From the primary amines are derived the diazo compounds and azo compounds; closely related are the hydrazines (q.v.).
The first class includes those substances which require no preliminary treatment, and comprises the amides and ammonium compounds, pyridines, quinolines, alkaloids, albumens and related bodies; the second class requires preliminary treatment and comprises, with few exceptions, the nitro-, nitroso-, azo-, diazoand amidoazo-compounds, hydrazines, derivatives of nitric and nitrous acids, and probably cyanogen compounds.
Bamberger, Ber., 1893, 26, p. 2786): CsH5N :N N :N jC COC6H5 - C6H5NH2+C6H4K C 6 H5 NH N N:C 0006H5; by the reduction of symmetrical acyl-ortho-nitrophenyl hydrazines (e.g.
Chemie, 1866, 2, p. 308), on account of their ready condensation to form azo compounds and their easy reduction to hydrazines, assumed that they were substances of the type R N: N Cl.
Senderens, Comptes rendus, 1901, 132, p. 210 seq.); and from hydrazines of the type CnH2,2_1 NH NH2 by oxidation with alkaline potassium ferricyanide (N.