Industry, 1899, 18, p. 553) adds excess of sodamide to a solution of the phenol in a suitable solvent, absorbs the liberated ammonia in an excess of acid, and titrates the excess of acid.
When passed with carbon dioxide through a red-hot tube it yields carbon oxysulphide, COS (C. Winkler), and when passed over sodamide it yields ammonium thiocyanate.
Its sodium salt is obtained by the action of sodamide on the oxime, in presence of benzene (A.
The hydrogen in ammonia is capable of replacement by metals, thus magnesium burns in the gas with the formation of magnesium nitride Mg3N2, and when the gas is passed over heated sodium or potassium, sodamide, NaNH 2, and potassamide, KNH 2, are formed.
It also combines with dry ammonia at 300-400° to form sodamide, NaNH 2, a white waxy mass when pure, which melts at 155°.
Heated in a current of carbon dioxide sodamide yields caustic soda and cyanamide, and with nitrous oxide it gives sodium azoimide; it deflagrates with lead or silver nitrate and explodes with potassium chlorate.
Sodamide was introduced by Claisen (Ber., 1905, 3 8, p. 6 93) as a condensing agent in organic chemistry, and has since been applied in many directions.
Wislicenus (Berichte, 1892, 25, p. 2084) has prepared the sodium salt by passing nitrous oxide over sodamide at high temperatures.
242938 (1894)] passes anhydrous ammonia over heated sodium to form sodamide, which is then brought in a molten condition into contact with carbon: NaNH 2 +C = NaNC+H 2.