Pont--Mousson, Frouard, Lor Ardennes Charleville, Nouzon Sain-Bel (Rhne), manganese chiefly from Ariege and Sane-et.
In unlimited supply, important deposits of rich iron ores suitable for smelting purposes; and for the manufacture of steel of certain descriptions abundance of manganese, chrome and tungsten ores are available.
Manganese probably exists in all the states, deposits having been found in New South Wales, Victoria, Queensland and Western Australia, the richest specimens being found in New South Wales.
Wolfram (tungstate of iron and manganese) occurs in some of the states, notably in New South Wales, Victoria, Tasmania and Queensland.
The manganese ores of the Bathurst district of New South Wales often contain a small percentage of cobalt - sufficient, indeed, to warrant further attempts to work them.
Iron, coal, copper and manganese are mined.
The chief minerals are sulphur, in the production of which Italy holds one of the first places, iron, zinc, lead; these, and, to a smaller extent, copper of an inferior quality, manganese and antimony, are successfully mined.
Near Tokat copper pyrites, with iron and manganese, kaolin and coal are found; but most of the copper worked here comes from the mines of Keban Maden and Arghana Maden, on the upper Euphrates and Tigris.
The colour of amethyst is usually attributed to the presence of manganese, but as it is capable of being much altered and even discharged by heat it has been referred by some authorities to an organic source.
Gay-Lussac in 181q, is usually obtained in the form of its barium salt by suspending freshly precipitated hydrated manganese dioxide in water and passing sulphur dioxide into the mixture until all is dissolved; the barium salt is then precipitated by the careful addition of barium hydroxide.
Much manganese sulphate is formed during the reaction, and H.
Soc., 1902, 81, p. I) showed that this can be almost entirely avoided by replacing the manganese oxide by hydrated ferric oxide, the reaction proceeding according to the equation: 2Fe(OH) 3 3S0 2 = FeS 2 0 6 FeS0 3 3H 2 0.
He points out that the available oxygen in the oxides may react either as SO 2 + H 2 O ?-- O = H 2 SO 4 or as 2S0 2 -IH20 + 0 = H 2 S 2 0 6; and that in the case of ferric oxide 96% of the theoretical yield of dithionate is obtained, whilst manganese oxide only gives about 75%.
The external trade of the Russian empire (bullion and the external trade of Finland not included) since the year 1886 is shown in the following table: The exports rank in the following order :- cereals (wheat, barley, rye, oats, maize, buckwheat) and flour, 49.2%; timber and wooden wares, 7.2; petroleum, 5.8; eggs, 5.4; flax, 5; butter, 3; sugar, 2-4; cottons and oilcake, 2 each; oleaginous seeds, &c., 1.5; with hemp, spirits, poultry, game, bristles, hair, furs, leather, manganese ore, wool, caviare, live-stock, gutta-percha, vegetables and fruit, and tobacco.
Considerable quantities of the following minerals have been found: barytes (heavy spar), magnetite (magnetic iron ore), and pyrolusite (manganese dioxide) in Humboldt county; roofing slate in Esmeralda county; cinnabar (ore containing quicksilver) in Washoe county; haematite in Elko and Churchill counties; cerussite and galena (lead ores) in Eureka county; and wolframite (a source of tungsten) at Round Mountain, White Pine county.
Recent experiments lead to the conclusion that iron, lead, manganese, lignite and sulphur exist in considerable abundance.
Manganese ore is mined for export, and bismuth is reported to have been discovered.
In the cultivated parts the land is so exceedingly fertile and productive that it sells for almost fabulous prices, and its value is still further enhanced by the discovery of manganese and copper mines in the basin of the Rion, and of the almost inexhaustible supplies of naphtha and petroleum at Baku in the Apsheron peninsula.
South of Batum), at Akhtala south of Tiflis, and at Kedabek in Elisavetpol; manganese to a considerably greater extent (over 400,000 tons annually) at Chiaturi in the Kvirila valley in Kutais.
The export that comes next in value is silk, and after it may be named wheat, barley, manganese ore, maize, wool, oilcake, carpets, rye, oats, liquorice and timber.
Now, however, the mottled soaps, blue and grey, are produced by working colouring matter, ultramarine for blue, and manganese dioxide for grey, into the soap in the frame, and mottling is very far from being a certificate of excellence of quality.
He found, however, that chromic acid, which he had represented as Cr06, neutralized a base containing 3 the 3 The following symbols were also used by Bergman: W, V, " + ", which represented zinc, manganese, cobalt, bismuth, nickel, arsenic, platinum, water, alcohol, phlogiston.
