The wall of the tube is very thin and delicate, and does not seem to be composed of cellulose or any modification of it.
The 1 The composition of the cellulose nitrates was reviewed by G.
The constitution of guncotton is a difficult matter to investigate, primarily on account of the very insoluble nature of cellulose itself, and also from the fact that comparatively slight variations in the concentration and temperature of the acids used produce considerable differences in the products.
Cellulose, the material of which vegetable cell-walls are almost universally composed, at any rate in their early condition, is known to occur, though only seldom, among animal organisms. Such forms as Volvox and the group of the Myxomycetes have been continually referred to both kingdoms, and their true systematic position is still a subject of controversy.
The formation of living substance is a process of building up from simple or relatively simple materials; the construction of its cellulose framework and supporting substance is done by the living substance after its own formation is completed, and is attended by a partial decomposition of such living substance.
Soc., 1901, 23, p. 527), who, assuming the formula C24H4 6 O 20 for cellulose, showed how the nitrocelluloses described by different chemists may be expressed by the formula C24H4,..-z020(N02)s, where x has the values 4, 5, 6, ...
In the recent methods the cotton remains in contact with the acids for two to four hours at the ordinary air temperature (15° C.), in which time it is almost fully nitrated, the main portion, say 90%, having a composition represented by the formula e C6H702(N03)3, the remainder consisting of lower nitrated products, some oxidation products and traces of unchanged cellulose and cellulose sulphates.
Strong or weak solutions of these substances also decompose it, producing some alkali nitrate and nitrite, the cellulose molecule being only partially restored, some quantity undergoing oxidation.
It is now known to have nothing in common with vegetable cellulose, but is regarded as one of the many albuminoid substances existing in the body under pathological conditions.
These are peculiar bodies which are found in the prostate, in the central nervous system, in the lung, and in other localities, and which get their name from being very like starch-corpuscles, and from giving certain colour reactions closely resembling those of vegetable cellulose or even starch itself.
D-Mannose, first prepared by oxidizing d-mannite, found in plants and manna-ash (Fraxinus ornus), was obtained by Tollens and Gans on hydrolysing cellulose and by Reis from seminine (reserve cellulose), found in certain plant seeds, e.g.
Kellner, who in 1886 patented the use of cathode (caustic soda) and anode (chlorine) liquors in the manufacture of cellulose from wood-fibre, and has since evolved many similar processes, has produced an apparatus that has been largely used.
Sugar, starch and cellulose) by nitric acid, and also by the fusion of many oxygen-holding compounds with caustic alkalis, this latter method being employed for the manufacture of oxalic acid.
In this process cellulose (in the form of sawdust) is made into a stiff paste with a mixture of strong caustic potash and soda solution and heated in flat iron pans to 20o-250 C. The somewhat dark-coloured mass is lixiviated with a small amount of warm water in order to remove excess of alkali, the residual alkaline oxalates converted into insoluble calcium oxalate by boiling with milk of lime, the lime salt separated, and decomposed by means of sulphuric acid.
An animal may be defined as a living organism, the protoplasm of which does not secrete a cellulose cell-wall, and which requires for its existence proteid material obtained from the living or dead bodies of existing plants or animals.
P. 865), the agents of the transformation of cellulose into peaty substances are saprophytic fungi and bacterial ferments.
The industries of Konigsberg have made great advances within recent years, notable among them are printing-works and manufactures of machinery, locomotives, carriages, chemicals, toys, sugar, cellulose, beer, tobacco and cigars, pianos and amber wares.
Filtration in the chemical laboratory is commonly effected by the aid of a special kind of unsized paper, which in the more expensive varieties is practically pure cellulose, impurities like feric oxide, alumina, lime, magnesia and silica having been removed by treatment with hydrochloric and hydrofluoric acids.
The wall of the hyphae of the fungus give in the young state the ordinary reactions of cellulose but older material shows somewhat different reactions, similar to those of the so-called fungus-cellulose.
While the fundamental constituent is a cellulose in many Mucorini and other Phycomycetes, in others bodies like pectose, callose, &c., commonly occur, and Wisselingh's researches show that chitin, a gluco-proteid common in animals, forms the main constituent in many cases, and is probably deposited directly as such, though, like the other substances, it may be mixed with cellulose.
