It is readily soluble in alcohol, ether and water.
Other products were soluble in the ether-alcohol mixture: they were less highly nitrated, and constituted the so-called collodion guncotton.
Pyrogallol dimethyl ether is found in beechwood tar.
The result, was in Helmholtz's words, to establish beyond doubt that ordinary light consists of electrical vibrations in an all-pervading ether which possesses the properties of an insulator and of a magnetic medium.
The crystalline form appears to be due entirely to the carotin, which can be artificially crystallized from an alcohol or ether solution.
It is a colourless pleasant-smelling liquid which boils at 154.3° C. Phenetol, phenyl ethyl ether, C 6 H 5.
The purity men love is like the mists which envelop the earth, and not like the azure ether beyond.
The now well-known fact that small doses of poisonous substances may act as stimuli to living protoplasm, and that respiratory activity and growth may be accelerated by chloroform, ether and even powerful mineral poisons, such as mercuric chloride, in minimal doses, offers some explanation of these phenomena of hypertrophy, wound fever, and other responses to the presence of irritating agents.
It has a characteristic smell, and a biting taste; it is poisonous, and acts as a powerful antiseptic. It dissolves in water, 15 parts of water dissolving about one part of phenol at 16-17° C., but it is miscible in all proportions at about 70° C.; it is volatile in steam, and is readily soluble in alcohol, ether, benzene, carbon bisulphide, chloroform and glacial acetic acid.
Chromium oxychloride reacts violently on phenol, producing hydroquinone ether, O(C 6 H 4 OH)2; chromic acid gives phenoquinone, and potassium permanganate gives paradiphenol, oxalic acid, and some salicylic acid (R.
Anisol, phenyl methyl ether, C 6 H 5.
Hantzsch (Ber., 1901, 34, p. 3337) has shown that in the action of alcohols on diazonium salts an increase in the molecular weight of the alcohol and an accumulation of negative groups in the aromatic nucleus lead to a diminution in the yield of the ether produced and to the production of a secondary reaction, resulting in the formation of a certain amount of an aromatic hydrocarbon.
Give ether and brandy subcutaneously and apply hot water-bottles and blankets if there are signs of collapse.
It is almost insoluble in water, but mixes in all proportions with absolute alcohol, ether, benzene and various oils.
7-trihydroxyxanthone, is found in the form of its methyl ether (gentisin) in gentian root; it is obtained synthetically by condensing phloroglucin with hydroquinone carboxylic acid.
The binary conception of compounds held by Berzelius received apparent support from the observations of Gay Lussac, in 1815, on the vapour densities of alcohol and ether, which pointed to the conclusion that these substances consisted of one molecule of water and one and two of ethylene respectively; and from Pierre Jean Robiquet and Jean Jacques Colin, showing, in 1816, that ethyl chloride (hydrochloric ether) could be regarded as a compound of ethylene and hydrochloric acid.
However, in 1833, Berzelius reverted to his earlier opinion that oxygenated radicals were incompatible with his electrochemical theory; he regarded benzoyl as an oxide of the radical C 14 H 1Q, which he named " picramyl " (from 7rucp6s, bitter, and &uvyalk, almond), the peroxide being anhydrous benzoic acid; and he dismissed the views of Gay Lussac and Dumas that ethylene was the radical of ether, alcohol and ethyl chloride, setting up in their place the idea that ether was a suboxide of ethyl, (C2H5)20, which was analogous to K 2 0, while alcohol was an oxide of a radical C 2 H 6; thus annihilating any relation between these two compounds.
This view was modified by Liebig, who regarded ether as ethyl oxide, and alcohol as the hydrate of ethyl oxide; here, however, he was in error, for he attributed to alcohol a molecular weight double its true value.
Williamson showed how alcohol and ether were to be regarded as derived from water by substituting one or both hydrogen atoms by the ethyl group; he derived acids and the acid anhydrides from the same type; and from a comparison of many inorganic and the simple organic compounds he concluded that this notion of a " water-type " clarified, in no small measure, the conception of the structure of compounds.
Thus the thio-alcohols or mercaptans (q.v.) contain the group - CH2 SH; and the elimination of the elements of sulphuretted hydrogen between two molecules of a thio-alcohol results in the formation of a thio-ether or sulphide, R 2 S.
Bamberger opposed Claus' formula on the following grounds: - The molecule of naphthalene is symmetrical, since 2.7 dioxynaphthalene is readily esterified by methyl iodide and sulphuric acid to a dimethyl ether; and no more than two mono-substitution derivatives are known.
By actual observations it has been shown that ether, alcohol, many esters of the normal alcohols and fatty acids, benzene, and its halogen substitution products, have critical constants agreeing with this originally empirical law, due to Sydney Young and Thomas; acetic acid behaves abnormally, pointing to associated molecules at the critical point.
A similar depression is presented by methyl alcohol (67°) and methyl ether (-23 °) Among the aromatic di-substitution derivatives the ortho compounds have the highest boiling-point, and the meta boil at a higher, or about the same temperature as the para compounds.
The thermal effect of the ether group has an average value of 34.3 1 calories.
Thus oxygen varies according as whether it is linked to hydrogen (hydroxylic oxygen), to two atoms of carbon (ether oxygen), or to one carbon atom (carbonyl oxygen); similarly, carbon varies according as whether it is singly, doubly, or trebly bound to carbon atoms.
