The solution is diluted with water, and the hydrocarbons are thereby precipitated and separated.
To this attitude he offered uncompromising opposition, and by the synthetical production of numerous hydrocarbons, natural fats, sugars and other bodies he proved that organic compounds can be formed by ordinary methods of chemical manipulation and obey the same laws as inorganic substances, thus exhibiting the "creative character in virtue of which chemistry actually realizes the abstract conceptions of its theories and classifications - a prerogative so far possessed neither by the natural nor by the historical sciences."
Dibasic acids of the paraffin series of hydrocarbons have the general formula C n H 2 (000H) 2 "; malonic and succinic acids are important members.
It readily condenses with aromatic hydrocarbons in the presence of sulphuric acid.
This heat of formation, like that of most hydrocarbons, is comparatively small: the heat of formation of saturated hydrocarbons is always positive, but the heat of formation of unsaturated hydrocarbons is frequently negative.
The calorific power of Baku oil appears to be highest, while this oil is poorest in solid hydrocarbons, of which the American petroleums contain moderate quantities, and the Upper Burma oils the largest amount.
The principal elements are found in various combinations, the hydrocarbons of the Pennsylvania oils being mainly paraffins (q.v.), while those of Caucasian petroleum belong for the most part to the naphthenes, isomeric with the olefines (q.v.).
The " cracking " process, whereby a considerable quantity of the oil which is intermediate between kerosene and lubricating oil is converted into hydrocarbons of lower specific gravity and boiling-point suitable for illuminating purposes, is one of great scientific and technical interest.
It is generally understood that the products of fractional distillation, even in the laboratory, are not identical with the hydrocarbons present in the crude oil, but are in part produced by the action of heat upon them.
They found that the paraffin was thus converted, with the evolution of but little gas, into hydrocarbons which were liquid at ordinary temperatures.
In an experiment on 3500 grams of paraffin produced from shale (melting point 44'5° C.) they obtained nearly 4 litres of liquid hydrocarbons, which they subjected to fractional distillation, and on examining the fraction distilling below loo° C., they found it to consist mainly of olefines.
The result of this treatment is that the comparatively heavy oils undergo dissociation, as shown by the experiments of Thorpe and Young, into specifically lighter hydrocarbons of lower boiling points, and the yield of kerosene from ordinary crude petroleum may thus be greatly increased.
Under such conditions, distillation takes place at higher temperatures than the normal boiling-points of the constituent hydrocarbons of the oil, and a partial cracking results.
In the American petroleum refineries it is found that sufficient cracking can be produced by slow distillation in stills of which the upper part is sufficiently cool to allow of the condensation of the vapours of the less volatile hydrocarbons, the condensed liquid thus falling back into the heated body of oil.
The rationale of this treatment is not fully understood, but the action appears to consist in the separation or decomposition of the aromatic hydrocarbons, fatty and other acids, phenols, tarry bodies, &c., which lower the quality of the oil, the sulphuric acid removing some, while the caustic soda takes out the remainder, and neutralizes the acid which has been left in the oil.
In France, the standard is 35° C. (Granier tester, equivalent to 98° F.), and according to their flashpoint, liquid hydrocarbons are divided into two classes (below and above 35° C.), considered differently in regard to quantities storable and other regulations.
A consequence of this empirical division was that marsh gas, ethylene and cyanogen were regarded as inorganic, and at a later date many other hydrocarbons of undoubtedly organic nature had to be included in the same division.
Taking as types hydrogen, hydrochloric acid, water and ammonia, he postulated that all organic compounds were referable to these four forms: the hydrogen type included hydrocarbons, aldehydes and ketones; the hydrochloric acid type, the chlorides, bromides and iodides; the water type, the alcohols, ethers, monobasic acids, acid anhydrides, and the analogous sulphur compounds; and the ammonia type, the amines, acid-amides, and the analogous phosphorus and arsenic compounds.
An apt definition of organic chemistry is that it is "the study of the hydrocarbons and their derivatives."
Two distinct types of hydrocarbons exist: (1) those consisting of an open chain of carbon atoms - named the " aliphatic series " (i.XEicAap, oil or fat), and (2) those consisting of a closed chain - the " carbocyclic series."
