The sesquisulphide, Ir 2 S 3, is obtained as a brown precipitate when sulphuretted hydrogen is passed into a solution of one of the sesqui-salts.
Following Newton, he believed a gas to be made up of particles or atoms, From Dalton's Hydrogen Gas.
In water and in ethylene experiment shows that 8 parts by weight of oxygen and 6 parts of carbon, respectively, are in union with one part of hydrogen; also, if the diagrams are correct, these numbers must be in the ratio of the atomic weights of oxygen and carbon.
Experiment shows that, in water and ammonia, we have, respectively, 8 parts of oxygen and 4.67 parts of nitrogen in union with one part of hydrogen; we can therefore infer that the oxides of nitrogen will all have the composition of 8m parts of oxygen to 4.67n parts of nitrogen.
The astonishing variety of ratios in which carbon and hydrogen combine was not at first realized.
Morley's experiments on the synthesis of water the hydrogen, the oxygen and the water that had been formed were separately determined; taking the mean of his results, the sum of the weights of the ingredients is not found to differ from the weight of the product by one part in 10,000.
To take the simplest possible case, if Dalton had been correct in assuming that the molecule of water was made up of one atom of oxygen and one of hydrogen, then the experimental fact that water contains eight parts by weight of oxygen to one part of hydrogen, would at once show that the atom of oxygen is eight times as heavy as the atom of hydrogen, or that, taking the atomic weight of hydrogen as the unit, the.
Similarly, Dalton's diagram for ammonia, together with the fact that ammonia contains 4.67 parts of nitrogen to one of hydrogen, at once leads to the conclusion that the atomic weight of nitrogen is 4.67.
The symbol, like that of Dalton, always stands for the atomic weight of the element, that is, while H stands for one part by weight of hydrogen, 0 stands for 16 parts of oxygen, and so on.
Thus the symbol or formula H 2 O for water expresses the view that the molecule of water consists of one atom of oxygen and two of hydrogen; and if we know the atomic weights of oxygen and hydrogen, it also tells us the composition of water by weight.
Dalton believed that the molecules of the elementary gases consisted each of one atom; his diagram for hydrogen gas makes the point clear.
Necessary to determine the specific gravities of the various gases referred to some one of them, say hydrogen; the numbers so obtained giving the weights of the molecules referred to that of the hydrogen molecule.
Metallic cobalt may be obtained by reduction of the oxide or chloride in a current of hydrogen at a red heat, or by heating the oxalate, under a layer of powdered glass.
On heating in hydrogen, ammonia or carbon monoxide, or with carbon or sodium, it is reduced to the metallic state.
Heated at 190-300° in a current of hydrogen it gives the oxide C0304, while at higher temperatures the monoxide is formed, and ultimately cobalt is obtained.
By suspending cobaltous hydroxide in water and adding hydrogen peroxide, a strongly acid liquid is obtained (after filtering) which probably contains cobaltous acid, H2CoO 3.
They are precipitated from their alkaline solutions as cobalt sulphide by sulphuretted hydrogen, but this precipitation is prevented by the presence of citric and tartaric acids; similarly the presence of ammonium salts hinders their precipitation by caustic alkalis.
It may be prepared in the amorphous form by heating cobalt with sulphur dioxide, in a sealed tube, at 200° C. In the hydrated condition it is formed by the action of alkaline sulphides on cobaltous salts, or by precipitating cobalt acetate with sulphuretted hydrogen (in the absence of free acetic acid).
For the quantitative determination of cobalt, it is either weighed as the oxide, C0304, obtained by ignition of the precipitated monoxide, or it is reduced in a current of hydrogen and weighed as metal.
Certain yeasts exercise a reducing action, forming sulphuretted hydrogen, when sulphur is present.
The gas contains a certain amount of hydrogen and oxides of carbon, also traces of nitrogen.
In order to get rid of hydrogen, some oxygen is added to the helium, and the mixture exploded by an electric spark.
The effect is even perceptible at a temperature as low as 220° C. Hydrogen, and, in a much less degree, oxygen and nitrogen, will also permeate silica, but only at higher temperatures.
At low temperatures, on the other hand, they find, using an initial pressure of 'coo mm., that the temperatures on the helium scale are measurably higher than on the hydrogen scale, owing to the more perfectly gaseous condition of helium.
It combines with sulphuretted hydrogen, in the .presence of water, to form the compound C 2 N 2 H 2 S, and in the presence of alcohol, to form the compound C 2 N 2.2H 2 S.
