Acetyl-chloride sentence example

acetyl-chloride
  • CN, may be prepared by the action of silver cyanide on acetyl chloride; or of acetyl chloride on nitrosoacetone (L.
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  • (C 6 H 4 CO 2 H) 2 is obtained by continued heating of salicylic acid and acetyl chloride to 130140° C. It is an amorphous yellow mass which is easily soluble in alcohol.
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  • The syn-aldoximes or treatment with acetyl chloride readily lose water and yield nitriles; the anti-aldoximes as a rule are acetylated and do not yield nitriles.
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  • Triethyl silicol, (C2H5),Si OH, is a true alcohol, obtained by condensing zinc ethyl with silicic ester, the resulting substance of composition, (C2H5)3 SiOC2H51 with acetyl chloride yielding a chloro-compound (C2H5)3SiC1, which with aqueous ammonia yields the alcohol.
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  • It is a gas at ordinary temperature, and may be liquefied, the liquid boiling at -5° C. It combines with acetyl chloride in the presence of zinc chloride to form a ketone, which on warming breaks down into hydrochloric acid and mesityl oxide (I.
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  • soc. chim., 18 95, (3) 1 3, p. 735); and from the syn-aldoximes by the action of acetyl chloride or acetic anhydride.
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  • Succinic anhydride, C 2 H 4 (CO) 2 0, is obtained by heating the acid or its sodium salt with acetic anhydride; by the action of acetyl chloride on the barium salt; by distilling a mixture of succinic acid and succinyl chloride, or by heating succinyl chloride with anhydrous oxalic acid.
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  • The trans-acid is a racemic compound, which on heating with acetyl chloride gives the anhydride of the cis-acid.
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  • By long heating the acid is converted into its anhydride, which, however, is obtained more readily by heating the silver salt of the acid with acetyl chloride.
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  • Acetyl-salicylic acid (salacetic acid), C 6 H 4 (O 000H 3) CO 2 H, is obtained by the action of acetyl chloride on the acid or its sodium salt (K.
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  • (C 6 H 4 CO 2 H) 2 is obtained by continued heating of salicylic acid and acetyl chloride to 130140° C. It is an amorphous yellow mass which is easily soluble in alcohol.
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  • Butlerow in 1864 by acting with zinc methyl on acetyl chloride (see Alcohols).
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  • The ketoximes by the action of acetyl chloride undergo a peculiar inframolecular re-arrangement known as the Beckmann trans formation (E.
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  • It can be prepared by distilling a mixture of dry calcium benzoate and acetate, Ca(O2CC6H5)2 + (CH3CO2)2Ca = 2CaCO3 + 2 C6H5CO.CH3, or by condensing benzene with acetyl chloride in the presence of anhydrous aluminium chloride (C. Friedel and J.
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  • It is a gas at ordinary temperature, and may be liquefied, the liquid boiling at -5° C. It combines with acetyl chloride in the presence of zinc chloride to form a ketone, which on warming breaks down into hydrochloric acid and mesityl oxide (I.
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  • The same type of reaction occurs when the metal is relatively electro-positive to the added radical, for example, with ethyl isocyanide and acetyl chloride (see above); compare also AgNC --AgN(:Cl 000H 3)C -->AgCl+CH,000N.
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