2 a but may unite with three of chlorine, which never combines with more than a single atom of hydrogen; an atom of phosphorus unites with only three atoms of hydrogen, but with five of chlorine, or with four of hydrogen and one of iodine; and the chlorides corresponding to the higher oxides of lead, nickel, manganese and arsenic, Pb0 2, Ni 2 0 3, Mn0 2 and As 2 0 5 do not exist as stable compounds, but the lower chlorides, PbCl 2j NiC12, MnC1 2 and AsC1 3j are very stable.
Hjelm in 1783, and tungsten by Don Fausto d'Elhuyar; manganese was isolated by J.
If the substance does not melt but changes colour, we may have present: zinc oxide - from white to yellow, becoming white on cooling; stannic oxide - white to yellowish brown, dirty white on cooling; lead oxide - from white or yellowish-red to brownish-red, yellow on cooling; bismuth oxide - from white or pale yellow to orange-yellow or reddish-brown, pale yellow on cooling; manganese oxide - from white or yellowish white to dark brown, remaining dark brown on cooling (if it changes on cooling to a bright reddishbrown, it indicates cadmium oxide); copper oxide - from bright blue or green to black; ferrous oxide - from greyish-white to black; ferric oxide - from brownish-red to black, brownish-red on cooling; potassium chromate - yellow to dark orange, fusing at a red heat.
If the bead is coloured we may have present: cobalt, blue to violet; copper, green, blue on cooling; in the reducing flame, red when cold; chromium, green, unaltered in the reducing flame; iron, brownish-red, light-yellow or colourless on cooling; in the reducing flame, red while hot, yellow on cooling, greenish when cold; nickel, reddish to brownish-red, yellow to reddish-yellow or colourless on cooling, unaltered in the reducing flame; bismuth, yellowish-brown, light-yellow or colourless on cooling; in the reducing flame, almost colourless, blackish-grey when cold; silver, light yellowish to opal, somewhat opaque when cold; whitish-grey in the reducing flame; manganese, amethyst red, colourless in the reducing flame.
To the filtrate from the aluminium, iron and chromium precipitate, ammonia and ammonium sulphide are added; the precipitate may contain nickel, cobalt, zinc and manganese sulphides.
The next group precipitate may contain the white gelatinous aluminium hydroxide, the greenish chromium hydroxide, reddish ferric hydroxide, and possibly zinc and manganese hydroxides.
The next group may contain black nickel and cobalt sulphides, flesh-coloured manganese sulphide, and white zinc sulphide.
Lead and manganese are partially separated as peroxides, but the remaining metals are not deposited from acid solutions.
Lead chromate is sometimes used, and many other substances, such as platinum, manganese dioxide, &c., have been suggested.
Trans., 1885, 176, 455) employed his yoke method to test the magnetic properties of thirty-five samples of iron and steel, among which were steels containing substantial proportions of manganese, silicon, chromium and tungsten.
The most striking phenomenon which they bring into prominence is the effect of any considerable quantity of manganese in annihilating the magnetic property of iron.
A sample of Hadfield's manufacture, containing 1 2.36% of manganese, differed hardly at all from a non-magnetic substance, its permeability being only 1.27.
5 More than fifty different specimens were tested, most of which contained a known proportion of manganese, nickel, tungsten, aluminium, chromium, copper or silicon; in some samples two of the substances named were present.
The addition of 15.2% of manganese produced an enormous effect C.R., 1897, 124, 176 and 1515; 1897, 125, 235; 1898, 126, 738.2 Ibid., 1898, 126, 741.
Certain non-magnetizable alloys of nickel, chromium-nickel and chromium-manganese were rendered magnetizable by annealing.
Heusler 2 in 1903 that certain alloys of the non-magnetic metal manganese with other non-magnetic substances were strongly magnetizable, their susceptibility being in some cases equal to that of cast iron.
The metals used in different combinations included tin, aluminium, arsenic, antimony, bismuth and boron; each of these, when united in certain proportions with manganese, together with a larger quantity of copper (which appears to serve merely as a menstruum), constituted a magnetizable alloy.
So far, the best results have been attained with aluminium, and the permeability was greatest when the percentages of manganese and aluminium were approximately proportional to the atomic weights of the two metals.
Thus in an alloy containing 26.5% of manganese and 14.6% of aluminium, the rest being copper, the induction for H= 20 was 4500, and for H=150, 5550.
When the proportion of aluminium to manganese was made a little greater or smaller, the permeability was diminished.