Cylinders, tanks and independent boilers should be encased in a non-conducting material such as silicate cotton, thick felt or asbestos composition.
It may be skimmed off the underlye and placed direct in the frames for solidification; but that is a practice scarcely at all followed, the addition of resin soap in the pan and the subsequent " crutching in " of silicate of soda and adulterant mixings being features common to the manufacture.
A further means of enabling a soap to contain large proportions of water and yet present a firm consistence is found in the use of silicate of soda.
The silicate in the form of a concentrated solution is crutched or stirred into the soap in a mechanical mixing machine after the completion of the saponification, and it appears to enter into a distinct chemical combination with the soap. While silicate soaps bear heavy watering, the soluble silicate itself is a powerful detergent, and it possesses certain advantages when used with hard waters.
ULTRAMARINE, a blue pigment, consisting essentially of a double silicate of aluminium and sodium with some sulphides or sulphates, and occurring in nature as a proximate component of lapis lazuli.
It has been suggested that ultramarine is a compound of a sodium aluminium silicate and sodium sulphide.
Artificially formed crystals of the various species of mica have been observed in furnace-slags and in silicate fusions.
The alum schists employed in the manufacture of alum are mixtures of iron pyrites, aluminium silicate and various bituminous substances, and are found in upper Bavaria, Bohemia, Belgium and Scotland.
Hopkinson, working at Chance's glass works, subsequently made an attempt to produce a titanium silicate glass, but nothing further resulted.
- Sheet-glass is almost wholly a soda-lime-silicate glass, containing only small quantities of iron, alumina and other impurities.
The fire may well have caused the natron, an impure form of carbonate of soda, to combine with the surrounding sand to form silicate of soda, which, although not a permanent glass, is sufficiently glass-like to suggest the x11.4 FIG.
66) actually records the discovery which effected the conversion of deliquescent silicate of soda into permanent glass.
It is only soluble in a mixture of hydrofluoric and nitric acid, or in solutions of the caustic alkalis, in the latter case yielding hydrogen and a silicate: Si-}-2KHO+H 2 O = K 2 SiO 3 +2H 2.
The term clay is often used by chemists to denote hydrated silicate of alumina (Al 2 O 3 2SiO 2.2H 2 O), of which kaolin or china clay is a fairly pure form.
In diameter) of sand and other minerals derived from the decomposition of rocks, with a small amount of silicate of alumina.
Of less importance is the silicate, Zn 2 SiO 4 H 2 0, named electric calamine or hemimorphite; this occurs in quantity in Altenburg near Aix-laChapelle, Sardinia, Spain and the United States (New Jersey, Pennsylvania, Missouri, Wisconsin).
Oxide of zinc, like most heavy metallic oxides, is easily reduced to the metallic state by heating it to redness with charcoal; pure red zinc ore may be treated directly; and the same might be done with pure calamine of any kind, because the carbon dioxide of the zinc carbonate goes off below redness and the silica of zinc silicate only retards, but does not prevent, the reducing action of the charcoal.
Here very clean non-magnetic concentrate of willemite, which is an anhydrous zinc silicate and a very highgrade zinc ore, is separated from an intimate mixture of willemite, zincite and franklinites, with calcite and some manganese silicates.
Oddo, Chemisches Centralblatt, 1896, 228.) Acid calcium silicates are represented in the mineral kingdom by gyrolite, H2Ca2(S103)3 H20, a lime zeolite, sometimes regarded as an altered form of apophyllite, which is itself an acid calcium silicate containing an alkaline fluoride, by okenite, H2Ca(S103)2 H20, and by xonalite 4CaSiO 3 41 2 O.
Calcium silicate is also present in the minerals: olivine, pyroxenes, amphiboles, epidote, felspars, zeolites, scapolites (qq.v.).
As silicate of soda) and in other soda-containing rocks.
Any silicate present is also converted into bicarbonate with elimination of silica, which must be filtered off.
It is a silicate, containing aluminium, magnesium and iron' brought originally from Greenland, and since found in a rock from the Vizagapatam district in India.
Hartley has employed it with great success, and in cyanite (a silicate of aluminium) has found a material which is infusible at the temperature of this flame, and is therefore suitable to hold the substance which it is desired to examine.
Magnesium is found widely distributed in nature, chiefly in the forms of silicate, carbonate and chloride, and occurring in the minerals olivine, hornblende, talc, asbestos, meerschaum, augite, dolomite, magnesite, carnallite, kieserite and kainite.
Minerals, like glauconite, which contain ferrous silicate, may in like manner yield limonite, on weathering.
Some, such as victoria stone, imperial stone and others, are hardened and rendered non-porous after manufacture by immersion in a solution of silicate of soda.
Others, like Ford's silicate of limestone, are practically lime mortars of excellent quality, which can be carved and cut like a sandstone of fine quality.
The chief natural compounds of aluminium are four in number: oxide, hydroxide (hydrated oxide), silicate and fluoride.
