Cobalt fluoride, CoF 2.2H 2 0, is formed when cobalt carbonate is evaporated with an excess of aqueous hydrofluoric acid, separating in rose-red crystalline crusts.
Berglund (Berichte, 18 74, 7, p. 469), in aqueous solution, by dissolving ammonium cobaltocobaltisulphite (NH4)2C02 [(S03) 6 'C02] 14H 2 O in dilute hydrochloric or nitric acids, or by decomposition of its silver salt with hydrochloric acid.
By the addition of excess of ammonia to its aqueous solution, in the complete absence of air, a blue precipitate of a basic nitrate of the composition 6C00 N 2 0 6 5H 2 O is obtained.
They form yellow or bronze-coloured crystals, which decompose on boiling their aqueous solution.
The aqueous solution, however, does not show the ordinary reactions of cobalt or of ammonia, and so it is to be presumed that the salt ionizes into [Co(NH 3) 6] and 3C1'.
The aqueous solution is turned bluish black by ferrous sulphate containing a ferric salt.
It dissolves readily in water and the aqueous solution decomposes on standing; a dark-brown flocculent precipitate of azulmic acid, C 4 H 5 N 5 0, separating whilst ammonium oxalate, urea and hydrocyanic acid are found in the solution.
In aqueous solution it gives a red colour with ferric chloride.
The alkaloid is obtained from an aqueous extract of tobacco by distillation with slaked lime, the distillate being acidified with oxalic acid, concentrated to a syrup and decomposed by potash.
Nicotimine is a colourless liquid which boils at 250 0 -255° C. Its aqueous solution is alkaline.
Cadmium chloride and iodide have been shown to behave in an anomalous way in aqueous solution (W.
Cadmium sulphate, CdSO 4, is known in several hydrated forms; being deposited, on spontaneous evaporation of a concentrated aqueous solution, in the form of large monosymmetric crystals of composition 3CdSO 4.8H 2 O, whilst a boiling saturated solution, to which concentrated sulphuric acid has been added, deposits crystals of composition CdSO 4 4H 2 0.
The aqueous vapour in the atmosphere is transparent to luminous but opaque to obscure heat-rays.
It is also readily soluble in solutions of the caustic alkalis, slightly soluble in aqueous ammonia solution, and almost insoluble in sodium carbonate solution.
The ortho-acid, in the form of its aqueous solution, is sometimes used as an antiseptic, under the name of aseptol.
The colloidal sulphur, Ss, described by Debus as a product of the interaction of sulphuretted hydrogen and sulphur dioxide in aqueous solution, is regarded by Spring (Rec. tra y.
Hyposulphurous acid, H 2 S 2 0 4, was first really obtained by Berthollet in 1789 when he showed that iron left in contact with an aqueous solution of sulphur dioxide dissolved without any evolution of gas, whilst C. F.
Its aqueous solution gradually decomposes with evolution of oxygen, behaves as a strong oxidant, and liberates iodine from potassium iodide.
The free acid is obtained (in dilute aqueous solution) by the addition of dilute sulphuric acid to an aqueous solution of the barium salt.
It is only stable in dilute aqueous solution, for on concentration the acid decomposes with formation of sulphuric acid, sulphur dioxide and sulphur.
Soc., 1888, 53, p. 278) is prepared by passing sulphuretted hydrogen gas into a nearly saturated aqueous solution of sulphur dioxide at about o° C. The solution is then allowed to stand for 48 hours and the process repeated many times until the sulphur dioxide is all decomposed.
The aqueous solution of the acid is fairly stable at ordinary temperatures.
It behaves as a strong oxidant and in aqueous solution is slowly hydrolysed.
In this way it is believed that the sub-aqueous cocoon in which the pupal stage is passed becomes filled with air.
The fouling of the air that results from the steam-engine, owing to the production of carbonic acid gas and of sulphurous fumes and aqueous vapour, is well known, and its use is now practically abandoned for underground working.
Hess now observed that in the process of mixing such neutral solutions no thermal effect was produced - that is, neutral salts in aqueous solution could apparently interchange their radicals without evolution or absorption of heat.
Thomsen by direct experiment found that the heat-capacity of a dilute aqueous solution diverged in general less than i per cent.
Represents the heat of neutralization of one gramme-equivalent of caustic soda with nitric acid, each in dilute aqueous solution before being brought into contact.
