Much manganese sulphate is formed during the reaction, and H.
This outlet having been closed by small stones and sulphate of lime cement, the pit is filled with sulphur ore, which is heaped up considerably beyond the edge of the pit and covered with a layer of burnt-out ore.
From the heating of native calcium sulphate and carbon is obtained calx sulphurata (U.S. and B.P.), or sulphurated lime, a greyish-white powder.
The whole of the lead and sulphur of the sulphide was found to be present in the sulphate; in other words, the combining ratio of the lead and sulphur was not altered by the addition of the oxygen.
The most common of these sulphides is cobaltous sulphide, CoS, which occurs naturally as syepoorite, and can be artificially prepared by heating cobaltous oxide with sulphur, or by fusing anhydrous cobalt sulphate with barium sulphide and common salt.
It forms dark red crystals isomorphous with ferrous sulphate, and readily soluble in water.
In "cold galvanizing" the zinc is deposited electrolytically from a bath, preferably kept neutral or slightly acid, containing a io% solution of crystallized zinc sulphate, ZnSO 4.7H20.
The superiority which is claimed for Burton ales is attributed to the use of well-water impregnated with sulphate of lime derived from the gypseous deposits of the district.
The aqueous solution is turned bluish black by ferrous sulphate containing a ferric salt.
P. 299), or by the addition of a concentrated solution of potassium cyanide to one of copper sulphate, the mixed solutions being then heated.
Their produce has gradually decreased since the 17th century, and is now unimportant, but sulphate of copper, iron pyrites, and some gold, silver, sulphur and sulphuric acid, and red ochre are also produced.
Zinc ores, in the several varieties of carbonates, silicates, oxide, sulphide and sulphate of zinc, have been found in several of the Australian states, but have attracted little attention except in New South Wales, where special efforts are being made successfully to produce a high-grade zinc concentrate from the sulphide ores.
The oxide is a black or brown powder according as it is prepared from the exalate or sulphate, and when pure it is non-fluorescent, but mixed with gadolinia or alumina it possesses this property.
It yields colourless salts; the crystallized sulphate has the formula Tb2(S04)3.8H20.
Alum and blue vitriol (sulphate of copper) are manufactured from decomposed schists at Khetri in Shaikhawati.
Each cell contains a zinc plate, immersed in a solution of zinc sulphate, and also a porous chamber containing crystals of copper sulphate and a copper plate.
Cadmium sulphate, CdSO 4, is known in several hydrated forms; being deposited, on spontaneous evaporation of a concentrated aqueous solution, in the form of large monosymmetric crystals of composition 3CdSO 4.8H 2 O, whilst a boiling saturated solution, to which concentrated sulphuric acid has been added, deposits crystals of composition CdSO 4 4H 2 0.
Chemicals sulphate of copper, employed chiefly as a preventive 01 certain maladies of the vine; carbonate of lead, hyper.
Any poisonous substance that is not included in the schedules can be sold by anyone, as, for instance, red lead, sulphate of copper, &c. The duty of the Pharmaceutical Society is a purely legal one, and relates only to the schedules of poisons framed by the government to protect the public by rendering it a difficult matter to obtain the poisons most frequently used for criminal purposes.
The treatment is therefore to administer an ounce of sodium sulphate in water by the mouth, or to inject a similar quantity of the salt in solution directly into a vein or into the subcutaneous tissues.
Magnesium sulphate may be given by the mouth, but is poisonous if injected intravenously.
It is prepared on the industrial scale for the manufacture of sulphuric acid, for the preparation of sodium sulphate by the Hargreaves process, and for use as a bleaching-disinfecting agent and as a preservative.
Solutions of persulphates in the cold give no precipitate with barium chloride, but when warmed barium sulphate is precipitated with simultaneous liberation of chlorine: K 2 S 2 0 8 + BaC1 2 = BaSO 4 + K 2 SO 4 + C1 2.
After unsuccessful attempts to rid themselves of the mice, the farmers appealed to the United States Biological Survey, and alfalfa hay poisoned with strychnia sulphate was used successfully in the Humboldt Valley in January 1908 and in the Carson Valley, where a similar plague threatened, in April 1908.5 Minerals.
Thus the heat of formation of anhydrous zinc sulphate, ZnSO 4j which cannot be determined directly, may be arrived at by summation (in Hess's units) as follows: Heats of formation are still determined for the most part in a precisely similar manner.
For example, when metallic zinc is dissolved in dilute sulphuric acid with production of zinc sulphate (in solution) and hydrogen gas, a definite quantity of heat is produced for a given amount of zinc dissolved, provided that the excess of energy in the initial system appears entirely as heat.
It was about this time that the value of a mixture of lime and sulphate of copper (bouillie bordelaise), sprayed in solution upon the growing plants, came to be recognized as a check upon the ravages of potato disease.
Successful trials of sulphate of copper solution as a means of destroying charlock in corn crops took place in the years 1898-1900.
