Both the iodide and bromide are used in photography.
The bromide, CoBr 2, resembles the chloride, and may be prepared by similar methods.
Boron bromide BBr 3 can be formed by direct union of the two elements, but is best obtained by the method used for the preparation of the chloride.
Iodide and chloro-bromide of silver, and argentiferous Silver lead ores, the largest deposits of the metal being found in the last-mentioned form.
A ray of light is directed upon the mirror, and the motion of the latter, due to the varying strengths and direction of the received currents, is made to write the transmitted signals upon a strip of bromide photographic paper about three inches wide.
The bromide paper is automatically passed through a developing bath, a fixing bath, and drying rollers.
The chloride,CdC1 2, bromide,CdBr 2, and iodide,Cdl2,arealsoknown, cadmium iodide being sometimes used in photography, as it is one of the few iodides which are soluble in alcohol.
Sulphur bromide, S 2 Br 2, is a dark red liquid which boils with decomposition at about 200° C. The products obtained by the action of iodine on sulphur are probably mixtures, although E.
The acid is considered to possess the structure 0 2 S(SH) (OH), since sodium thiosulphate reacts with ethyl bromide to give sodium ethyl thiosulphate, which on treatment with barium chloride gives presumably barium ethyl thiosulphate.
The chloro-bromide and bromide of silver were also included under this term until they were distinguished chemically in 1841 and 1842, and described under the names embolite and bromargyrite (or bromyrite) respectively; the chloride then came to be distinguished as chlorargyrite, though the name cerargyrite is often now applied to this alone.
An, matter), formed the basis of benzaldehyde, benzoic acid, benzoyl chloride, benzoyl bromide and benzoyl sulphide, benzamide and benzoic ether.
It was long supposed that the simplest ring obtainable contained six atoms of carbon, and the discovery of trimethylene in 1882 by August Freund by the action of sodium on trimethylene bromide, Br(CH 2) 3 Br, came somewhat as a surprise, especially in view of its behaviour with bromine and hydrogen bromide.
But on the other hand, it is readily converted by hydrobromic acid into normal propyl bromide, CH 3 CH 2 CH 2 Br.
The halogens may be sometimes detected by fusing with lime, and testing the solution for a bromide, chloride and iodide in the usual way.
Hydrocarbons of similar structure have been prepared by Thiele, for example, the orange-yellow tetraphenyl-para-xylylene, which is obtained by boiling the bromide C6H4[CBr(C6H5)2]2 with benzene and molecular silver.
When heated with the halogens, acetophenone is substituted in the aliphatic portion of the nucleus; thus bromine gives phenacyl bromide, C6H6CO.CH2Br.
Acetonyl-acetophenone, C6H5.CO.CH2.CH2.CO.CH3, is produced by condensing phenacyl bromide with sodium acetoacetate with subsequent elimination of carbon dioxide, and on dehydration gives aa-phenyl-methyl-furfurane.
Oxazoles are produced on condensing phenacyl bromide with acid-amides (M.
Lead bromide, PbBr 2, a white solid, and lead iodide, PbI 21 a yellow solid, are prepared by precipitating a lead salt with a soluble bromide or iodide; they resemble the chloride in solubility.
It is formed when the vapours of toluene, stilbene, dibenzyl, ortho-ditolyl, or coumarone and benzene are passed through a red-hot tube; by distilling morphine with zinc dust; and, with anthracene, by the action of sodium on ortho-brombenzyl bromide (C. L.
Stannous bromide, SnBr 2, is a light yellow substance formed from tin and hydrobromic acid.
Stannic bromide, SnBr 4, is a white crystalline mass, melting at 33° and boiling at 201°, obtained by the combination of tin and bromine, preferably in carbon bisulphide solution.
CYANAMIDE, NC NH 2j the amide of normal cyanic acid, obtained by the action of ammonia on cyanogen chloride, bromide or iodide, or by the desulphurization of thio-urea with, mercuric oxide; it is generally prepared by the latter process.
Hydriodic acid reduces it to hexamethylene" (cyclo-hexane or hexa-hydro-benzene); chlorine and bromine form substitution and addition products, but the action is slow unless some carrier such as iodine, molybdenum chloride or ferric chloride for chlorine, and aluminium bromide for bromine, be present.
It may be obtained from storax by distillation with water, and synthetically by heating cinnamic acid with lime, by the action of aluminium chloride on a mixture of vinyl bromide and benzene, by removing the elements of hydrobromic acid from bromethylbenzene by means of alcoholic potash, or, best, by treating (-bromhydrocinnamic acid with soda, when it yields styrolene, carbon dioxide and hydrobromic acid.
The a-halogen compounds are obtained by heating styrolene chloride (or bromide) with lime or alcoholic potash; they are liquids which have a penetrating odour, and yield acetophenone when heated with water to 180°.
Stilbene bromide when treated with alcoholic potash gives diphenyl acetylene or tolane, C6H5 C: C CsH5.
Zinc bromide, ZnBr 2, and Zinc iodide, Zn12, are deliquescent solids formed by the direct union of their elements.
It is formed by the condensation of acetylene tetrabromide with benzene in the presence of aluminium chloride: Br CH Br CH C H +C6H6=4HBr+C6H4) I, )C6H4, Br CH Br CH and similarly from methylene dibromide and benzene, and also when benzyl chloride is heated with aluminium chloride to 200° C. By condensing ortho-brombenzyl bromide with sodium, C. L.
NH 2, is prepared by the action of ammonia on trimethylene bromide (E.
Chem-., 1905, 47, p. 1 45), who, by estimating the ratios of strontium bromide and chloride to silver, obtained the values 87.663 and 87.661.
Heated with anhydrous sodium acetate and acetic anhydride it gives cinnamic acid; with ethyl bromide and sodium it forms triphenyl-carbinol (C 6 H 5) 3 C OH; with dimethylaniline and anhydrous zinc chloride it forms leuco-malachite green C6H5CH[C6H4N(CH3)2]2; and with dimethylaniline and concentrated hydrochloric acid it gives dimethylaminobenzhydrol, C 6 H 5 CH(OH)C 6 H 4 N(CH 3) 2.
The only trace we can find at present is in ethyl bromide, in which the radical band about 90o is curtailed in one wing.
The difference between amyl iodide and amyl bromide is not sufficiently marked to be of any value."
The bromide and iodide are formed in a similar manner by heating the metal in gaseous hydrobromic or hydriodic acids.
Chromic salts are of a blue or violet colour, and apparently the chloride and bromide exist in a green and violet form.
Chromic bromide, CrBr 3, is prepared in the anhydrous form by the same method as the chloride, and resembles it in its properties.
Chlorates); but it is manufactured by acting with bromine water on iron filings and decomposing the iron bromide thus formed with potassium carbonate.
The action of potassium bromide and potassium iodide has been treated under bromine and iodine (q.v.).
The bromide and iodide crystallize from hot solutions in anhydrous cubes; from solutions at ordinary temperatures in monoclinic prisms with 2H 2 O; and at low temperatures with 5H 2 O.
Above), also known as diethylene diamine, may be prepared by reducing pyrazine, or, better, by combining aniline and ethylene bromide to form diphenyl diethylene diamine, the dinitroso compound of which hydrolyses to para-dinitrosophenol and pipera zine.
Whereas calcium chloride, bromide, and iodide are deliquescent solids, the fluoride is practically insoluble in water; this is a parallelism to the soluble silver fluoride, and the insoluble chloride, bromide and iodide.