Chem., 1905, (2), 71, p. 452) by reducing ruthenium salts with hydrazine hydrate in the presence of gum-arabic.
Its ethyl ester condenses with hydrazine to form pyrazolone (R.
Thus with hydroxylamine aldehydes yield aldoximes, R CH: N OH, and ketones, ketoximes, R 2 C: N OH (see Oximes), while phenyl hydrazine gives phenylhydrazones, R 2 C:N NH C 6 H 5 (see Hydrazones).
Arndt, Ber., 1899, 32, p. 2136); by the oxidation of hydroxylamine (ibid., 1900, 33, p. 30); and by the electrolysis of hydrazine and its salts (E.
Nitrogen combines with hydrogen to form ammonia, NH 3, hydrazine, N 2 H 4, and azoimide, N 3 H (qq.v.); the other known hydrides, N 4 H 4 and N5H5, are salts of azoimide, viz.
The aldehyde group also reacts with phenyl hydrazine to form two phenylhydrazones; under certain conditions a hydroxyl group adjacent to the aldehyde group is oxidized and glucosazone is produced; this glucosazone is decomposed by hydrochloric acid into phenyl hydrazine and the keto-aldehyde glucosone.
Its ethyl ester reacts with hydrazine to form hippuryl hydrazine, C,H 5 CO NH CH 2 CO NH NH 2, which was used by Curtius for the preparation of azoimide.
The diketotetrahydrotriazoles, or urazoles, are formed by condensing urea derivatives with hydrazine salts, urazole itself resulting by the action of urea or biuret on hydrazine or its salts.
- Fischer found that if one molecule of phenylhydrazine acted upon one molecule of an aldose or ketose a hydrazone resulted which in most cases was very soluble in water, but if three molecules of the hydrazine reacted (one of which is reduced to ammonia and aniline) insoluble crystalline substances resulted, termed osazones, which readily characterized the sugar from which it was obtained.
Semioxamazide, H 2 N CO CO-NH NH 2, is prepared by the action of hydrazine hydrate on oxamaethane (W.
Chem., 1905 (2), 71, p. 45 2) by reducing osmium compounds with hydrazine hydrate in the presence of gum arabic.
Goldschmidt, Ber., 1888, 21, p. 2578), and on reduction with zinc dust (preferably in alcoholic acetic acid solution) they yield usually a hydrazine and an amine.
HYDRAZONE, in chemistry, a compound formed by the condensation of a hydrazine with a carbonyl group (see Alde Hydes; Ketones).
They combine with hydrocyanic acid to form nitriles, which on hydrolysis furnish hydroxyacids, (CH3)2C0 -> (CH 3) 2 C OH CN - (CH3)2 C OH C02H; with phenylhydrazine they yield hydrazones; with hydrazine they yield in addition ketazines RR' C:N N:C RR' (T.
When heated with hydrazine hydrate at 150° C. it gives a-naphthyl hydrazine, C 1 oH 7 NH NH 2 Hoffmann, Ber., 1898, 31, p. 2909).
Amidourea, or semicarbazide, NH 2 CO NH NH 2, is best prepared from hydrazine sulphate and potassium cyanate (J.
Thiosemicarbazide, NH 2 CS NH NH 2, prepared from hydrazine sulphate, potassium carbonate and thiocyanate (N.
Amidoguanidine is a body of hydrazine type, for it reduces gold and silver salts and yields a benzylidine derivative.
It forms a hydrazone with phenyl hydrazine, and an oxime with hydroxylamine.
A colloidal selenium was obtained by C. Paal and C. Koch (Ber., 1905, 38, p. 526) by reducing selenious acid dissolved in an aqueous solution of sodium protalbate with hydrazine hydrate and hydrochloric acid, the precipitate obtained being then dissolved in sodium carbonate.