The ammonium cobalto-cobaltisulphite is prepared by saturating an air-oxidized ammoniacal solution of cobaltous chloride with sulphur dioxide.
The pentammine purpureo-salts are formed from the luteo-salts by loss of ammonia, or from an air slowly oxidized ammoniacal cobalt salt solution, the precipitated luteosalt being filtered off and the filtrate boiled with concentrated acids.
It is now known that the action takes place in two stages; the ammonium salt is first oxidized to the nitrite stage and subsequently to the nitrate.
Its methyl derivatives yield the corresponding carboxylic acids when oxidized by potassium permanganate.
It is somewhat readily oxidized; nitric acid gives carbonic and oxalic acids, and chromic acid, carbonic and acetic acids.
Heated with sulphuric acid and with nitric acid it is oxidized to boric acid, whilst on fusion with alkaline carbonates and hydroxides it gives a borate of the alkali metal.
It is obtained by the oxidation of orthophenylene diamine with ferric chloride; when a mixture of para-aminodimethylaniline and meta-toluylenediamine is oxidized in the cold, toluylene blue, an indamine, being formed as an intermediate product and passing into the red when boiled; and also by the oxidation of dimethylparaphenylene diamine with metatoluylene diamine.
It is rapidly oxidized on heating to a temperature of 500°-600° C., and also when fused with nitre or potassium chlorate.
It is readily oxidized by nitric acid, and when strongly heated_ in a current of hydrogen is reduced to the metallic condition.
It is not ~certain how far substances in the protoplasm are directly oxidized without entering into the composition of the living substance, though this appears to take place.
The cut cells die, and oxidized products are concerned in the change of color, the brown juices exuding and soaking into the cell-walls.
The Istrian stone of which the edifice is built has taken a fine patina, which makes the whole look like some richly embossed casket in oxidized silver.
Glycerin when treated with hydrochloric acid gives propenyl dichlorhydrin, which may be oxidized to s-dichloracetone.
Iron and quinine citrate is used as a bitter stomachic and tonic. In the blood citrates are oxidized into carbonates; they therefore act as remote alkalis, increasing the alkalinity of the blood and thereby the general rate of chemical change within the body.
The use of mercury cups is open to many objections on account of the fact that the mercury becomes oxidized, and such instruments are not very convenient for transportation.
Carbon bisulphide slowly oxidizes on exposure to air, but by the action of potassium permanganate or chromic acid it is readily oxidized to carbon dioxide and sulphuric acid.
The hornsilvers all occur under similar conditions and are often associated together; they are found in metalliferous veins with native silver and ores of silver, and are usually confined to the upper oxidized parts of the lodes.
It is also oxidized when fused with caustic potash and nitre, forming a ruthenate.
Lavoisier, to whom chemistry was primarily the chemistry of oxygen compounds, having developed the radical theory initiated by Guyton de Morveau, formulated the hypothesis that vegetable and animal substances were oxides of radicals composed of carbon and hydrogen; moreover, since simple radicals (the elements) can form more than one oxide, he attributed the same character to his hydrocarbon radicals: he considered, for instance, sugar to be a neutral oxide and oxalic acid a higher oxide of a certain radical, for, when oxidized by nitric acid, sugar yields oxalic acid.
Considering derivatives primarily concerned with transformations of the hydroxyl group, we may regard our typical acid as a fusion of a radical R CO - (named acetyl, propionyl, butyl, &c., generally according to the name of the hydrocarbon containing the same number of carbon atoms) and a hydroxyl group. By replacing the hydroxyl group by a halogen, acid-haloids result; by the elimination of the elements of water between two molecules, acid-anhydrides, which may be oxidized to acid-peroxides; by replacing the hydroxyl group by the group. SH, thio-acids; by replacing it by the amino group, acid-amides (q.v.); by replacing it by the group - NH NH2, acid-hydrazides.
Other hydrocarbon nuclei generally classed as aromatic in character result from the union of two or more benzene nuclei joined by one or two valencies with polymethylene or oxidized polymethylene rings; instances of such nuclei are indene, hydrindene, fluorene, and fluoranthene.
This compound is readily oxidized to benzoic acid, C 6 H 5 000H, the aromatic residue being unattacked; nitric and sulphuric acids produce nitro-toluenes, C6H4 CH3 N02j and toluene sulphonic acids, C 6 H 4 CH 3 SO 3 H; chlorination may result in the formation of derivatives substituted either in the aromatic nucleus or in the side chain; the former substitution occurs most readily, chlor-toluenes, C 6 H 4 CH 3 Cl, being formed, while the latter, which needs an elevation in temperature or other auxiliary, yields benzyl chloride, C 6 H 5 CH 2 C1, and benzal chloride, C 6 11 5 CHC1 2.
Soc. 61, p. 367): If the hydrogen compound of the substituent already in the benzene nucleus can be directly oxidized to the' corresponding hydroxyl compound, then meta-derivatives predominate on further substitution, if not, then orthoand paraderivatives.
Klaproth in 1799, is obtained when pure carbon (graphite or charcoal) is oxidized by alkaline permanganate, or when carbon forms the positive pole in an electrolytic cell (Ber., 1883, 16, p. 1209).
Carius showed that potassium chlorate and sulphuric acid oxidized benzene to trichlorphenomalic acid, a substance afterwards investigated by Kekule and 0.
