It may be synthetically prepared by fusing potassium benzene sulphonate with caustic alkalis (A.
It has been obtained synthetically by M.
7-trihydroxyxanthone, is found in the form of its methyl ether (gentisin) in gentian root; it is obtained synthetically by condensing phloroglucin with hydroquinone carboxylic acid.
It may be synthetically prepared by the dry distillation of ammonium mucate, or, better, by heating it with glycerin to 180-200° C. (H.
Fats doubtless originate by the " cleavage " of the synthetically formed proteids, or from carbohydrates.
It may therefore be said that caoutchouc has been already artificially or synthetically prepared, and the possibility of producing synthetic rubber cheaply on a commercial scale remains the only problem.
There are many substances produced by plants which can be synthetically prepared by chemical means, but, as with quinine, the process involved is too costly to enable the synthetic product to compete with the natural product.
It can be synthetically prepared by the reduction of coniferyl alcohol, (HO) (CH 3 O) C6H3 CH :CH CH20H, which occurs in combination with glucose in the glucoside coniferin, C16H2208.
Fischer's a-acrose therefore led to the synthesis of the dextro and laevo forms Gf mannose, glucose and fructose; and these substances have been connected synthetically with many other sugars by means of his cyanhydrin process, leading to higher sugars, and Wohl and.
It may be obtained from storax by distillation with water, and synthetically by heating cinnamic acid with lime, by the action of aluminium chloride on a mixture of vinyl bromide and benzene, by removing the elements of hydrobromic acid from bromethylbenzene by means of alcoholic potash, or, best, by treating (-bromhydrocinnamic acid with soda, when it yields styrolene, carbon dioxide and hydrobromic acid.
It may be obtained synthetically by heating sodium in a current of carbon dioxide to 360° C.; by the oxidation of ethylene glycol; by heating sodium formate to 400° C. (V.
It may be synthetically prepared by any of the general methods described in the article Alcohols.
Alcohol is produced by fermentation from vegetable substances containing starch or sugar, from fermentable sugars produced by the hydrolysis of cellulosic bodies, and synthetically from calcium carbide and from the ethylene contained in coal and coke-oven gases.
Liebermann in 1868 prepared that substance synthetically from anthracene, but their process was not practicable on a large scale, and it was left to him to patent a method that was commercially valuable.
They were first prepared synthetically by reducing the isonitrosoketones.
The olefines may be synthetically prepared by eliminating water from the alcohols of the general formula CnH2n+1 OH, using sulphuric acid or zinc chloride generally as the dehydrating agent, although phosphorus pentoxide, syrupy phosphoric acid and anhydrous oxalic acid may frequently be substituted.
In order to prove this novel conclusion he started afresh from the Cartesian " I think " in the Kantian form of the synthetic unity of apperception acting by a priori categories; but instead of allowing, with all previous metaphysicians, that the Ego passively receives sensations from something different, and not contenting himself with Kant's view that the Ego, by synthetically combining the matter of sensations with a priori forms, partially constructs objects, and therefore Nature as we know it, he boldly asserted that the Ego, in its synthetic unity, entirely constructs things; that its act of spontaneity is not mere synthesis of passive sensations, but construction of sensations into an object within itself; and that therefore understanding makes as well as shapes Nature.
Although he does not agree with Kant that either the formal element in sense or the synthesis of sensations is a priori, yet in very Kantian fashion, through not distinguishing between operation and object, he holds that, in synthetically combining sensations of touch and sight, we not only have a complex perception of a solid body, but also know this " object thought of " as itself the complex of these sensations objectified.
It may be synthetically prepared by the action of anhydrous aluminium chloride on a mixture of naphthalene and ethylene dibromide (R.
Synthetically prepared by the reduction of benzoyl chloride; by the action of nitrous acid on benzylamine; by boiling benzyl chloride with an aqueous solution of potassium carbonate, or by the so-called "Cannizzaro" reaction, in which benzaldehyde is shaken up with caustic potash, one half of the aldehyde being oxidized to benzoic acid, and the other half reduced to the alcohol.
