The Korn telephotographic apparatus is based on the principle of an apparatus devised by Shelford Bidwell in 1881 for the electrical transmission of pictures to a distance, in which use was made of the change in electrical resistance which selenium undergoes when acted upon by light.
A totally reflecting prism placed inside the glass cylinder projects the light which penetrates the film upon a selenium cell situated at the end of the cylinder.
Owing to the variable illumination of the selenium thus produced, the resistance of the latter, and therefore the intensity of the current sent through the line to the receiving station by the battery, will be altered accordingly.
By means of this " light-relay " the intensity of the light acting at any moment upon the sensitized paper is made proportional to the illumination of the selenium in the transmitter.
To eliminate the sluggish action of the selenium transmitter a selenium cell similar to that at the transmitting station is arranged at the receiving apparatus, and exposed to precisely similar variations of light, the arrangement being such that the lag of this cell counteracts the lag of the transmitting cell.
Sulphur containing selenium, such as occurs in the isle of Vulcano in the Lipari Isles, may be orange-red; and a similar colour is seen in sulphur which contains arsenic sulphide, such as that from La Solfatara near Naples.
Eilos, like), strictly belongs to certain elements which do not possess the properties of the true metals, although they more closely resemble them than the non-metals in many respects; thus, selenium and tellurium, which are closely allied to sulphur in their chemical properties, although bad conductors of heat and electricity, exhibit metallic lustre and have relatively high specific gravities.
The following, however, are negative towards the remaining elements which are more or less positive:-Fluorine, chlorine, bromine, iodine, oxygen, sulphur, selenium, tellurium.
In the same year Berzelius discovered selenium in a deposit from sulphuric acid chambers, his masterly investigation including a study of the hydride, oxides and other compounds.
The allotropy of selenium was first investigated by Berzelius; and more fully in 1851 by J.
Hittorf, who carefully investigated the effects produced by heat; crystalline selenium possesses a very striking property, viz.
The elements which go to form heterocyclic rings, in addition to carbon, are oxygen, sulphur, selenium and nitrogen.
The three primary members are furfurane, thiophene and pyrrol, each of which contains four methine or CH groups, and an oxygen, sulphur and imido (NH) member respectively; a series of compounds containing selenium is also known.
If, on the other hand, the sulphur system be replaced by a corresponding selenium system, an element of higher atomic weight, it would be expected that a slight increase would be observed in the vertical parameter, and a greater increase recorded equally in the horizontal parameters.
It may conveniently be extended to similar mixtures of sulphur and selenium or tellurium, of bismuth and sulphur, of copper and cuprous oxide, and of iron and carbon, in fact to all cases in which substances can be made to mix in varying proportions without very marked indication of chemical action.
Bismuth forms compounds similar to the trisulphide with the elements selenium and tellurium.
Small quantities are occasionally met with in iron pyrites, and hence tellurium is found with selenium in the flue dust, or chamber deposits of sulphuric acid works.
Chem., 1897, p. II) extracts the element from black tellurium as follows:- The ore is boiled with concentrated sulphuric acid, the solution diluted, hydrochloric acid added and the tellurium (together with selenium) precipitated by sulphur dioxide and the process repeated when a purer tellurium is obtained.
Like sulphur and selenium, tellurium combines directly with hydrogen to form telluretted hydrogen, TeH2, an extremely objectionable smelling and highly poisonous gas, which was first prepared by Sir H.
These substances, and also carbon, sulphur, selenium and tellurium, render the metal very brittle.
Such, for instance, were those of Spindler and Wrangell in the Black Sea by sinking an electric lamp, those of Paul Regnard by measuring the change of electric resistance in a selenium cell or the chemical action of the light on a mixture of chlorine and hydrogen, by which he found a very rapid diminution in the intensity of light even in the surface layers of water.
The mineral nearly always contains a small amount of silver, and sometimes antimony, arsenic, copper, gold, selenium, &c. Argentiferous galena is an important source of silver; this metal is present in amounts rarely exceeding %, and often less than o 03% (equivalent to 104 ounces per ton).
Antimony, bismuth, selenium, tellurium, chromic iron ore, tin, nickel, cobalt, vanadium, titanium, molybdenum, uranium and tantalum are produced in the United States in small amounts, but such production in several cases has amounted to only slight discoveries, and in general they are of little importance in the market.
When there is appreciable absorption as in the case of the vapours of chlorine, bromine, iodine, sulphur, selenium and arsenic, luminosity begins at a red heat.