The wall consists of a basis of cellulose, and in some cases readily breaks up into a definite number of plates, fitting into one another like the plates of the carapace of a tortoise; it is, moreover, often finely sculptured or coarsely ridged and flanged.
With reference to their chemical physiology, the gelatinization of the cell-wall, which is so marked a feature, is doubtless attributable to the occurrence along with cellulose of pectic compounds.
The other industries of the town, notably dyeing, stuff-printing and stamping, are very considerable, and there are also engineering and machine shops, chemical, cellulose, soap, and other factories, breweries, distilleries and tanneries.
But all cells which are permanent tissue-elements of the plantbody possess, in addition, a more or less rigid limiting membrane or cell-wall, consisting primarily of cellulose or some allied substance.
This consists of elongated cells with cellulose walls, which are locall~ thickened along the original corners of the cells, reducing the lumer to a cylinder, so that a number of vertical pillars of cellulose con nected by comparatively thin walls form the framework of th~ tissue.
The peculiar substance called callose, chemically allied to cellulose, is frequently formed over the surface of the perforated end-walls.
The inability to enter the cells may be due to the lack of chemotactic bodies, to incapacity to form cellulose-dissolving enzymes, to the existence in the hostcells of antagonistic bodies which neutralize or destroy the acids, enzymes or poisons formed by the hyphae, or even to the formation and excretion of bodies which poison the Fungus.
It is probable that most, if not all, the metabolic changes which take place in a cell, such as the transformation of starch, proteids, sugar, cellulose; and the decomposition -of numerous other organic substances which would otherwise require a high temperature or powerful reagents is also due to their activity.
Cell Membrane.The membrane which surrounds the protoplasts in the majority of plants is typically composed of cellulose, together with a number of other substances which are known as pectic compounds.
They can be distinguished by their insolubility in cupramfnonia, which dissolves cellulose, and by their behaviour towards stains, some of which stain pectic substances but not cellulose.
In the Fungi it is usually composed of a modified form of cellulose known as fungus cellulose, which, according to Mangin, consists of callose in combination either with cellulose or pectic compounds.
Both cuticularized and suberized membranes are insoluble in cuprammonia, and are colored yellow or brown in a soltition of chlor-iodide of zinc. It is probable that the corky or suberized cells do not contain any cellulose (Gilson, Wisselingh); whilst cuticularized cells are only modified in their outer layers, cellulose inner layers being still recognizable.
The suberized and cuticularized cell-walls appear to contain a fatty body called suberin, and such cell-walls can be stained red by a solution of alcanin, the lignified and cellulose membranes remaining unstained.
According to Lecointe, the young wall consists partly of cellulose and partly of a substance which is not cellulose, the latter existing in the form of slight depressions, which mark the position of the future pores.
They are present from the beginning of the development of the cell-wail, and arise from the spindle fibres, all of which may be continued as connecting threads (endosperm of Tamus communis), or part of them may be overlaid by cellulose lamellae (endosperm of Lilium Martagon), or they may be all overlaid as in pollen mother-cells and pollen grains of Helleborus foetidus.
It appears to be synthesized in the plant tissues from carbon dioxide and water, formaldehyde being an intermediate product; or it may be a hydrolytic product of a glucoside or of a polysaccharose, such as cane sugar, starch, cellulose, &c. In the plant it is freely converted into more complex sugars, poly-saccharoses and also proteids.
GUNCOTTON, an explosive substance produced by the action of strong nitric acid on cellulose at the ordinary temperature; chemically it is a nitrate of cellulose, or a mixture of nitrates, according to some authorities.
Crum was probably the first to recognize that some hydrogen atoms of the cellulose had been replaced by an oxide of nitrogen, and this view was supported more or less by other workers, especially Hadow, who appears to have distinctly recognized that at least three compounds were present, the most violently explosive of which constituted the main bulk of the product commonly obtained and known as guncotton.
The smallest empirical formula for cellulose (q.v.) may certainly be written C6H1005.
The oldest and perhaps most reasonable idea represents guncotton as cellulose trinitrate, but this has been much disputed, and various formulae, some based on cellulose as C, 2 H200 10, others on a still more complex molecule, have been proposed.
The products of the action of nitric acid on cellulose are not nitro compounds in the sense that picric acid is, but are nitrates or nitric esters.
Cellulose sulphates are one, and possibly the main, cause of instability in guncotton, and it is highly desirable that they should be completely hydrolysed and removed in the washing process.