CC13+C02 O?OIi O / O / (4) Cl2HC CO CHCl2+CH302C CCl2C02CH3 (5) Cl2HC CONH2 Cl (z) (2) When phenol is oxidized in acid solution by chlorine, tetrachlorquinone is obtained, a compound also obtainable from hydroquinone.
Merling (Ann., 1894, 278, p. 20) showed to be converted into n-glutaric acid, [[Hooc (Ch2)3 000h]], when oxidized with potassium permanganate; according to D.
The prism formula also received support from the following data: protocatechuic acid when oxidized by nitrous acid gives carboxytartronic acid, which, on account of its ready decomposition into carbon dioxide and tartronic acid, was considered to be HO C(COOH) 3.
From these results Baeyer concluded that Claus' formula with three para-linkings cannot possibly be correct, for the Q2.5 dihydroterephthalic acid undoubtedly has two ethylene linkages, since it readily takes up two or four atoms of bromine, and is oxidized in warm aqueous solution by alkaline potassium permanganate.
From the fact that reduction products containing either one or two double linkages behave exactly as unsaturated aliphatic compounds, being readily reduced or oxidized, and combining with the halogen elements and haloid acids, it seems probable that in benzenoid compounds the fourth valencies are symmetrically distributed in such a manner as to induce a peculiar stability in the molecule.
149, p. 20) established the symmetry of the naphthalene nucleus, and showed that whichever half of the molecule be oxidized the same phthalic acid results.
This is obviously unsymmetrical, consisting of an aliphatic and an aromatic nucleus; Claus explained the formation of the same phthalic acid from the oxidation of either nucleus by supposing that if the aromatic group be oxidized, the aliphatic residue assumes the character of a benzene nucleus.
That stilbene, C 6 H 5 CH:CH C 6 H5, is very readily oxidized, while phenanthrene is not, supports, in some measure, the views of Bamberger.
The oxidation with nitric acid in sealed tubes at a temperature of 150° to 200° for aliphatic compounds, and 250° to 260° for aromatic compounds, is in common use, for both the sulphur and phosphorus can be estimated, the former being oxidized to sulphuric acid and the latter to phosphoric acid.
On the surface, where the sand is bathed by the tidal water, the ferrous sulphide becomes oxidized and the sand is bleached, but underneath it is dense black or grey, as the case may be.
The aldehyde group also reacts with phenyl hydrazine to form two phenylhydrazones; under certain conditions a hydroxyl group adjacent to the aldehyde group is oxidized and glucosazone is produced; this glucosazone is decomposed by hydrochloric acid into phenyl hydrazine and the keto-aldehyde glucosone.
When this compound is acted on by water, hydrogen peroxide and levulinic aldehyde are formed, the aldehyde being subsequently oxidized by the hydrogen peroxide, forming levulinic acid.
The dressed ore is introduced through a "hopper" at the top, and exposed to a moderate oxidizing flame until a certain proportion of ore is oxidized, openings at the side enabling the workmen to stir up the ore so as to constantly renew the surface exposed to the air.
In Cumberland, Northumberland, Durham and latterly the United States, the reverberatory furnace is used only for roasting the ore, and the oxidized ore is then reduced by fusion in a low, square blastfurnace (a "Scottish hearth furnace") lined with cast iron, as is also the inclined sole-plate which is made to project beyond the furnace, the outside portion (the "work-stone") being provided with grooves guiding any molten metal that may be placed on the "stone" into a cast iron pot; the "tuyere" for the introduction of the wind was, in the earlier types, about half way down the furnace.
The zinc and some lead are oxidized; part of the zinc passes off with the fumes, part is dissolved by the litharge, forming a melted mixture which is skimmed off and reduced in a blast-furnace or a reverberatory smelting furnace.
In the kettle covered with a hood the zinc is oxidized by means of dry steam, and incidentally some lead by the air which cannot be completely excluded.
They are easily oxidized to the corresponding fatty acid, in many cases simply by exposure to air.
Paraldehyde is oxidized by dilute nitric acid, with formation of much glyoxal, (CHO) 2.
Nitroso-tertiary butane, (CH 3) 3 C NO, is formed when the corresponding hydroxylamine is oxidized by sulphuric monoper acid (E.
These are oxidized and precipitated conjointly by excess of ammonia.
Exposed to air this mixture is oxidized to the pigment uranium red, U6(NH4)2S09, which is a fine blood-coloured amorphous powder.
The solutions are oxidized, precipitated with ammonia, the precipitate dissolved in hydrochloric acid, and re-thrown down by boiling with sodium sulphate.
In a similar manner, formic acid and dicyanophenylhydrazine yields a phenyl-triazole carboxylic acid, in which the phenyl group may be nitrated, the nitro group reduced to the amino group, and the product oxidized to a triazole carboxylic acid, which, by elimination of carbon dioxide, yields the free triazole: HO 2 C C=N H02C C =N, NPh-> N :CH N :CH They also result when the acidylthiosemicarbazides are strongly heated, the mercapto-triazoles so formed being converted into triazoles on oxidation with hydrogen peroxide (M.
Calcium or potassium sulphides and potassium hydrosulphides completely reduce nitroglycerin to glycerin, some of the sulphur being oxidized and some precipitated.
Aniline and similar bases are oxidized and partially nitrated by nitroglycerin, with the production of non-explosive compounds.