Soc., 1856, p. 30) electrolysed an equimolecular mixture of potassium and calcium chlorides (which melts at a lower temperature than potassium chloride) also between carbon electrodes; whilst Castner's process, in which caustic potash is electrolysed, is employed commercially.
Hydrolysis with hydrochloric acid or baryta water gives tropic acid and tropine; on the other hand, by boiling equimolecular quantities of these substances with dilute hydrochloric acid, atropine is reformed.
Balard discovered chlorine monoxide in 1834, investigating its properties and reactions; and his observations on hypochlorous acid and hypochlorites led him to conclude that " bleaching-powder " or " chloride of lime " was a compound or mixture in equimolecular proportions of calcium chloride and hypochlorite, with a little calcium hydrate.
Neumann, who, in 1831, deduced from observations on many carbonates (calcium, magnesium, ferrous, zinc, barium and lead) that stoichiometric quantities (equimolecular weights) of compounds possess the same heat capacity.
He introduced the idea of comparing the refractivity of equimolecular quantities of different substances by multiplying the function (n-1)/d by the molecular weight (M) of the substance, and investigated the relations of chemical grouping to refractivity.
Obviously equimolecular surfaces are given by (Mv) 3, where M is the molecular weight of the substance, for equimolecular volumes are Mv, and corresponding surfaces the two-thirds power of this.
In commerce three brands of aniline are distinguished - aniline oil for blue, which is pure aniline; aniline oil for red, a mixture of equimolecular quantities of aniline and orthoand para-toluidines; and aniline oil for safranine, which contains aniline and ortho-toluidine, and is obtained from the distillate (echappes) of the fuchsine fusion.