Chlorination in glacial acetic acid solution yields pentachlor-m-diketo-R-hexene (2) and, at a later stage, heptachlor-m-diketo-R-hexene (3).
Hantzsch (Ber., 1889, 22, p. 1238) succeeded in ob R taining derivatives of o-diketo-R-hexene, which yield R-pentene and aliphatic compounds on decomposition.
When thus chlorinated phenol (I) yields trichlor-o-diketo-R-hexene (2), which may be hydrolysed to an acid (3), which, in turn, suffers rearrangement to trichlor-R-pentene-oxycarboxylic acid (4).
Cyclo-hexene (tetrahydrobenzene), C 6 H 10, was obtained by A.
Methyl-i-cyclo-hexene- I-one-3, CH.
Isocamphor, CioH160, is methyl-Iisopropyl-3-cyclo-hexene-I-one 6.
Tetrahydro Tetrahydrobenzoic acid (cyclo-hexene i-carboxylic acid-I), C 6 H 9 CO 2 H.
Tetrahydrophthalic acids (cyclo - hexene dicarboxylic acids), C 6 H 8 (CO 2 H) 2.