Let us now consider hydrocarbons containing 2 atoms of carbon.
Hydrocarbons containing any number of double or triple linkages, as well as both double and triple linkages, are possible, and a considerable number of such compounds have been prepared.
From n-butane we may derive, by a similar substitution of methyl groups, the two hydrocarbons: (I) CH 3 CH 2 CH 2 CH 2 CH 3, and (2) CH 3.
These three hydrocarbons are isomeric, i.e.
(methylene) groups and the molecule consists of a single chain; such hydrocarbons are referred to as being normal; (2) has a branch and contains the group; CH (methine) in which the free valencies are attached to carbon atoms; such hydrocarbons are termed secondary or iso-; (3) is characterized by a carbon atom linked directly to four other carbon atoms; such hydrocarbons are known as tertiary.
Deferring the detailed discussion of cyclic or ringed hydrocarbons, a correlation of the various types or classes of compounds which may be derived from hydrocarbon nuclei will now be given.
Cyclic Hydrocarbons and Nuclei.
By fusing two nuclei we obtain the formula of naphthalene, C 1 oH 8; by fusing three, the hydrocarbons anthracene and phenanthrene, C14H10; by fusing four, chrysene, C18H12, and possibly pyrene, C16H1n; by fusing five, picene, C22 H 14.
This and other facts connected with the stability of benzenoid compounds are clearly shown when we consider mixed aliphatic-aromatic hydrocarbons, i.e.
Thomsen then investigated heats of combustion of various benzenoid hydrocarbons - benzene, naphthalene, anthracene, phenanthrene, &c. - in the crystallized state.
But, at the same time, the constants in the above relation are not identical with those in the corresponding relation empirically deduced from observations on fatty hydrocarbons; and we are therefore led to conclude that a benzene union is considerably more stable than an ethylene union.
Considering the hydrocarbons given by the general formula C x H y, the internal linkages of the carbon atoms need at least xi bonds, using up 2(xI) valencies of the 4x to be accounted for, and thus leaving no more than 2(x-11) for binding hydrogen: a compound C 3 H 9 is therefore impossible, and indeed has never been met.
They may be prepared by the oxidation of secondary alcohols; by the addition of the elements of water to hydrocarbons of the acetylene type RC CH; by oxidation of primary alcohols of the type RR' CH CH 2 OH:RR' CH CH 2 OH --> R CO R'+H20+H2C02; by distillation of the calcium salts of the fatty acids, C.H2.02; by heating the sodium salts of these acids CnH2n02 with the corresponding acid anhydride to 190 C. (W.
The para or true quinones are obtained by the oxidation of hydrocarbons with chromic acid or of various para di-derivatives of benzene with chromic acid mixture, such, for example, as para-aminophenol, para-phenylene diamine, paraa.minoazobenzene, &c. H.
OLEFINE, in organic chemistry, the generic name given to open chain hydrocarbons having only singly and doubly linked pairs of carbon atoms. The word is derived from the French olefiant (from olefier, to make oil), which was the name given to ethylene, the first member of the series, by the Dutch chemists, J.
The earlier papers deal chiefly with the properties and modes of synthesis of cloud chain hydrocarbons and their derivatives.
Bone has shown that when exposed for some time to the sun's rays it undergoes certain polymerization changes which lead to the deposition of a film of heavy hydrocarbons on the surface of the tube.
Hydrocarbons, such as petroleum, bitumen, paraffin, &c., are also found occasionally in coal, but more generally in the associated sandstones and limestones of the Carboniferous formation.
P This term is founded on a misapprehension of the nature of the occurrence, since, although the softening takes place at a low temperature, still it marks the point at which destructive distillation commences, and hydrocarbons both of a solid and gaseous character are formed.
The action is not properly understood; it may be due to the reducing gases (hydrogen, hydrocarbons, &c.) which are invariably present in wood charcoal.
It dissolves most organic compounds, resins, hydrocarbons, fatty acids and many metallic salts, sometimes forming, in the latter case, crystalline compounds in which the ethyl alcohol plays a role similar to that of water of crystallization.
It is convenient to distinguish between aliphatic and aromatic acids; the first named being derived from open-chain hydrocarbons, the second from ringed hydrocarbon nuclei.