However, in 1833, Berzelius reverted to his earlier opinion that oxygenated radicals were incompatible with his electrochemical theory; he regarded benzoyl as an oxide of the radical C 14 H 1Q, which he named " picramyl " (from 7rucp6s, bitter, and &uvyalk, almond), the peroxide being anhydrous benzoic acid; and he dismissed the views of Gay Lussac and Dumas that ethylene was the radical of ether, alcohol and ethyl chloride, setting up in their place the idea that ether was a suboxide of ethyl, (C2H5)20, which was analogous to K 2 0, while alcohol was an oxide of a radical C 2 H 6; thus annihilating any relation between these two compounds.
The suboxide, Pb 2 0, is the first product of the oxidation of lead, and is also obtained as a black powder by heating lead oxalate to 300° out of contact with air.
A suboxide, Na 3 0, appears to be formed as a grey mass when a clean surface of the metal is exposed to air, or when pure air is passed through the metal just above its melting point (De Forcrand, Compt.
Three oxides of carbon are known, namely, carbon suboxide, C,02, carbon monoxide, CO, and carbon dioxide, C02.
Carbon suboxide, C302, is formed by the action of phosphorus pentoxide on ethyl malonate (0.
A suboxide, Ni 2 O (?), described by W.
Two classes may be distinguished: the aldo-ketenes, including ketene itself, together with its monoalkyl derivatives and carbon suboxide, and the keto-ketenes which comprise the dialkyl ketenes.
Three oxides of barium are known, namely, the monoxide, BaO, the dioxide, Ba02, and a suboxide, obtained by heating Ba0 with magnesium in a vacuum to 110o (Guntz, loc. cit., 1906, p. 359).
Phosphorus suboxide, P 4 O, is said to be formed, mixed with the other oxides, when the element is burnt in a limited supply of air or in pure oxygen under reduced pressure (E.
Two oxides of arsenic are definitely known to exist, namely the trioxide (white arsenic), As406, and the pentoxide, As205, while the existence of a suboxide, As20(?), has also been mooted.
It slowly reacts with cold water to form phosphorous acid; but with hot water it is energetically decomposed, giving much red phosphorus or the suboxide being formed with an explosive evolution of spontaneously inflammable phosphoretted hydrogen; phosphoric acid is also formed.