When distilled with phosphoric anhydride they yield nitriles.
91): - 98'734 An ichthyo-coprolite from Tenby was found to contain 15.4% of phosphoric anhydride.
Some other glycerides isolated from natural sources are analogous in composition to tristearin, but with this difference, that the three radicals which replace hydrogen in glycerin are not all identical; thus kephalin, myelin and lecithin are glycerides in which two hydrogens are replaced by fatty acid radicals, and the third by a complex phosphoric acid derivative.
Of phosphoric acid, the cereal crops take up as much as, or more than, any other crops of the rotation, excepting clover; and the greater portion thus taken up is lost to the farm in the saleable product - the grain.
Of potash, each of the rotation crops takes up very much more than of phosphoric acid.
But much less potash than phosphoric acid is exported in the cereal grains, much more being retained in the straw, whilst the other products of the rotation - the root and leguminous crops - which are also supposed to be retained on the farm, contain very much more potash than the cereals, and comparatively little of it is exported in meat and milk.
Thus the whole of the crops of rotation take up very much more of potash than of phosphoric acid, whilst probably even less of it is ultimately lost to the land.
The average of a large number of analyses of Upland cotton seed gives the following figures for its fertilizing constituents: - Nitrogen, 3.07%; phosphoric acid, 1.02%; potash, 1.17%; besides small amounts of lime, magnesia and other valuable but less important ingredients.
Sea Island cotton seed is rather more valuable than Upland: the corresponding figures for the three principal constituents being nitrogen 3.51, phosphoric acid 1 69, potash 1.59%.
Using average prices paid for nitrogen, phosphoric acid and potash when bought in large quantities and in good forms, these ingredients, in a ton of cotton seed, amount to $9.00 worth of fertilizing material.
The hulls thus burned produced an ash containing an average of 9% of phosphoric acid and 24% of potash - a very valuable fertilizer in itself, and one eagerly sought by growers of tobacco and vegetables.
An acid is said to be monobasic, dibasic, tribasic, &c., according to the number of replaceable hydrogen atoms; thus HNO 3 is monobasic, sulphuric acid H 2 SO 4 dibasic, phosphoric acid H 3 PO 4 tribasic.
Clarke, Gay Lussac and Stromeyer, published his masterly investigation of the various phosphoric acids and their salts, obtaining results subsequently employed by J.
Both phosphoric and phosphorous acids became known, although imperfectly, towards the end of the 18th century; phosphorous acid was first obtained pure by Davy in 1812, while pure phosphorous oxide, the anhydride of phosphorous acid, remained unknown until T.
He applied himself more particularly to the oxygen compounds, and determined with a fair degree of accuracy the ratio of carbon to oxygen in carbon dioxide, but his values for the ratio of hydrogen to oxygen in water, and of phosphorus to oxygen in phosphoric acid, are only approximate; he introduced no new methods either for the estimation or separation of the metals.
If phosphoric acid is absent, aluminium, chromium and ferric hydrates are precipitated.
If, however, phosphoric acid is present in the original substance,we may here obtain a precipitate of the phosphates of the remaining metals, together with aluminium, chromium and ferric hydrates.
The phosphates of aluminium, chromium and iron are precipitated, and the solution contains the same metals as if phosphoric acid had been absent.
Nevertheless, in certain cases, the temperature coefficient of conductivity becomes negative at high temperatures, a solution of phosphoric acid, for example, reaching a maximum conductivity at 75° C.
This salt gives the corresponding chloride and fluoride with hydrochloric and hydrofluoric acids, and the phosphate, Pb(HP04)2, with phosphoric acid.
The normal ortho-phosphate, Pb3(P04)2, is a white precipitate obtained by adding sodium phosphate to lead acetate; the acid phosphate, PbHPO 4, is produced by precipitating a boiling solution of lead nitrate with phosphoric acid; the pyrophosphate and meta-phosphate are similar white precipitates.
Form an insoluble calcium soap. The interaction between the soaps, the phosphates and the carbonates which are brought by the blood and lymph to the part results in the weaker fatty acids being replaced by phosphoric and carbonic acid, and thus in the formation of highly insoluble calcium phosphate and carbonate deposits in the disorganized tissues.
