David Dean, without a remote control, had difficulty with the TV and these two old fogies were out surfing the net like a couple of Silicon Valley youngsters.
Scheele had done, and because he was employing a glass vessel he got "fluor acid air" (silicon fluoride).
Carbon was joined with silicon, zirconium and titanium, while boron, being trivalent, was relegated to another group. A general classification of elements, however, was not realized by Frankland, nor even by Odling, who had also investigated the question from the valency standpoint.
Thus, hydrogen unites with but a single atom of chlorine, zinc with two, boron with three, silicon with four, phosphorus with five and tungsten with six.
A masterly device, initiated by him, was to collect gases over mercury instead of water; this enabled him to obtain gases previously only known in solution, such as ammonia, hydrochloric acid, silicon fluoride and sulphur dioxide.
The term allotropy has also been applied to inorganic compounds, identical in composition, but assuming different crystallographic forms. Mercuric oxide, sulphide and iodide; arsenic trioxide; titanium dioxide and silicon dioxide may be cited as examples.
The results of Berzelius were greatly extended by Hermann Kopp, who recognized that carbon, boron and silicon were exceptions to the law.
Weber, who showed that with rise of temperature the specific (and atomic) heat increases, finally attaining a fairly constant value; diamond, graphite and the various amorphous forms of carbon having the value about 5.6 at moo°, and silicon 5.68 at 232°; while he concluded that boron attained a constant value of 5.5.
Normal values of K were given by nitrogen peroxide, N204, sulphur chloride, S 2 C1 21 silicon tetrachloride, SiC1 4, phosphorus chloride, PC1 3, phosphoryl chloride, POC1 31 nickel carbonyl, Ni(CO) 4, carbon disulphide, benzene, pyridine, ether, methyl propyl ketone; association characterized many hydroxylic compounds: for ethyl alcohol the factor of association was 2.74-2.43, for n-propyl alcohol 2.86-2.72, acetic acid 3.62 -2.77, acetone 1 .
Mehner patented heating the oxides of silicon, boron or magnesium with coal or coke in an electric furnace, and then passing in nitrogen, which forms, with the metal liberated by the action of the carbon, a readily decomposable nitride.
At the same time, however, it forms a number of compounds in which it is most decidedly tetravalent; and thus it shows relations to carbon, silicon, germanium and tin.
Trans., 1885, 176, 455) employed his yoke method to test the magnetic properties of thirty-five samples of iron and steel, among which were steels containing substantial proportions of manganese, silicon, chromium and tungsten.
5 More than fifty different specimens were tested, most of which contained a known proportion of manganese, nickel, tungsten, aluminium, chromium, copper or silicon; in some samples two of the substances named were present.
The addition of silicon in small quantities considerably diminished permeability and increased coercive force; but when the proportion amounted to 2.5% the maximum permeability (µ =5100 for H =2) was greater than that of the nearly pure iron used for comparison, while the coercive force was only 0.9.
The specimens distinguished by unusually high permeability were constituted as follows: Silicon-iron.
The silicon-iron had, in fields up to about Io, a greater permeability than a sample of the best Swedish charcoal-iron, and its hysteresisloss for max.
For additional information regarding the composition and qualities of permanent magnet steels reference may be made 6 The marked effect of silicon in increasing the permeability of cast iron has also been noticed by F.
A few years later further work, with Albert Ladenburg, on the same element yielded silicochloroform and:led to a demonstration of the close analogy existing between the behaviour in combination of silicon and carbon.
The older methods used for the preparation of the amorphous form, namely the decomposition of silicon halides or silicofluorides by the alkali metals, or of silica by magnesium, do not give good results, since' the silicon obtained is always contaminated with various impurities, but a pure variety may be prepared according to E.
A somewhat impure silicon (containing 90-98% of the element) is made by the Carborundum Company of Niagara Falls (United States Patents 745 122 and 842273, 1908) by heating coke and sand in an electric furnace.
The product is a crystalline solid of specific gravity 2.34, and melts at about 1430° C. See also German Patent 108817 for the production of crystallized silicon from silica and carborundum.
The specific heat varies with the temperature, from 0.136 at -39° C. to 0.2029 at 232° C. Silicon distils readily at the temperature of the electric furnace.
It decomposes ammonia at a red heat, liberating hydrogen and yielding a compound containing silicon and nitrogen.
Silicon hydride, SiH4, is obtained in an impure condition, as a spontaneously inflammable gas, by decomposing magnesium silicide with hydrochloric acid, or by the direct union of silicon and hydrogen in the electric arc. In the pure state it may be prepared by decomposing ethyl silicoformate in the presence of sodium (C. Friedel and A.
It burns when brought into contact with chlorine, forming silicon chloride and hydrochloric acid.
Wailer (Ann., 1857, 104, p. 94), is formed by heating crystallized silicon in hydrochloric acid gas at a temperature below red heat, or by the action of hydrochloric acid gas on copper silicide, the products being condensed by liquid air and afterwards fractionated (0.