Which with baryta gave chloroform and maleic acid.
Many derivatives are known, some of which exist in two structural forms, exhibiting geometrical isomerism after the mode of fumaric and maleic acids.
It forms deliquescent crystals, which are readily soluble in alcohol and melt at ioo° C. When heated for some time at 130° C. it yields fumaric acid (q.v.), and on rapid heating at 180° C. gives maleic anhydride and fumaric acid.
Consequently, of each pair of isomers we may establish beforehand which is the more stable; either in particular circumstances, a direct change taking place, as, for instance, with maleic acid, which when exposed to sunlight in presence of a trace of bromine, yields the isomeric fumaric acid almost at once, or, indirectly, one may conclude that the isomer which forms under greater heat-development is the more stable, at least at lower temperatures.
Dessaignes, ibid., 1860, 115, p. 120; by reducing fumaric and maleic acids with sodium amalgam; by heating bromacetic acid with silver to 130° C.; in small quantity by the oxidation of acetic acid with potassium persulphate (C. Moritz and R.
Hydriodic acid and phosphorus reduce it to maleic acid and finally to succinic acid.
Pasteur, Ann., 1853, 88, p. 212); by heating tartaric or racemic acid for some time with water to 165° C.; by the oxidation of laevulose; and by the oxidation of phenol or maleic acid with an alkaline solution of potassium permanganate (0.