"Jenn, you remember what we learned when we went through training together, about how, when you realize how thirsty you are …" "… you've already reached the point of dehydration," she finished.
As a useful preliminary it is convenient to divide heterocyclic ring systems into two leading groups: (I) systems resulting from simple internal dehydration (or similar condensations) of saturated aliphatic compounds - such compounds are: the internal anhydrides or cyclic ethers of the glycols and thioglycols (ethylene oxide, &c.); the cyclic alkyleneimides resulting from the splitting off of ammonia between the amino groups of diaminoparaffins (pyrrolidine, piperazine, &c.); the cyclic esters of oxycarboxylic acids (lactones, lactides); the internal anhydrides of aminocarboxylic acids (lactams, betaines); cyclic derivatives of dicarboxylic acids (anhydrides, imides, alkylen-esters, alkylenamides, &c.).
-> CH3C6H5CONHC6H51 N OH Syn-phenyltolylketoxime CH3 C6H4 C C6H5 CH3C6H4NH000,H5 HO N A nti-tolylphenylketoxime In the case of the aldoximes, that one which most readily loses the elements of water on dehydration is assumed to contain its hydroxyl radical adjacent to the movable hydrogen atom and is designated the syn-compound.
Acetonyl-acetophenone, C6H5.CO.CH2.CH2.CO.CH3, is produced by condensing phenacyl bromide with sodium acetoacetate with subsequent elimination of carbon dioxide, and on dehydration gives aa-phenyl-methyl-furfurane.
COï¿½NH2, which by further dehydration yield nitriles, Rï¿½CN.
The carbonate, being insoluble in strong alcohol (and many other liquid organic compounds), is much used for dehydration of the corresponding aqueous preparations.
Dehydration results in the formation of a "betaine," which is a tetrahydro-trigonelline (see Betaine).
In later processes, carnallite (a natural double chloride of magnesium and potassium) has commonly, after careful dehydration, been substituted for the single chloride.
It probably represents the partial dehydration of limonite, and by further loss of water may pass into haematite or red iron ore.
Correlatively in its process of dehydration to form plaster of Paris, monosymmetric gypsum is converted into the orthorhombic form before it begins to be dehydrated.
Distilled with zinc dust morphine yields phenanthrene, pyridine and quinoline; dehydration gives, under certain conditions, apomorphine, C17H17N02, a white amorphous substance, readily soluble in alcohol, either and chloroform.