It may be synthetically prepared by the fusion of cymol sulphonic acid with caustic potash; by the action of nitrous acid on 1-methyl-2-amino-4-propyl benzene; by prolonged heating of 5 parts of camphor with r part of iodine; or by heating carvol with glacial phosphoric acid.
It may be obtained synthetically by the action of ammonium iodide on cyanamide, CN NH2+ NH 4 I=CN 3 H 5 HI
The most comprehensive view of Rosmini's philosophical standpoint is to be found in his Sistema filosofico, in which he set forth the conception of a complete encyclopaedia of the human knowable, synthetically conjoined, according to the order of ideas, in a perfectly harmonious whole.
4 trioxyanthraquinone) is found with alizarin in madder root; it is now prepared synthetically by oxidizing alizarin with manganese dioxide and sulphuric acid.
Anthragallol is synthetically prepared by the condensation of benAoic and gallic acids with sulphuric acid OH i [[Cooh + I 10h - 2h20+ Hooc /Oh]] or from pyrogallol and phthalic anhydride in the presence of sulphuric acid or zinc chloride.
Deduction is synthesis when it is progressive from real ground to consequence, as when we start from these two results of analysis as principles and deduce synthetically the proposition that therefore the angles of a triangle are equal to two right angles, in the order familiar to the student of Euclid.
Newton did indeed first show synthetically what kind of motions by mechanical laws have their ground in a centripetal force varying inversely as the square of the distance (all P is M); but his next step was, not to deduce synthetically the planetary motions, but to make a new start from the planetary motions as facts established by Kepler's laws and as examples of the kind of motions in question (all S is P); and then, by combining these two premises, one mechanical and the other astronomical, he analytically deduced that these facts of planetary motion have their ground in a centripetal force varying inversely as the squares of the distances of the planets from the sun (all S is M).
It may be synthetically obtained by distilling oxindole (C 8 H 8 NO) with zinc dust; by heating orthonitrocinnamic acid with potash and iron filings; by the reduction of indigo blue; by the action of sodium ethylate on orthoaminochlorstyrene; by boiling aniline with dichloracetaldehyde; by the dry distillation of ortho-tolyloxamic acid; by heating aniline with dichioracetal; by distilling a mixture of calcium formate and calcium anilidoacetate; and by heating pyruvic acid phenyl hydrazone with anhydrous zinc chloride.
Synthetically it may ba obtained by reducing malic or tartaric acids with hydriodic acid (R.
In 1867 Wurtz prepared neurine synthetically by the action of trimethylamine on glycol-chlorhydrin, and in 1872 he discovered aldol, pointing out its double character as at once an alcohol and an aldehyde.
It may also be mentioned that many toxins have now been obtained by growing the particular organism in a proteid-free medium, a fact which shows that if the toxin is a proteid it may be formed synthetically by the bacterium as well as by modification of proteid already present.
It may be prepared synthetically by fusing meta-iodophenol, phenol meta-sulphonic acid, and benzene meta-disulphonic acid with potash; by the action of nitrous acid on meta-aminophenol; or by the action of 10% hydrochloric acid on meta-phenylene diamine (J.
It may be synthetically prepared by distilling allyl ethylamine over heated lead oxide (W.
It may be prepared synthetically by condensing ortho-aminoacetophenone with paraldehyde and caustic soda (L.
Hydriodic acid and red phosphorus on benzene, and considered to be hexahydrobenzene, is obtained synthetically by the action of sodium on 1.5 dibromhexane; and by the action of magnesium on acetylbutyl iodide (N.
It may be prepared synthetically by fusing its dicarboxylic ester (from malonic ester and sodio malonic ester at 145° C.) with potash (C. W.
It may be obtained synthetically by Fittig and Tollens's method (above); by Friedel and Craft's process, devised in 1877, of acting with aluminium chloride on a mixture of benzene and methyl chloride; this reaction leads to the production of higher homologues which may, however, break down under the continued action of the aluminium chloride; or by heating the toluene carboxylic acids obtained by oxidizing the higher homologues of benzene.