ACID-AMIDES, chemical compounds which may be considered as derived from ammonia by replacement of its hydrogen with acidyl residues, the substances produced being known as, primary, secondary or tertiary amides, according to the number of hydrogen atoms replaced.
On the other hand, they show faintly acid properties since the hydrogen: of the amido group can be replaced by metals to give such compounds as mercury acetamide (CH 3 CONH) 2 Hg.
By the addition of sulphuretted hydrogen to the nitriles, or by the action of phosphorus pentasulphide on the acid-amides.
It is decomposed by water, and with a solution of yellow phosphorus in carbon bisulphide it gives a red powder of composition PBI 2, which sublimes in vacuo at 210° C. to red crystals, and when heated in a current of hydrogen loses its iodine and leaves a residue of boron phosphide PB.
Borimide B 2 (NH) 3 is obtained on long heating of the compound B 2 S 3.6NH 3 in a stream of hydrogen, or ammonia gas at 115-120° C. It is a white solid which decomposes on heating into boron nitride and ammonia.
A pentasulphide B2S5 is prepared, in an impure condition, by heating a solution of sulphur in carbon bisulphide with boron iodide, and forms a white crystalline powder which decomposes under the influence of water into sulphur, sulphuretted hydrogen and boric acid.
Recent analyses prove the presence of a small but variable amount of potassium (K 2 O, 2.68-4.13°/x) in the Cornish crystals, though in those from Hungary there is only a trace; this constituent appears to take the place of basic hydrogen in the above formula.
On oxidation with chromic or nitric acids, or potassium permanganate, it yields nicotinic acid or (3-pyridine carboxylic acid, C 5 H 4 N CO 2 H; alkaline potassium ferricyanide gives nicotyrine, C10H10N2, and hydrogen peroxide oxynicotine, C10H14N20.
On fusion with solid potash at 250° C. it completely decomposes, giving potassium oxalate and hydrogen, C2H602-1-2KHO =K2C204+4H2.
It does not melt at a white heat, and is easily reduced to the metal by heating in a current of hydrogen or with carbon.
Cadmium sulphide, CdS, occurs naturally as greenockite (q.v.), and can be artificially prepared by passing sulphuretted hydrogen through acid solutions of soluble cadmium salts, when it is precipitated as a pale yellow amorphous solid.
It can also be determined as sulphide, by precipitation with sulphuretted hydrogen, the precipitated sulphide being dried at Ioo° C. and weighed.
His researches on sebacic acid (1802) and on bile (1807), and his discovery of peroxide of hydrogen (1818) also deserve mention.
Molybdenum dioxide, Mo02, is formed by heating sodium trimolybdate, Na2M03010, to redness in a current of hydrogen (L.
It is readily oxidized by nitric acid, and when strongly heated_ in a current of hydrogen is reduced to the metallic condition.
Molybdenum trisulphide, MoS3, is obtained by saturating a solution of an alkaline molybdate with sulphuretted hydrogen and adding a mineral acid.
The original hypothesis of Baeyer suggested that the course of events is the following: the carbon dioxide is decomposed into carbon monoxide and oxygen, while water is simultaneously split up into hydrogen and oxygen; the hydrogen and the carbon monoxide unite to form formaldehyde and the oxygen is exhaled.
Certain Algae have been found capable of forming nutritive carbohydrates in darkness, when supplied with a compound of this body with sodium-hydrogen-sulphite.
The first chemical change suggested is an interaction between carbon dioxide and water, under the influence of light acting through chlorophyll, which leads to the simultaneous formation of formaldehyde and hydrogen peroxide.
The formaldehyde at once undergoes a process of condensation oi- polymerization by the protoplasm of the plastid, while the hydrogen peroxide is said to be decomposed into water and free oxygen by another agency in the cell, of the nature of one of the enzymes of which we shall speak later.
It may be obtained from argyrodite by heating the mineral in a current of hydrogen; or by heating the dioxide to redness with carbon.
It can also be obtained by passing sulphuretted hydrogen through a solution of the dioxide in hydrochloric acid.
By heating the disulphide in a current of hydrogen, germanious sulphide, GeS, is formed.
Volcanic sulphur usually occurs as a sublimate around or on the walls of the vents, and has probably been formed in many cases by the interaction of sulphur dioxide and hydrogen sulphide.
Deposits of sulphur are frequently formed by the decomposition of hydrogen sulphide, on exposure to the atmosphere: hence natural sulphureous waters, especially hot springs, readily deposit sulphur.