Normal values of K were given by nitrogen peroxide, N204, sulphur chloride, S 2 C1 21 silicon tetrachloride, SiC1 4, phosphorus chloride, PC1 3, phosphoryl chloride, POC1 31 nickel carbonyl, Ni(CO) 4, carbon disulphide, benzene, pyridine, ether, methyl propyl ketone; association characterized many hydroxylic compounds: for ethyl alcohol the factor of association was 2.74-2.43, for n-propyl alcohol 2.86-2.72, acetic acid 3.62 -2.77, acetone 1 .
Margoliouth, " The Doctrine of Ether in the Kabbalah," Jew.
Soc., 18 9 8, 73, p. 35 2) as a colourless liquid by the addition of hydroxylamine hydrochloride to an aqueous solution of formaldehyde in the presence of sodium carbonate; the resulting solution was extracted with ether and the oxime hydrochloride precipitated by gaseous hydrochloric acid, the precipitate being then dissolved in water, the solution exactly neutralized and distilled.
They are usually insoluble in water, alcohol and ether; and their presence as solutes in vegetable and animal fluids is not yet perfectly understood, but it is probably to be connected with the presence of salts or other substances.
It crystallizes in colourless plates or needles, which melt at 99° C. Its solutions in alcohol and ether have a faint blue fluorescence.
In particular, he found that the calculated velocity with which it transmitted electromagnetic disturbances was equal to the observed velocity of light; hence he was led to believe, not only that his medium and the ether were one and the same, but, further, that light itself was an electromagnetic phenomenon.
Soc. chim., 1904 [31, 31, p.1306) prepares aldehydes by the gradual addition of disubstituted formamides (dissolved in anhydrous ether) to magnesium alkyl haloids, the best yields being obtained by the use of diethyl formamide.
Grignard (Comptes Rendus, 1900 et seq.) showed that aldehydes combine with magnesium alkyl iodides (in absolute ether solution) to form addition products, which are decomposed by water with the formation of secondary alcohols, thus from acetaldehyde and magnesium methyl iodide, isopropyl alcohol is obtained.
It is miscible in all proportions with alcohol, ether and water.
The silver salt, obtained by shaking an ether solution of nitroform with freshly prepared, slightly moist silver oxide, reacts with methyl iodide to form trinitroethane, a crystalline solid which melts at 56° C. Concentrated caustic potash decomposes the latter compound, forming the potassium salt of dinitroethane, CH3 C(N02)2K.
On the ether hand, a survey of the facts of cellular embryology which were accumulated in regard to a variety of classes within a few years of Kovalevsky's work led to a generalization, independently arrived at by Haeckel and Lankester, to the effect that a lower grade of animals may be distinguished, the Protozoa or Plastidozoa, which consist either of single cells or colonies of equiformal cells, and a higher grade, the Metazoa or Enterozoa, in which the egg-cell by " cell division " gives rise to two layers of cells, the endoderm and the ectoderm, surrounding a primitive digestive chamber, the archenteron.
These results show that piperonylic acid is the methylene ether of protocatechuic acid.
This colouring power is due to the presence of polychlorite, a substance whose chemical formula appears to be C4 8 1-160018, and which may be obtained by treating saffron with ether, and afterwards exhausting with water.
This particular product was insoluble in a mixture of ether and alcohol, and its composition could be expressed by the term tri-nitrocellulose.
Carefully prepared guncotton after washing with alcohol-ether until nothing more dissolves may require to be heated to 180-185° C. before inflaming.
A characteristic difference between guncotton and collodion cotton is the insolubility of the former in ether or alcohol or a mixture of these liquids.
The solubility in ether-alcohol may be owing to a lower degree of nitration, or to the temperature conditions under which the process of manufacture has been carried on.
Generally speaking, the lower the nitrogen content of a guncotton, as found by the nitrometer, the higher the percentage of matters soluble in a mixture of ether-alcohol.
The making of ether by the action of sulphuric acid on alcohol was known in about the 13th century; and later Basil Valentine and Valerius Cordus described its preparation and properties.
The name ether appears to have been applied to the drug only since the times of Frobenius, who in 1730 termed it spiritus aethereus or vini vitriolatus.
It was considered to be a sulphur compound, hence its name sulphur ether; this idea was proved to be erroneous by Valentine Rose in about 1800.
Ether is manufactured by the distillation of 5 parts of 90% alcohol with 9 parts of concentrated sulphuric acid at a temperature of 140°-145° C., a constant stream of alcohol being caused to flow into the mixture during the operation.
The presence of so small a quantity as i% of alcohol may be detected in ether by the colour imparted to it by aniline violet; if water or acetic acid be present, the ether must be shaken with anhydrous potassium carbonate before the application of the test.
Applied externally, ether evaporates very rapidly, producing such intense cold as to cause marked local anaesthesia.
It appeared to have no companion in the universe--sporting there alone--and to need none but the morning and the ether with which it played.
It is soluble in alcohol, ether, chloroform and boiling water.
He had the credit of being the first to explain the process of etherification and to elucidate the formation of ether by the interaction of sulphuric acid and alcohol.