Telluric acid forms cubic and monoclinic crystals from a hot nitric acid solution, and ammonium fluosilicate gives cubic and hexagonal forms from aqueous solutions between 6° and 13°.
In aqueous solution it gives a red colour with ferric chloride.
The colloidal sulphur, Ss, described by Debus as a product of the interaction of sulphuretted hydrogen and sulphur dioxide in aqueous solution, is regarded by Spring (Rec. tra y.
It is only stable in dilute aqueous solution, for on concentration the acid decomposes with formation of sulphuric acid, sulphur dioxide and sulphur.
Represents the heat of neutralization of one gramme-equivalent of caustic soda with nitric acid, each in dilute aqueous solution before being brought into contact.
Cobalt fluoride, CoF 2.2H 2 0, is formed when cobalt carbonate is evaporated with an excess of aqueous hydrofluoric acid, separating in rose-red crystalline crusts.
They form yellow or bronze-coloured crystals, which decompose on boiling their aqueous solution.
The free acid is obtained (in dilute aqueous solution) by the addition of dilute sulphuric acid to an aqueous solution of the barium salt.
Soc., 1888, 53, p. 278) is prepared by passing sulphuretted hydrogen gas into a nearly saturated aqueous solution of sulphur dioxide at about o° C. The solution is then allowed to stand for 48 hours and the process repeated many times until the sulphur dioxide is all decomposed.
Ferric chloride colours its aqueous solution violet.
This product melts at 86° C., and becomes anhydrous when heated to 110° C. The anhydrous compound can also be prepared, as hard crusts melting at 146°, by crystallizing concentrated aqueous solutions at 30 to 35°.
It dissolves readily in water and the aqueous solution decomposes on standing; a dark-brown flocculent precipitate of azulmic acid, C 4 H 5 N 5 0, separating whilst ammonium oxalate, urea and hydrocyanic acid are found in the solution.
The alkaloid is obtained from an aqueous extract of tobacco by distillation with slaked lime, the distillate being acidified with oxalic acid, concentrated to a syrup and decomposed by potash.
Nicotimine is a colourless liquid which boils at 250 0 -255° C. Its aqueous solution is alkaline.
Cadmium sulphate, CdSO 4, is known in several hydrated forms; being deposited, on spontaneous evaporation of a concentrated aqueous solution, in the form of large monosymmetric crystals of composition 3CdSO 4.8H 2 O, whilst a boiling saturated solution, to which concentrated sulphuric acid has been added, deposits crystals of composition CdSO 4 4H 2 0.
It is also readily soluble in solutions of the caustic alkalis, slightly soluble in aqueous ammonia solution, and almost insoluble in sodium carbonate solution.
The ortho-acid, in the form of its aqueous solution, is sometimes used as an antiseptic, under the name of aseptol.
Hyposulphurous acid, H 2 S 2 0 4, was first really obtained by Berthollet in 1789 when he showed that iron left in contact with an aqueous solution of sulphur dioxide dissolved without any evolution of gas, whilst C. F.
Its aqueous solution gradually decomposes with evolution of oxygen, behaves as a strong oxidant, and liberates iodine from potassium iodide.
The aqueous solution of the acid is fairly stable at ordinary temperatures.
It behaves as a strong oxidant and in aqueous solution is slowly hydrolysed.
In this way it is believed that the sub-aqueous cocoon in which the pupal stage is passed becomes filled with air.
The fouling of the air that results from the steam-engine, owing to the production of carbonic acid gas and of sulphurous fumes and aqueous vapour, is well known, and its use is now practically abandoned for underground working.
Hess now observed that in the process of mixing such neutral solutions no thermal effect was produced - that is, neutral salts in aqueous solution could apparently interchange their radicals without evolution or absorption of heat.
Thomsen by direct experiment found that the heat-capacity of a dilute aqueous solution diverged in general less than i per cent.
It has already been stated that the heats of neutralization of acids and bases in aqueous solution are additively composed of two terms, one being constant for a given base, the other constant for a given acid.
In the ordinary process of soap-making the glycerin remains dissolved in the aqueous liquors from which the soap is separated.
Its viscid character, and its non-liability to dry and harden by exposure to air, also fit it for various other uses, such as lubrication, &c., whilst its peculiar physical characters, enabling it to blend with either aqueous or oily matters under certain circumstances, render it a useful ingredient in a large number of products of varied kinds.
Aqueous and alcoholic solutions of ammonia convert carbon bisulphide into ammonium dithiocarbamate, which readily breaks down into ammonium thiocyanate and sulphuretted hydrogen (A.
Carbon bisulphide combines with primary amines to form alkyl dithiocarbamates, which when heated lose sulphuretted hydrogen and leave a residue of a dialkyl thio-urea, CS 2 +2R NH 2 - R NH CSS NH 3 RCS(NHR)2+H2S; or if the aqueous solution of the dithiocarbamate be boiled with mercuric chloride or silver nitrate solution, a mustard oil (q.v.) is formed, R.NH CSS NH3R+HgC12-Hg(R NH CSS)2->2RNCS-}-HgS+H2S.
It forms a characteristic explosive silver salt on the addition of ammoniacal silver nitrate to its aqueous solution, and an amorphous precipitate which explodes on warming with ammoniacal cuprous chloride.
It readily forms a sodium salt, from the aqueous solution of which on the addition of a mineral acid an isomeric solid form of the nitro compound (melting at 84° C.) is precipitated.
An aqueous solution readily dissolves lead oxide, with formation of a strongly alkaline solution containing basic acetates (Acetum Plumbi or Saturni).
Berthelot, on the other hand, assumed that the heat-capacity of an aqueous solution is equal to that of an equal volume of water, and calculated his results on this assumption, which involves much the same uncertainty as that of Thomsen.
From its aqueous solution, concentrated hydrochloric acid precipitates hydrocobalticyanic acid, H 3 Co(CN) 61 as a colourless solid which is very deliquescent, and is not attacked by concentrated hydrochloric and nitric acids.