Aluminium silicate is the chemical body of which all clays are nominally composed.
Aluminium silicates are widely diffused in the mineral kingdom, being present in the commonest rock-forming minerals (felspars, &c.), and in the gem-stones, topaz, beryl, garnet, &c. It also constitutes with sodium silicate the mineral lapis-lazuli and the pigment ultramarine.
For one kind of meat we could substitute another; wool could be replaced by cotton, silk or fur; were our common silicate glass gone, we could probably perfect and cheapen some other of the transparent solids; but even if the earth could be made to yield any substitute for the forty or fifty million tons of iron which we use each year for rails, wire, machinery, and structural purposes of many kinds, we could not replace either the steel of our cutting tools or the iron of our magnets, the basis of all commercial electricity.
About 1740 Benjamin Huntsman introduced the " crucible process " of melting steel in small crucibles, and thus freeing it from the slag, or rich iron silicate, with which it, like wrought iron, was mechanically mixed, whether it was made in the old forge or in the puddling furnace.
Slag or Cinder, a characteristic component of wrought iron, which usually contains from 0.20 to 2.00% of it, is essentially a silicate of iron (ferrous silicate), and is present in wrought iron simply because this product is made by welding together pasty granules of iron in a molten bath of such slag, without ever melting the resultant mass or otherwise giving the envelopes of slag thus imprisoned a chance to escape completely.
Lime of the limestone and the ash of the fuel to form a complex molten silicate called the " cinder " or " slag."
The duty of the limestone (CaCO 3) is to furnish enough lime to form with the gangue of the ore and the ash of the fuel a lime silicate or slag of such a composition (1) that it will melt at the temperature which it reaches at about level A, of fig.
Of these the first escapes immediately as a gas, and the others unite with iron oxide, lime, or other strong base present to form a molten silicate or silica-phosphate called " cinder " or " slag," which floats on the molten or pasty metal.
As the iron oxide is stirred into the molten metal laboriously by the workman or "puddler " with his hook or "rabble," it oxidizes the silicon to silica and the phosphorus to phosphoric acid, and unites with both these products, forming with them a basic iron silicate rich in phosphorus, called " puddling " or " tap cinder."
The slag, in order that it may have such an excess of base that this will retain the phosphoric acid as fast as it is formed by the oxidation of the phosphorus of the pig iron, and prevent it from being re-deoxidized and re-absorbed by the iron, should, according to von Ehrenwerth's rule which is generally followed, contain enough lime to form approximately a tetra-calcic silicate, 4CaO,S10 2 with the silica which results from the oxidation of the silicon of the pig iron and tri-calcic phosphate, 3CaO,P205, with the phosphoric acid which forms. The danger of this " rephosphorization " is greatest at the end of the blow, when the recarburizing additions are made.
Where the carbon, in thus diffusing inwards, meets particles of the slag, a basic ferrous silicate which is always present in wrought iron, it forms carbonic oxide, FeO+ C = Fe+CO, which puffs the pliant metal up and forms blisters.
Finally, then, both experiment and the natural occurrence in rocks and meteorites suggest that diamond may crystallize not only from iron but also from a basic silicate magma, possibly from various rocks consisting of basic silicates.
A rare blue chalcedony is sometimes polished under the name of "sapphirine" - a term applied also to a distinct mineral (an aluminium-magnesium silicate) from Greenland.
Amorphous and (generally) hydrated, or with a silicate containing silica in an active condition, it will unite with the silica and form a silicate of lime capable of resisting the action of water.
The mixture of the lime and active silica or silicate is a pozzuolanic cement.
As the outcome of these inquiries it has been established that tricalcium silicate 3CaO S10 2 is the essential constituent of Portland cement.
The two principal minerals are termed alite and celite; according to the best opinion, alite consists of a solid solution of tricalcium aluminate in tricalcium silicate, and celite of a solid solution of dicalcium aluminate in dicalcium silicate.
Since alite is a solid solution and, although an individual mineral, is not a chemical unit, the proportion of tricalcium silicate to tricalcium aluminate in a given specimen of alite will vary; but, whatever the proportions, each of these substances will react in its characteristic manner according to the equations given above.
As mentioned above, the constituents other than the tricalcium silicate and tricalcium aluminate of which alite is composed, are of minor importance.
In France this slaking is conducted systematically by the makers, the freshly burned lime being sprinkled with water and stored in large bins where slaking proceeds slowly and regularly until the whole of the surplus uncom bined lime is slaked and rendered harmless, while the cementitious compounds, notably tricalcium silicate, remain untouched.
- Mixtures of animal, vegetable and mineral substances are employed in great variety in the arts for making joints, mending broken china and other objects, &c. A strong cement for alabaster and marble, which sets in a day, may be prepared by mixing 12 parts of Portland cement, 8 of fine sand and 1 of infusorial earth, and making them into a thick paste with silicate of soda; the object to be cemented need not be heated.