POLYMETHYLENES, in chemistry, cyclic compounds, the simplest members of which are saturated hydrocarbons of general formula C 7, H 2nj where n may be r to 9, and known as tri-, tetra-, penta-, hexa-, and hepta-methylene, &c., or cyclo- propane, -butane, -pentane, -hexane, -heptane, &c.: - CH 21 CH 2 CH 2 CH2.CH2 CH2 CH2 CH2?C1H,, I I H ?
Dihydro Anhydride with acetic anhydride Sodium amalgam in faintly alkaline solution Sodium amalgam (hot) .1 Hydrobromide on reduction Remove H Br from 1.3 Dihydro dibromide Cyclo-heptane Group. Cyclo-heptane (suberane), C 7 H 14, obtained by the reduction of suberyl iodide, is a liquid which boils at 117° C. On treatment with bromine in the presence of aluminium bromide it gives chiefly pentabromtoluene.
Cyclo-heptene, C 7 H 121 is obtained by the action of alcoholic potash on suberyl iodide; and from cyclo-heptane carboxylic acid, the amide of which by the action of sodium hypobromite is converted into cyclo-heptanamine, which, in its turn, is destructively methylated (R.
Cyclo-heptanone (suberone), C 7 H 12 O, is formed on the distillation of suberic acid with lime, and from a-brom-cyclo-heptane carboxylic acid by treatment with baryta and subsequent distillation over lead peroxide (R.
Cyclo-heptane carboxylic acid (suberanic acid), C7H13C02H, is obtained by the reduction of cyclo-heptene-I-carboxylic acid; from brom-cyclo-heptane by the Grignard reaction; and by the reduction of hydrotropilidine carboxylic acid by sodium in alcoholic solution (R.
Numerous amino-derivatives of the cyclo-heptane series have been prepared by R.
Amino-cyclo-heptane (suberylamine) is obtained by the reduction of suberone oxime or by the action of sodium hypobromite on the amide of cycloheptane carboxylic acid.
The heptane layer was collected and analyzed by GC-MS.