Reduction of this ester leads to the formation of ammonia, hydroxylamine, and dimethyl pyrrol dicarboxylic ester, C(CH3): C C02R HN< C(CO 2 R) :C CH3.
Thiele, Ann., 1898, 302, p. 299): HN:CC NH NH2 OC C 6 H 5 NH N + -> HN:CC C C6 H 5 NH 2 OC C6H5 N = C/-C6H5 Wolff has obtained a chloro-derivative by the action of potassium cyanide on diazoacetophenone and subsequent treatment with acid.
HC=N CO NH CO NH HN CO ›NH, N=CH?
It is evident that we may have tones of frequency hn 1 kn 2 hn i - kn 2 hnl+kn2, where h and k are any integers.
GUANIDINE, CN 3 H 5 or HN: C(NH 2) 2j the amidine of amidocarbonic acid.
By direct union with glycocoll acid, it yields glycocyamine, NH2 (HN): C NH CH 2 CO 2 H, whilst with methyl glycocoll (sarcosine) it forms creatine, NH2 (NH): C N(CH3) CH2 C02H.
By the action of nitric acid on guanidine in the presence of sulphuric acid, nitroguanidine, HN: C(NH 2) NH NO 2 (a substance possessing acid properties) is obtained; from which, by reduction with zinc dust, amidoguanidine, HN :C(NH 2) NH NH 2, is formed.
On oxidation with potassium permanganate, it gives azodicarbondiamidine nitrate, NH 2 (HN) C N: N C:(NH) NH 2 2HNO 3, which, when reduced by sulphuretted hydrogen, is converted into the corresponding hydrazodicarbondiamidine, NH 2 (HN):C NH NH C:(NH) NH 2.
By the action of nitrous acid on a nitric acid solution of amidoguanidine, diazoguanidine nitrate, NH 2 (HN): C NH N 2 NO 3, is obtained.
By fusing guanidine with urea, dicyandiamidineH 2 N (HN): C NH CO NH 21 is formed.
- anp, Anterior neural pore; be, rudiment of buccal skeleton; c, cilia; cb, ciliated band; cc, ciliated groove; cm, cilia at margin of mouth; gl, external opening of club-shaped gland; Hn, Hatschek's nephridium; lm, left metapleur; n, notochord; pp, praeoral pit; ps, primary gill-slits, I, 5, and 13; rm, right metapleur showing through.
1 + t .Il o .O?h'n,'C111au?11LnI?In11n7n'InIwN1 ?