The mother liquor includes generally more or less of nickel, cobalt, zinc and other heavy metals, which, as Wailer showed, can be removed as insoluble sulphides by the addition of ammonium sulphide; uranium, under the circumstances, is not precipitated by this reagent.
Uranium is chemically related to chromium, molybdenum and tungsten.
In the same year as Klaproth detected uranium, he also isolated zirconia or zirconium oxide from the mineral variously known as zircon, hyacinth, jacynth and jargoon; but he failed to obtain the metal, this being first accomplished some years later by Berzelius, who decomposed the double potassium zirconium fluoride with potassium.
The only practically available raw material for 'the extraction of uranium is pitchblende (q.v.).
Exposed to air this mixture is oxidized to the pigment uranium red, U6(NH4)2S09, which is a fine blood-coloured amorphous powder.
He was the first to discover uranium, zirconium and titanium, and to characterize them as distinct elements, though he did not obtain any of them in the pure metallic state; and he elucidated the composition of numerous substances till then imperfectly known, including compounds of the then newly recognized elements: tellurium, strontium, cerium and chromium.
He extracted a substance to which he assigned the character of an element, naming it uranium (from O'pavos, heaven); but it was afterwards shown by E.
In 1789 Klaproth isolated from pitchblende a yellow oxide which he viewed as the oxide of a new metal, which he named uranium, after the newly discovered planet of Herschel.
He concluded that the uranium salt was Ur 2033S0 3, where Ur 2 0 3, according to his analysis, represents 864 parts of yellow oxide (0 = 16).
The precipitate, after having been collected and washed, is digested with a warm concentrated solution of ammonium carbonate, which dissolves the uranium as a yellow solution of ammonium uranate, while the hydrated oxide of iron, the alumina, &c., remain.
Uranium is a white malleable metal, which is pretty hard, though softer than steel.
Uranyl nitrate, U02(N03)2.6H20, is the most important uranium salt.
Another radioactive substance - ionium - was isolated from carnotite, a uranium mineral, by B.
Curie obtained only a fraction of a gramme of the chloride and Giesel 2 to 3 gramme of the bromide from a ton of uranium residues.
In two cases, however, it has been found in the absence of appreciable quantities of uranium and thorium compounds, namely in beryl, and in sylvine (potassium chloride).
Artificial pitchblende, which serves as a starting-point for the preparation of uranium compounds.
Metallic uranium, as shown by Peligot, can be obtained by the reduction of a mixture of dry chloride of potassium and dry uranous chloride, UC1 4, with sodium at a red heat.
Uranous Compounds.-Uranium dioxide, UO 2 (Berzelius's metal), is a brown to copper-coloured powder, obtained by heating U308 or uranyl oxalate in hydrogen.
Sodium uranate, Na2U207, is used as a pigment for painting on glass and porcelain under the name of uranium yellow.
Dilute sulphuric acid precipitates uranium yellow, Na 2 U 2 0 7.6H 2 O, from the solution so obtained.
Ammonium uranate heated to redness yields pure U308, which serves as a raw material for uranium compounds.
By electrolysis it yields uranium dioxide as a pyrophoric powder, and peruranic hydroxide, U04.2H20, when treated with hydrogen peroxide.
Uranyl chloride, UO 2 C1 2, is a yellow crystalline mass formed when chlorine is passed over uranium dioxide at a red heat.
The most modern and the most generally accepted method is volumetric, and is based on the reaction between zinc chloride and potassium ferrocyanide, by which insoluble zinc ferrocyanide and soluble potassium chloride are formed; the presence of the slightest excess of potassium ferrocyanide is shown by a brownish tint being imparted by the solution to a drop of uranium nitrate.
Helium is relatively abundant in many minerals, all of which are radioactive, and contain uranium or thorium as important constituents.
He was distinguished as the discoverer of radioactivity, having found in 1896 that uranium at ordinary temperatures emits an invisible radiation which in many respects resembles Rntgen rays, and can affect a photographic plate after passing through thin plates of metal.
The sulphates are treated with water, which dissolves the uranium and other soluble salts, while silica, lead sulphate, &c., remain; these are removed by filtration.
The filtrate contains the uranium as uranous and the iron as ferrous salt.
Analysis.-A borax bead dissolves uranium oxides in the reducing flame with a green, in the oxidizing flame with a yellow, colour.
The purple-blue of cobalt, the chrome green or yellow of chromium, the dichroic canarycolour of uranium and the violet of manganese, are constant.
Antimony, bismuth, selenium, tellurium, chromic iron ore, tin, nickel, cobalt, vanadium, titanium, molybdenum, uranium and tantalum are produced in the United States in small amounts, but such production in several cases has amounted to only slight discoveries, and in general they are of little importance in the market.
Radius, ray), a metallic chemical element obtained from pitchblende, a uranium mineral, by P. and Mme.
Becquerel's observation in 1896 that certain uranium preparations emitted a radiation resembling the X rays observed by Rntgen in 1895.
After removing the uranium, it was found that the bismuth separated with a very active substance - polonium; this element was afterwards isolated by Marckwald, and proved to be identical with his radiotellurium; that the barium could be separated with another active substance - radium; whilst a third fraction, composed mainly of the rare earths (thorium, &c.), yielded to Debierne another radioactive element - actinium, which proved to be identical with the emanium of Giesel.
After the discovery of the radioactive properties of uranium by Henri Becquerel in 1896, it was noticed that some minerals of uranium, such as pitchblende, were more active than the element itself, and this circumstance suggested that such minerals contained small quantities of some unknown substance or substances possessing radioactive properties in a very high degree.
Evaporation of a solution at ordinary temperatures gives colourless monoclinic prisms of Th(SO 4) 2.9H 2 O, which is isomorphous with uranium sulphate, U(S04)2.9H20.
Aqueous solutions of the acid are decomposed in sunlight by uranium salts, with evolution of carbon dioxide and the formation of propionic acid.
Becquerel in 1896 that minerals containing uranium, and particularly the mineral known as pitchblende, had the power of affecting sensitive photographic plates enclosed in a black paper envelope when the mineral was placed on the outside, as 1 See J.
The figures for the more important minerals are as follows: Gold ore, manganese ore and uranium ore are produced in small quantities, and the list of minerals worked in the United Kingdom also includes chalk, lead, alum, phosphate of lime, chert and flint, gravel and sand, zinc ore, gypsum, arsenic, copper, barytes, wolfram and strontium sulphate.
The phosphorescence of the sulphide obtained by heating the thiosulphate is much increased by adding uranium, bismuth, or thorium before ignition pr.
Antimony is extracted at Milleschau near Tabor; uranium and radium near Joachimsthal; graphite near Krumau and Budweis; porcelain-earth near Carlsbad.
Without filtering, the standard solution is added from a burette, and from time to time a drop of the solution is removed on the glass stirring-rod and added to a drop or two of a strong solution of uranium nitrate, previously placed on a white porcelain plate.
Peligot's results, though called in question by Berzelius, have been amply confirmed by all subsequent investigators; only now, on theoretical grounds, first set forth by Mendeleeff, we double Peligot's atomic weight, so that U now signifies 240 parts of uranium, while UO 3 stands as the formula of the yellow oxide, and UO 2 as that of Berzelius's metal.