It has already been stated that the heats of neutralization of acids and bases in aqueous solution are additively composed of two terms, one being constant for a given base, the other constant for a given acid.
In the ordinary process of soap-making the glycerin remains dissolved in the aqueous liquors from which the soap is separated.
Its viscid character, and its non-liability to dry and harden by exposure to air, also fit it for various other uses, such as lubrication, &c., whilst its peculiar physical characters, enabling it to blend with either aqueous or oily matters under certain circumstances, render it a useful ingredient in a large number of products of varied kinds.
Aqueous and alcoholic solutions of ammonia convert carbon bisulphide into ammonium dithiocarbamate, which readily breaks down into ammonium thiocyanate and sulphuretted hydrogen (A.
Carbon bisulphide combines with primary amines to form alkyl dithiocarbamates, which when heated lose sulphuretted hydrogen and leave a residue of a dialkyl thio-urea, CS 2 +2R NH 2 - R NH CSS NH 3 RCS(NHR)2+H2S; or if the aqueous solution of the dithiocarbamate be boiled with mercuric chloride or silver nitrate solution, a mustard oil (q.v.) is formed, R.NH CSS NH3R+HgC12-Hg(R NH CSS)2->2RNCS-}-HgS+H2S.
It forms a characteristic explosive silver salt on the addition of ammoniacal silver nitrate to its aqueous solution, and an amorphous precipitate which explodes on warming with ammoniacal cuprous chloride.
The phlogistonists endeavoured to introduce chemical notions to support it: Becher, in his Physica subterranea (1669), stated that mineral, vegetable and animal matter contained the same elements, but that more simple combinations prevailed in the mineral kingdom; while Stahl, in his Specimen Becherianum (1702), held the " earthy " principle to predominate in the mineral class, and the " aqueous " and " combustible " in the vegetable and animal classes.
This substance, and also the preceding compound, is converted by aqueous caustic soda into dichlormaleic acid, trichlorethylene, and hydrochloric acid (5) (Th.
From these results Baeyer concluded that Claus' formula with three para-linkings cannot possibly be correct, for the Q2.5 dihydroterephthalic acid undoubtedly has two ethylene linkages, since it readily takes up two or four atoms of bromine, and is oxidized in warm aqueous solution by alkaline potassium permanganate.
Telluric acid forms cubic and monoclinic crystals from a hot nitric acid solution, and ammonium fluosilicate gives cubic and hexagonal forms from aqueous solutions between 6° and 13°.
Ferric chloride colours its aqueous solution violet.
In aqueous solution the free acid acts as an oxidizing agent, bleaching indigo and liberating iodine from potassium iodide, or it may act as a reducing agent since it readily tends to pass into nitric acid: consequently it discharges the colour of acid solutions of permanganates and chromates.
It is somewhat volatile at ordinary temperature, and its aqueous solution possesses a strongly acid reaction.
In aqueous solutions, for instance, a few hydrogen (H) and hydroxyl (OH) ions derived from the water are always present, and will be liberated if the other ions require a higher decomposition voltage and the current be kept so small that hydrogen and hydroxyl ions can be formed fast enough to carry all the current across the junction between solution and electrode.
This leads us to examine more closely the part played by water in the electrolysis of aqueous solutions.
If an aqueous solution of methyl acetate be allowed to stand, a slow decomposition goes on.
The temperature coefficient of conductivity has approximately the same value for most aqueous salt solutions.
This product melts at 86° C., and becomes anhydrous when heated to 110° C. The anhydrous compound can also be prepared, as hard crusts melting at 146°, by crystallizing concentrated aqueous solutions at 30 to 35°.
Aqueous non-oxidizing acids generally have little or no action on lead in the absence of air.
These are knocked off, ground up with water, freed from metal-particles by elutriation, and the paste of white lead is allowed to set and dry in small conical forms. The German method differs from the Dutch inasmuch as the lead is suspended in a large chamber heated by ordinary means, and there exposed to the simultaneous action of vapour of aqueous acetic acid and of carbon dioxide.
Lead nitrate, Pb(N03)2, is obtained by dissolving the metal or oxide in aqueous nitric acid; it forms white crystals, difficultly soluble in cold water, readily in hot water and almost insoluble in strong nitric acid.
Lead acetate, Pb(C2H302)2.3H20 (called "sugar" of lead, on account of its sweetish taste), is manufactured by dissolving massicot in aqueous acetic acid.