It combines with ammonia to form AlC13.3NH3; and forms double compounds with phosphorus pentachloride, phosphorus oxychloride, selenium and tellurium chlorides, as well as with many metallic chlorides; sodium aluminium chloride, AlC1 3 ï¿½NaC1, is used in the production of the metal.
It combines readily with fluorine, chlorine and bromine, and also with sulphur, selenium, phosphorus, &c.
Crookes presumed that his thallium was something of the order of sulphur, selenium or tellurium; but Lamy, who anticipated him in isolating the new element, found it to be a metal.
Of selenium, 45.8 per cent.
Traces of gold, silver, selenium or thallium are sometimes present, and the mineral is sometimes worked as an ore of gold or silver.
The impurities contained in coarse-copper are mainly iron, lead, zinc, cobalt, nickel, bismuth, arsenic, antimony, sulphur, selenium and tellurium.
The principles have long been known on which is based the electrolytic separation of copper from the certain elements which generally accompany it, whether these, like silver and gold, are valuable, or, like arsenic, antimony, bismuth, selenium and tellurium, are merely impurities.
SELENIUM [[[symbol]] Se, atomic weight 79.2 (0 =16)], a nonmetallic chemical element, discovered in 1817 by J.
Berzelius, who called it selenium (Gr.
In this process, the residues are boiled with a dilute sulphuric acid to which nitric acid and potassium chlorate are added in order to transform the element into selenic acid, H 2 Se0 4, which is then reduced to selenious acid, H 2 Se0 3, by boiling with hydrochloric acid, and finally to selenium by sulphur dioxide.
It is obtained from zorgite by heating the mineral with aqua regia; the excess of acid is evaporated, and the resulting syrupy liquid diluted, filtered and decomposed by sulphur dioxide, when the selenium is precipitated (Billandot, Ency.
Chem., 18 57, 71, p. 2 79) fuses the commercial selenium with potassium cyanide in a stream of hydrogen, takes up the melt in water and passes air through the solution; the precipitated tellurium is filtered off, and the solution then supersaturated with hydrochloric acid, when selenium is gradually deposited.
Phys., 1900 (7), 21, p. 34) converts the element by dilute nitric acid into selenium dioxide which is then sublimed, and dissolved in water.
Several allotropic forms of selenium have been described, but the work of A.
Chem., 1900, 4, p. 423) seems to establish that the element exists in three distinct forms, namely liquid selenium (which includes the vitreous, soluble and amorphous forms), crystalline red selenium (which includes, perhaps, two very closely allied forms), and crystalline, grey or metallic selenium.
Liquid selenium becomes more and more viscous in character as its temperature falls from 220° C. to 60° C.; it is soft at about 60°, but is hard and brittle between 30° and 40°.
The red crystalline variety is obtained by crystallization of selenium from carbon bisulphide, or by leaving the amorphous form in contact with the same solvent.
A colloidal selenium was obtained by C. Paal and C. Koch (Ber., 1905, 38, p. 526) by reducing selenious acid dissolved in an aqueous solution of sodium protalbate with hydrazine hydrate and hydrochloric acid, the precipitate obtained being then dissolved in sodium carbonate.
The specific gravity of selenium is 4.8; the specific heat varies from 0.0716 to 0.1147, depending upon the particular form.
Selenium combines directly with hydrogen when heated in the gas, and with fluorine in the cold.
Seleniuretted Hydrogen, H 2 Se, is obtained by the direct union of its constituent elements in the heat; by the decomposition of various selenides with mineral acids; by the decomposition of aluminium selenide, or phosphorus selenide with water; by the action of selenium on a concentrated solution of hydriodic acid; and by heating selenium with colophene (H.
Its aqueous solution is unstable, gradually depositing red selenium on standing.
Selenium fluoride, SeF4, is obtained as a colourless liquid by the direct action of fluorine or selenium (P. Lebeau, Comptes rendus, 1907, 144, p. 1042).
Selenium dichloride, Se 2 C1 21 is obtained by the action of chlorine on selenium; by the action of phosphorus pentachloride on selenium or the dioxide; by the action of hydrochloric acid on seleno-sulphur trioxide (E.
SeC1 2 (+H 2 O)-->Se 2 C1 2 -1-SO 2 (OH)Cl; and by heating selenium and selenium tetrachloride to ioo° C. in a sealed tube.
It is a yellowish-brown oily liquid which commences to distil at 130° C. with partial decomposition into selenium and the tetrachloride.