BARYTES, a widely distributed mineral composed of barium sulphate (BaSO 4).
The mineral is usually found in a state of considerable chemical purity, though small amounts of strontium and calcium sulphates may isomorphously replace the barium sulphate: ammonium sulphate is also sometimes present, whilst clay, silica, bituminous matter, &c., may be enclosed as impurities.
Its property of absorbing large proportions of water, up to 80%, and yet present the appearance of a hard solid body, makes the material a basis for the hydrated soaps, smooth and marbled, in which water, sulphate of soda, and other alkaline solutions, soluble silicates, fuller's earth, starch, &c. play an important and bulky part.
The ores found here comprise silver-free galena, sulphate of zinc and calamine.
The dioxide, Ru02, is formed by heating sulphate, or by heating the metal in a current of oxygen.
The insoluble residue contains a mixture of two sulphides, one of which is converted into the sulphate by nitric acid, whilst the other (a crystalline solid) is insoluble in acids.
Ruthenium sulphate, Ru(S04)2, as obtained by oxidizing the sulphide, is an orange-yellow mass which is deliquescent and dissolves in water, the solution possessing a strongly acid reaction.
Thus copper sulphate was CuO+S0 3, potassium sulphate 2S0 3 +P00 2 (the symbol Po for potassium was subsequently discarded in favour of K from kalium).
Thus acid sodium sulphate, normal sodium sulphate, and zinc sulphate have the formulae Na-0 O Na O, O O ¦ O H.o> S
The compounds of mercury attracted considerable attention, mainly on account of their medicinal properties; mercuric oxide and corrosive sublimate were known to pseudo-Geber, and the nitrate and basic sulphate to " Basil Valentine."
1 The metals of the alkaline-earths were somewhat neglected; we find Georg Agricola considering gypsum (calcium sulphate) as a compound of lime, while calcium nitrate and chloride became known at about the beginning of the 17th century.
Sulphur dioxide, recognized by its smell and acid reaction, results from the ignition of certain sulphites, sulphates, or a mixture of a sulphate with a sulphide.
Any residue consists of black mercuric sulphide (and possibly white lead sulphate), in which mercury is confirmed by its usual tests.
The carbonates are dissolved in hydrochloric acid, and calcium sulphate solution is added to a portion of the solution.
The solution free from barium is treated with ammonia and ammonium sulphate, which precipitates strontium, and the calcium in the solution may be identified by the white precipitate with ammonium oxalate.
The substance is heated with metallic sodium or potassium (in excess if sulphur be present) to redness, the residue treated with water, filtered, and ferrous sulphate, ferric chloride and hydrochloric acid added.
Examples of the first case are found among the colourless acridines and quinoxalines which give coloured salts; of the second case we may notice the colourless hydrochloride and sulphate of the deep yellow o-aminobenzophenone.
The ordinary structural formula of potassium sulphate is K - O - S - O - K.
For example, episomorphs of white potash alum and violet chrome alum, of white magnesium sulphate and green nickel sulphate, and of many other pairs of salts, have been obtained.
Magnesium sulphate (orthorhombic) takes up ferrous sulphate (monoclinic) to the extent of 19%, forming isomorphous orthorhombic crystals; ferrous sulphate, on the other hand, takes up magnesium sulphate to the extent of 54% to form monoclinic crystals.
By plotting the specific volumes of these mixed crystals as ordinates, it is found that they fall on two lines, the upper corresponding to the orthorhombic crystals, the lower to the monoclinic. From this we may conclude that these salts are isodimorphous: the upper line represents isomorphous crystals of stable orthorhombic magnesium sulphate and unstable orthorhombic ferrous sulphate, the lower line isomor phous crystals of stable monoclinic ferrous sulphate and unstable monoclinic magnesium sulphate.
The raw materials used in the manufacture are: (I) iron-free kaolin, or some other kind of pure clay, which should contain its silica and alumina as nearly as possible in the proportion of 2SiO 2: Al203 demanded by the formula assigned to ideal kaolin (a deficit of silica, however, it appears can be made up for by addition of the calculated weight of finely divided silica); (2) anhydrous sulphate of soda; (3) anhydrous carbonate of soda; (4) sulphur (in the state of powder); and (5) powdered charcoal or relatively ash-free coal, or colophony in lumps.
"Ultramarine poor in silica" is obtained by fusing a mixture of soft clay, sodium sulphate, charcoal, soda and sulphur.
It is remarkable that even a small addition of zinc-white (oxide of zinc) to the reddish varieties especially causes a considerable diminution in the intensity of the colour, while dilution with artificial precipitated sulphate of lime ("annalin") or sulphate of baryta ("blanc fix") acts pretty much as one would expect.
Among the analytical methods worked up by him the best known is that for the estimation of sugars by "Fehling's solution," which consists of a solution of cupric sulphate mixed with alkali and potassium-sodium tartrate (Rochelle salt).