It is decomposed by water, and with a solution of yellow phosphorus in carbon bisulphide it gives a red powder of composition PBI 2, which sublimes in vacuo at 210° C. to red crystals, and when heated in a current of hydrogen loses its iodine and leaves a residue of boron phosphide PB.
Its own phosphide), which possesses valuable properties.
Phosphuretted hydrogen, one of the most important impurities, which has been blamed for the haze formed by the combustion of acetylene under certain conditions, is produced by the action of water upon traces of calcium phosphide found in carbide.
Calcium phosphide, Ca 3 P 2, is obtained as a reddish substance by passing phosphorus vapour over strongly heated lime.
A phosphide, PCr, is known; it burns in oxygen forming the phosphate.
Phosphorus combines directly with the metal to form W3P4; another phosphide, W2P, results on igniting a mixture of phosphorus pentoxide and tungsten.
The phosphide obtained by heating cupric phosphate, Cu 2 H 2 P 2 O 81 in hydrogen, when mixed with potassium and cuprous sulphides or levigated coke, constitutes " Abel's fuse," which is used as a primer.
A phosphide, Cu 3 P 2, is formed by passing phosphoretted hydrogen over heated cuprous chloride.
An antimony phosphide and arsenide are known, as is also a thiophosphate, SbPS 4, which is prepared by heating together antimony trichloride and phosphorus pentasulphide.
When finely divided it decomposes water giving hydrogen phosphide; it also reduces sulphurous and sulphuric' acids, and when boiled with water gives phosphine and hypophosphorous acid; when slowly oxidized under water it yields, hypophosphoric acid.
Hofmann, Ber., 1871, 4, p. 200); by the decomposition of crystalline calcium phosphide or of aluminium phosphide with water (H.
It is also decomposed when heated with sulphur or with most metals, in the latter case with the liberation of hydrogen and formation of phosphide of the metal.
By passing the products of the decomposition of calcium phosphide with water over granular calcium chloride, the P 2 H 4 gives a new hydride, P1.2H6 and phosphine, the former being an odourless, canary-yellow, amorphous powder.
Solid Phosphoretted Hydrogen, P 4 H 2, first obtained by Le Verrier (loc. cit.), is formed by the action of phosphorus trichloride on gaseous phosphine (Besson, Comptes rendus, 111, p. 972); by the action of water on phosphorus di-iodide and by the decomposition of calcium phosphide with hot concentrated hydrochloric acid.
Halogen Compounds.-Phosphorus trifluoride, PF 3, discovered by Davy, may be obtained mixed with the pentafluoride; by direct combination of its elements; from the tribromide and arsenic trifluoride (Maclvor); from the tribromide and zinc fluoride, and from dried copper phosphide and lead fluoride (H.
Arsenic phosphide, AsP, results when phosphine is passed into arsenic trichloride, being precipitated as a red-brown powder.
Fe2P forms crystalline needles insoluble in acids except aqua regia; it is obtained by fusing copper phosphide with iron.
Rend., 1909, 1 4 8, p. 1 397) on hydrogen phosphide, which gave the value 30.906, and of G.
Sulphate of copper, in doses of 3 to 5 gr., freely diluted and repeated every few minutes forms the harmless, black phosphide of copper, which is rapidly eliminated by the kidneys.