In the ordinary chemical analyses of the soil determinations are made of the nitrogen and various carbonates present as well as of the amount of phosphoric acid, potash, soda, magnesia and other components soluble in strong hydrochloric acid.
7,600 lb Phosphoric acid.
9,200 „ From the figures given previously of the amount of nitrogen, potash and phosphoric acid removed by a wheat or mangel crop it would appear that this soil has enough of these ingredients in it to yield many such crops; yet experience has shown that these crops cannot be grown on such a poor sandy soil unless manures containing phosphates, potash and nitrogen are added.
Where the amount of phosphoric acid (P 2 0,) is less than.
In the case of arable soils, where the amount of phosphoric acid determined by this method falls below 01%, phosphatic manuring is essential for good crops.
Propylene is liberated during the reaction, and the phosphoric acid ester of meta-cresol which is formed is then fused with potash.
Sulphurous, phosphoric, carbonic, &c., should be regarded as elementary substances.
This view, which was specially supported by Gay-Lussac and Leopold Gmelin and accepted by Berzelius, necessitated that all acids were monobasic. The untenability of this theory was proved by Thomas Graham's investigation of the phosphoric acids; for he then showed that the ortho- (ordinary), pyroand metaphosphoric acids contained respectively 3, 2 and I molecules of " basic water " (which were replaceable by metallic oxides) and one molecule of phosphoric oxide, P2 05.
Graham's work was developed by Liebig, who called into service many organic acids - citric, tartaric, cyanuric, comenic and meconic - and showed that these resembled phosphoric acid; and he established as the criterion of polybasicity the existence of compound salts with different metallic oxides.
Phosphoric Silver phosphate.
Sir John Murray finds the source of the phosphoric acid to be the decomposition of large quantities of animal matter, and he illustrates this by the well-known circumstance of the death of vast shoals of fish when warm Gulf-Stream water displaces the cold current which usually extends to the American coast.
This compound on heating with phosphoric anhydride loses water and yields anthraquinone, CsH4 O 15 CsH
PHOSPHATES, in chemistry, the name given to salts of phosphoric acid.
As stated under Phosphorus, phosphoric oxide, P 2 0 5, combines with water in three proportions to form H 2 O P 2 0 5 or HP03, metaphosphoric acid; 2H 2 O P 2 0 5 or H4P207, pyrophosphoric acid; and 3H 2 O P 2 0 5 or H 3 PO 4, orthophosphoric or ordinary phosphoric acid.
(K,Na,NH 4)H 5 (PO 4)2, are also known; these may be regarded as composed of a monometallic phosphate with phosphoric acid, thus M'H 2 PO 4 H 3 PO 4.
Other precipitants of phosphoric acid or its salts in solution are: ammonium molybdate in nitric acid, which gives on heating a canary-yellow precipitate of ammonium phosphomolybdate, 12[M00 3] (NH 4) 3 PO 4, insoluble in acids but readily soluble in ammonia; magnesium chloride, ammonium chloride and ammonia, which give on standing in a warm place a white crystalline precipitate of magnesium ammonium phosphate, Mg(NH 4)PO 4.6H 2 0, which is soluble in acids but highly insoluble in ammonia solutions, and on heating to redness gives magnesium pyrophosphate, Mg 2 P 2 0 7; uranic nitrate and ferric chloride, which give a yellowish-white precipitate, soluble in hydrochloric acid and ammonia, but insoluble in acetic acid; mercurous nitrate which gives a white precipitate, soluble in nitric acid, and bismuth nitrate which gives a white precipitate, insoluble in nitric acid.
Pyrophosphoric acid, 'H' 4 P 2 0 7, is a tetrabasic acid which may be regarded as derived by eliminating a molecule of water between two molecules of ordinary phosphoric acid; its constitution may therefore be written (HO) 2 0P O PO(OH) 2.
It may be obtained as a glassy mass, indistinguishable from metaphosphoric acid, by heating phosphoric acid to 215°.
It forms a colourless vitreous mass, hence its name " glacial phosphoric acid."
The trachyte of Cabo de Gata in south-east Spain, which contains 12-15% of phosphoric acid.
