrous oxalic acid.
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  • The trans-acid is a racemic compound, which on heating with acetyl chloride gives the anhydride of the cis-acid.
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  • By long heating the acid is converted into its anhydride, which, however, is obtained more readily by heating the silver salt of the acid with acetyl chloride.
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  • (C 6 H 4 CO 2 H) 2 is obtained by continued heating of salicylic acid and acetyl chloride to 130140° C. It is an amorphous yellow mass which is easily soluble in alcohol.
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  • Butlerow in 1864 by acting with zinc methyl on acetyl chloride (see Alcohols).
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  • The same type of reaction occurs when the metal is relatively electro-positive to the added radical, for example, with ethyl isocyanide and acetyl chloride (see above); compare also AgNC --AgN(:Cl 000H 3)C -->AgCl+CH,000N.
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