Other methods are to place the metal and mercury together in dilute acid, to add mercury to the solution of a metallic salt, to place a metal in a solution of mercuric nitrate, or to electrolyse a metallic salt using mercury as the negative electrode.
These chemists electrolyse either pure calcium chloride, or a mixture of this salt with fluorspar, in a graphite vessel which servos as the anode.
Cryolite is not a safe body to electrolyse, because the minimum voltage needed to break up the aluminium fluoride is 4.0, whereas the sodium fluoride requires only 4.7 volts; if, therefore, the current rises in tension, the alkali is reduced, and the final product consists of an alloy with sodium.
In diameter, found that the current given by it could only electrolyse acidulated water in 40 hours sufficient to liberate one cubic centimetre of mixed gases.
One of the first discoveries made with it was its power to electrolyse or chemically decompose certain solutions.
Davy tried to electrolyse baryta, but was unsuccessful; later attempts were made by him using barium chloride in the presence of mercury.
Elektrochem., 1906, 55, p. 537) electrolyse a mixture of bromide and chloride which melts at 520°.