Owing, however, to its poverty in that form of nitrogenous compound called gluten, so abundant in wheat, barley-flour cannot be baked into vesiculated bread; still it is a highlynutritious substance, the salts it contains having a high proportion of phosphoric acid.
The normal phosphate, (NH4)3P04,is obtained as a crystalline powder, on mixing concentrated solutions of ammonia and phosphoric acid, or on the addition of excess of ammonia to the acid phosphate (NH 4) 2 HPO 4.
Diammonium hydrogen phosphate, (NH 4) 2 HPO 4, is formed by evaporating a solution of phosphoric acid with excess of ammonia.
Ammonium dihydrogen phosphate, NH 4 ï¿½H 2 PO 4, is formed when a solution of phosphoric acid is added to ammonia until the solution is distinctly acid.
The olefines may be synthetically prepared by eliminating water from the alcohols of the general formula CnH2n+1 OH, using sulphuric acid or zinc chloride generally as the dehydrating agent, although phosphorus pentoxide, syrupy phosphoric acid and anhydrous oxalic acid may frequently be substituted.
It is a most powerful oxidizing agent, phosphorus being readily oxidized to phosphoric acid, arsenic to arsenic acid, silicon at 250° C. to silica, and hydrochloric acid to chlorine and water.
Shutt have proved that soils from the NorthWest Provinces contain an average of 18,000 lb of nitrogen, 15,580 lb of potash and 6,700 lb of phosphoric acid per acre, these important elements of plant food being therefore present in much greater abundance than they are in ordinary cultivated European soils of good quality.
Bog iron ore is an impure limonite, usually formed by the influence of micro-organisms, and containing silica, phosphoric acid and organic matter, sometimes with manganese.
Phosphoric acid, in the form of phosphates, is a most valuable plant food, and is absorbed by most plants in fairly large quantities from the soil.
In the basic Bessemer process, also, unforeseen variations in the siliconcontent are harmful, because the quantity of lime added should be just that needed to neutralize the resultant silica and the phosphoric acid and no more.
As the essential difference between cast iron on one hand and wrought iron and steel on the other is that the former contains necessarily much more carbon, usually more silicon, and often more phosphorus that are suitable or indeed permissible in the latter two, the chief work of all these conversion processes is to remove the excess of these several foreign elements by oxidizing them to carbonic oxide CO, silica S102, and phosphoric acid P 2 0 5, respectively.
As the iron oxide is stirred into the molten metal laboriously by the workman or "puddler " with his hook or "rabble," it oxidizes the silicon to silica and the phosphorus to phosphoric acid, and unites with both these products, forming with them a basic iron silicate rich in phosphorus, called " puddling " or " tap cinder."
That it shall have a great excess of the strong base, ferrous oxide, FeO, for the phosphoric acid to unite with, lest it be deoxidized by the carbon of the iron as fast as it forms, and so return to the iron, following the general rule that oxidized bodies enter the slag and unoxidized ones the metallic iron.
In the basic Bessemer process phosphorus is readily removed by oxidation, because the product of its oxidation, phosphoric acid, P 2 O 5, in the presence of an excess of base forms stable phosphates of lime and iron which pass into the slag, making it valuable as an artificial manure.
So powerful an acid as silica, then the phosphoric acid has so feeble a hold on the base in the slag that it is immediately redeoxidized by the carbon of the metal, or even by the iron itself, P 2 O 5 +5Fe = 2P+5FeO, and the resultant deoxidized phosphorus immediately recombines with the iron.
The slag, in order that it may have such an excess of base that this will retain the phosphoric acid as fast as it is formed by the oxidation of the phosphorus of the pig iron, and prevent it from being re-deoxidized and re-absorbed by the iron, should, according to von Ehrenwerth's rule which is generally followed, contain enough lime to form approximately a tetra-calcic silicate, 4CaO,S10 2 with the silica which results from the oxidation of the silicon of the pig iron and tri-calcic phosphate, 3CaO,P205, with the phosphoric acid which forms. The danger of this " rephosphorization " is greatest at the end of the blow, when the recarburizing additions are made.
The usual composition of this slag is iron oxide, i o to 16%; lime, 40 to 50%; magnesia, 5%; silica, 6 to 9%; phosphoric acid, 16 to 20%.