Coloured and white paper, ready-made clothing, cellulose, tobacco, lime and liqueurs are the chief manufactures, while a considerable export trade is done down the Main in wood, cattle and wine.
If a thin cellulose membrane is interposed between the lamellae, the hyphae nevertheless turn chemotropically from the one lamella to the other and pierce the cellulose membrane in the process.
Cellulose Chlorophyll and wax Caffeine .
The mature pollengrain is, like other spores, a single cell; except in the case of some submerged aquatic plants, it has a double wall, a thin delicate wall of unaltered cellulose, the endospore or intine, and a tough outer cuticularized exospore or extine.
When it persists as a massive element of the seed its nutritive function is usually apparent, for there is accumulated within its cells reserve-food, and according to the dominant substance it is starchy, oily, or rich in cellulose, mucilage or proteid.
Valoniaceae and The thallus is of more varied structure in this group than in any Dasycladaceae are partially septate, but elsewhere no cellulose partiother.
The cell-wall of the higher plants, it gives usually no react i ons of cellulose, nor is chitin present as in the fungi, but it consists of a proteid substance and is apparently a modification of the general protoplasm.
Among the enzymes already extracted from fungi are invertases (yeasts, moulds, &c.), which split cane-sugar and other complex sugars with hydrolysis into simpler sugars such as dextrose and levulose; diastases, which convert starches into sugars (Aspergillus, &c.); cytases, which dissolve cellulose similarly (Botrytis, &c.); peptases, using the term as a general one for all enzymes which convert proteids into peptones and other bodies (Penicillium, &c.); lipases, which break up fatty oils (Empusa, Phycomyces, &c.); oxydases, which bring about the oxidations and changes of colour observed in Boletus, and zymase, extracted by Buchner from yeast, which brings about the conversion of sugar into alcohol and carbondioxide.
Cellulose has an affinity for acid stains, pectic substances for basic stains.
Both the oxide and hydroxide dissolve in ammonia to form a beautiful azure-blue solution (Schweizer's reagent), which dissolves cellulose, or perhaps, holds it in suspension as water does starch; accordingly, the solution rapidly perforates paper or calico.
Such cellulose is gradually reconverted into water and carbon dioxide, but for some time nothing positive was known as to the agents which thus break up the paper, rags, straw, leaves and wood, &c., accumulating in cesspools, forests, marshes and elsewhere in such abundance.
The work of van Tieghem, van Senus, Fribes, Omeliansky and others has now shown that while certain anaerobic bacteria decompose the substance of the middle lamella - chiefly pectin compounds - and thus bring about the isolation of the cellulose fibres when, for instance, flax is steeped or " retted," they are unable to attack the cellulose itself.
There exist in the mud of marshes, rivers and cloacae, &c., however, other anaerobic bacteria which decompose cellulose, probably hydrolysing it first and then splitting the products into carbon dioxide and marsh gas.
We have thus an explanation of the occurrence of marsh gas and sulphuretted hydrogen in bogs, and it is highly probable that the existence of these gases in the intestines of herbivorous animals is due to similar putrefactive changes in the undigested cellulose remains.
In marshes, estuaries, sulphur springs, &c. When cellulose bacteria set free FIG.
As the sieve plate grows these non-cellulose regions swell and gradually become converted into the same kind of mucous substance as that contained in the tube; the two cells are thus placed in open communication.
Other industries are the manufacture of cellulose, artificial manure, flour and malt; and there are saw-mills, iron foundries and breweries in the town.
In addition to being the principal emporium for the Austrian traffic on the Elbe, Tetschen has a considerable industry, its products comprising chemicals, oil, soap, cotton stuffs, plaster of Paris, glazed and coloured paper, cellulose, beer, flour and preserved fish.
In recent years the growth of the leaf under cloth tents has greatly increased, as it has been abundantly proved that the product thus secured is much more valuable - lighter in colour and weight, finer in texture, with an increased proportion of wrapper leaves, and more uniform qualities, and with lesser amounts of cellulose, nicotine, gums and resins.
The swollen cell-walls - in some cases consists mainly of cellulose, in others chiefly of a proteid substance; the matrix in some cases is horny and resistant, in others more like a thick solution of gum.
The enormous masses of cellulose deposited annually on the earth's surface are, as we know,!